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Volume 25
Main Index

Issue 1


Differences in binding of (1,2-cyclohexanediamine)platinum(II) isomers with d(GpG)
Kenji Inagaki and Yoshinori Kidani
pp 1 - 3; DOI:
10.1021/ic00221a001
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Synthesis of the octathiotritungstate dianion, W3S82-. First example of square-planar coordination about a tungsten atom
Sumit Bhaduri and James A. Ibers
pp 3 - 4; DOI:
10.1021/ic00221a002
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Synthesis of square-pyramidal platinum-osmium clusters by metal-metal exchange. Isolation and structural characterization of a hexanuclear intermediate
Richard D. Adams, James E. Babin, Rahina Mahtab, and Suning Wang
pp 4 - 5; DOI:
10.1021/ic00221a003
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Mixed-metal gold clusters. Synthesis and x-ray structural characterization of [Au5Re(H)4(PPh3)7](PF6)2 and [Au3Rh(H)(CO)(PPh3)5](PF6)
Paul D. Boyle, Brian J. Johnson, Angela Buehler, and Louis H. Pignolet
pp 5 - 7; DOI:
10.1021/ic00221a004
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Unusual route to an acyl complex in cluster chemistry: synthesis, structure, and reactivity of Ru3(.mu.-.eta.2-C(O)(C6H5)(.mu.3-.eta.2-P(C6H5)(C5H4N)(CO)9
Noel Lugan, Guy Lavigne, and Jean Jacques Bonnet
pp 7 - 9; DOI:
10.1021/ic00221a005
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Synthesis of new hybrid phosphine amide complexes of rhodium(I) and iridium(I). Intramolecular "chelate-assisted" oxidative addition of an N-H bond to iridium(I)
David Hedden and D. Max Roundhill
pp 9 - 15; DOI:
10.1021/ic00221a006
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Solid-state structure of .alpha.-bis[bis(diphenylphosphino)ethane]tetrachlorodimolybdenum and its transformation to .beta.-bis[bis(diphenylphosphino)ethane]tetrachlorodimolybdenum. Evidence for the internal flip mechanism
Pradyot A. Agaskar and F. Albert Cotton
pp 15 - 19; DOI:
10.1021/ic00221a007
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Peroxo and dioxo metal carbonyl intermediates in the photooxidation of matrix-isolated M(CO)6 (M = Cr, Mo, W) in the presence of dioxygen: a vibrational spectroscopic study using oxygen-18
Matthew J. Almond, Joseph A. Crayston, Anthony J. Downs, Martyn Poliakoff, and James J. Turner
pp 19 - 25; DOI:
10.1021/ic00221a008
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Insertions of small molecules carbon monoxide, methyl isocyanide, sulfur dioxide, and carbon disulfide into the Pd-Pd .sigma.-bond of Pd2Cl2(PMe2CH2PMe2)2. Crystal and molecular structure of Pd2(.mu.-CO)Cl2(PMe2CH2PMe2)2
Marc L. Kullberg and Clifford P. Kubiak
pp 26 - 30; DOI:
10.1021/ic00221a009
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Vibrational spectra of terminal metal hydrides: solution and matrix-isolation studies of [(.eta.-C5H5)2MHn]x+ (M = Re, Mo, W, Nb, Ta; n = 1-3; x = 0, 1)
Reuben B. Girling, Peter Grebenik, and Robin N. Perutz
pp 31 - 36; DOI:
10.1021/ic00221a010
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Magnetic and spectroscopic studies of new electrically conducting copper complexes: 7,7,8,8-tetracyanoquinodimethanides of copper chelates with di-2-pyridylamine
Motomichi Inoue and Michiko B. Inoue
pp 37 - 41; DOI:
10.1021/ic00221a011
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Tris(o-phenylenedioxy)cyclotriphosphazene: the clathration-induced monoclinic to hexagonal solid-state transition
Harry R. Allcock, Michael L. Levin, and Robert R. Whittle
pp 41 - 47; DOI:
10.1021/ic00221a012
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Preparation of six- and eight-membered mixed cyanuric-thiazyl rings, (R2NCN)x(NSCl)2 (x = 1,2) and the x-ray crystal structure of (Et2NCN)(NSCl)2
T. Chivers, J. F. Richardson, and N. R. M. Smith
pp 47 - 51; DOI:
10.1021/ic00221a013
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Synthesis and characterization of new chromium(III) complexes of macrocyclic ligands
Balachandran Unni Nair, T. Ramasami, and D.. Ramaswamy
pp 51 - 55; DOI:
10.1021/ic00221a014
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Optical resolution and racemization reaction of tris(bathophenanthrolinedisulfonato)iron(II): absence of an intramolecular racemization path in aqueous solution
Akihiko Yamagishi
pp 55 - 57; DOI:
10.1021/ic00221a015
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Competition of thiols and cyanide for gold(I)
George Lewis and C. Frank Shaw
pp 58 - 62; DOI:
10.1021/ic00221a016
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Proton NMR study of aromatic ring stacking in ternary palladium(II) complexes involving aromatic diamines and dipeptides with N-terminal aromatic amino acid residues
Akira Odani, Shuhei Deguchi, and Osamu Yamauchi
pp 62 - 69; DOI:
10.1021/ic00221a017
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NMR investigation of the lanthanide complexes with a 14-membered polyaza polyacetic macrocycle TETA. Another rare example of nonlabile lanthanide compounds
J. F. Desreux and M. F. Loncin
pp 69 - 74; DOI:
10.1021/ic00221a018
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Absorption and EPR spectral characterization of tetrasulfur-bridged mixed-valence dimers of molybdenum(III/IV). EPR evidence for tight ion pair formation in anionic systems
Carla J. Casewit and M. Rakowski DuBois
pp 74 - 80; DOI:
10.1021/ic00221a019
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Host-to-guest, excited-state energy transfer in lamellar solids. Photoluminescent properties of hydrated europium uranyl phosphate
Michael M. Olken, Carla M. Verschoor, and Arthur B. Ellis
pp 80 - 82; DOI:
10.1021/ic00221a020
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Isomers of C2B3H5 and the diamond-square-diamond rearrangement mechanism
Benjamin M. Gimarc and Jane J. Ott
pp 83 - 85; DOI:
10.1021/ic00221a021
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Boron-nitrogen compounds. 108. Triply bridged diboron species of the pyrazabole type
J. Bielawski and K. Niedenzu
pp 85 - 87; DOI:
10.1021/ic00221a022
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Boron-nitrogen compounds. 109. Polynuclear pyrazolyl-bridged spiro species containing boron and metal centers
J. Bielawski, T. G. Hodgkins, W. J. Layton, K. Niedenzu, P. M. Niedenzu, and S. Trofimenko
pp 87 - 90; DOI:
10.1021/ic00221a023
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Formation of 1,1-[bis(diphenylphosphino)ethane]-2,3-dicarba-1-nickela-closo-heptaborane via the intermediacy of 4,5-[.mu.-halogeno[bis(diphenylphosphino)ethane]nickel]-2,3-dicarba-nido-hexaborane(8)
Lawrence Barton and Pamela K. Rush
pp 91 - 93; DOI:
10.1021/ic00221a024
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Electron transfer. 76. Reduction of carboxylato-bound chromium(V) with uranium(IV)
Rathindra N. Bose and E. S. Gould
pp 94 - 97; DOI:
10.1021/ic00221a025
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Hydrogenation of unsaturated dicarboxylic acids by dicarbonylbis(.eta.5-cyclopentadienyl)titanium(II) and molecular structure of (.mu.-acetylenedicarboxylato)bis[bis(.eta.5-methylcyclopentadienyl)titanium(III)]
David R. Corbin, J. L. Atwood, and Galen D. Stucky
pp 98 - 102; DOI:
10.1021/ic00221a026
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Bis axially coordinated (phthalocyaninato)ruthenium(II) compounds
Wolfram Kobel and Michael Hanack
pp 103 - 107; DOI:
10.1021/ic00221a027
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Interaction of copper(II) with N-(2-hydroxyethyl)piperazine-N'-ethanesulfonic acid (HEPES)
Kaspar Hegetschweiler and Paul Saltman
pp 107 - 109; DOI:
10.1021/ic00221a028
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Hyper-closo metallaboranes
R. T. Baker
pp 109 - 111; DOI:
10.1021/ic00221a029
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Structure and bonding in recently isolated metallaboranes
John D. Kennedy
pp 111 - 112; DOI:
10.1021/ic00221a030
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Photochemistry of (.eta.5-C5H5)2M2(CO)3 (M = Co, Rh) in low-temperature organic glasses: generation of [(.eta.5-C5H5)M(.mu.-CO)]2
F. Ruth Anderson and Mark S. Wrighton
pp 112 - 114; DOI:
10.1021/ic00221a031
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Kinetics of the reduction of manganese(III) myoglobin by dithionite
Robert Langley, Peter Hambright, Kenneth Alston, and P. Neta
pp 114 - 117; DOI:
10.1021/ic00221a032
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An NMR study of carbon-13 in two zirconium iodide cluster carbides, CsZr6I14C and Zr6I12C
C. G. Fry, J. D. Smith, B. C. Gerstein, and J. D. Corbett
pp 117 - 118; DOI:
10.1021/ic00221a033
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Crystal structure of [Co(CoL3)2]2(SO4)Cl4: corrigendum
Richard E. Marsh, Mary Jane Heeg, and Edward Deutsch
pp 118 - 118; DOI:
10.1021/ic00221a034
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Electrochemistry studies of [Nb3(.eta.6-HMB)3Cl6]+ (HMB = hexamethylalbenzene), a trinuclear metal cluster complex that reversibly attains four oxidation states
David C. Boyd, Matthew Gebhard, and Kent R. Mann
pp 119 - 120; DOI:
10.1021/ic00221a035
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Issue 2


Electrochemistry of porphyrins containing a metal-metal bond. Reactions of "carbenoid" (TpTP)GeFe(CO)4 and (TpTP)SnFe(CO)4
K. M. Kadish, B. Boisselier-Cocolios, C. Swistak, J. M. Barbe, and R. Guilard
pp 121 - 122; DOI:
10.1021/ic00222a001
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Synthesis of tris(3,5-di-tert-butylcatecholato)molybdenum(VI) and its reaction with molecular oxygen
Marion E. Cass and Cortlandt G. Pierpont
pp 122 - 123; DOI:
10.1021/ic00222a002
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Electrochemical generation of an iron(IV) porphyrin
John T. Groves and John A. Gilbert
pp 123 - 125; DOI:
10.1021/ic00222a003
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Preparation and structure of W(CO)5OPPh2NPPh3, a novel complex containing a ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation
Donald J. Darensbourg, Magdalena Pala, and Arnold L. Rheingold
pp 125 - 127; DOI:
10.1021/ic00222a004
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The principal components of synthetic vitamin B'12
Luigi C. Marzilli, Wallace O. Parker, Rakesh K. Kohli, H. L. Carrell, and Jenny P. Glusker
pp 127 - 129; DOI:
10.1021/ic00222a005
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Alkylation of ortho-carborane by ester pyrolysis
David Albagli, Guo Xiu Zheng, and Maitland Jones
pp 129 - 130; DOI:
10.1021/ic00222a006
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Transfer of oxygen from percarboxylic acids and alkyl hydroperoxides to (meso-tetraphenylporphinato)cobalt(III) chloride
William A. Lee and Thomas C. Bruice
pp 131 - 135; DOI:
10.1021/ic00222a007
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Synthesis and study of mononuclear ruthenium(II) complexes of sterically hindering diimine chelates. Implications for the catalytic oxidation of water to molecular oxygen
J. P. Collin and Jean Pierre Sauvage
pp 135 - 141; DOI:
10.1021/ic00222a008
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Cobalt(II) chelate catalyzed oxidation of 3,5-di-tert-butylcatechol
Shigeru Tsuruya, Shunichi Yanai, and Mitsuo Masai
pp 141 - 146; DOI:
10.1021/ic00222a009
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Chelated cobalt bis(ethylenediamine) amino acid ester complexes: racemization during peptide synthesis
Nahla Mensi and Stephan S. Isied
pp 147 - 150; DOI:
10.1021/ic00222a010
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Studies of technetium complexes. 9. Use of the tetrachloronitridotechnetate(VI) anion for the preparation of nitrido complexes of technetium. Crystal structure of bis(8-quinolinethiolato)nitridotechnetium(V)
John Baldas, John Bonnyman, and Geoffrey A. Williams
pp 150 - 153; DOI:
10.1021/ic00222a011
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X-ray crystallographic characterization of a stepwise, metal-assisted oxidative decarboxylation: vanadium complexes of ethylenebis[(o-hydroxyphenyl)glycine] and derivatives
Paul E. Riley, Vincent L. Pecoraro, Carl J. Carrano, Joseph Bonadies, and Kenneth N. Raymond
pp 154 - 160; DOI:
10.1021/ic00222a012
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Dynamics of spin-state interconversion and cooperativity for ferric spin-crossover complexes in the solid state. 6. Magnetic and spectroscopic characterizations of [Fe(3-OEt-SalAPA)2]X (X = ClO4-, or BPh4-)
Mark D. Timken, A. M. Abdel-Mawgoud, and David N. Hendrickson
pp 160 - 164; DOI:
10.1021/ic00222a013
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Electron transfer. 77. Electrochemistry of carboxylato-bound chromium(V)
Rathindra N. Bose, V. D. Neff, and E. S. Gould
pp 165 - 168; DOI:
10.1021/ic00222a014
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Direct synthesis of alkali-metal and ammonium pentafluoroperoxytitanates(IV), A3[Ti(O2)F5], and first synthesis and structural assessment of alkali-metal and ammonium difluorodiperoxytitanates(IV), A2[Ti(O2)2F2]
Mihir K. Chaudhuri and Bimalendu Das
pp 168 - 170; DOI:
10.1021/ic00222a015
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The cyanate ion as bridging ligand: synthesis, spectroscopic characterization, and magnetic properties of (.mu.-cyanato)bis(pentaamminechromium(III)) chloride
Thomas Schoenherr
pp 171 - 175; DOI:
10.1021/ic00222a016
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Spectroscopic and kinetic studies on a series of di- to heptanuclear tris(bipyrazine)ruthenium(II)-pentacyanoferrate(II) complexes in aqueous solution
H. E. Toma and A. B. P. Lever
pp 176 - 181; DOI:
10.1021/ic00222a017
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Trends of magnetic interactions in related transition-metal dimers
B. Leuenberger and H. U. Guedel
pp 181 - 184; DOI:
10.1021/ic00222a018
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Reduction of peroxotitanium(IV) by sulfur(IV), iron(II), and titanium(III) in acidic solution
Richard C. Thompson
pp 184 - 188; DOI:
10.1021/ic00222a019
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Circularly polarized luminescence studies of the ternary complexes formed by terbium(III) with chiral amino polycarboxylates and achiral substrate ligands
Laura Spaulding, Harry G. Brittain, Lila H. O'Connor, and Karl H. Pearson
pp 188 - 193; DOI:
10.1021/ic00222a020
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Reactivity of trinuclear ruthenium clusters with mercury halides
Edward Rosenberg, David Ryckman, I Nan Hsu, and Robert W. Gellert
pp 194 - 199; DOI:
10.1021/ic00222a021
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Trinucleation of arylazo oxime ensembles. 2. Linear iron(II)-nickel(II)-iron(II) and related systems
Samudranil Pal, Rabindranath Mukherjee, Milagros Tomas, Larry R. Falvello, and Animesh Chakravorty
pp 200 - 207; DOI:
10.1021/ic00222a022
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New terdentate ligands containing nitrogen and phosphorus or arsenic as donor atoms and their complexes with ruthenium(II) and -(III)
M. M. Taqui Khan and V. Vijay Sen Reddy
pp 208 - 214; DOI:
10.1021/ic00222a023
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A new mixed-ligand diruthenium(II) compound. Synthesis and characterization of [Ru2Cl(Me2PCH2PMe2)2(PhNpy)2][PBh4]
Akhil R. Chakravarty, F. Albert Cotton, and Larry R. Falvello
pp 214 - 219; DOI:
10.1021/ic00222a024
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Preparation and structural characterization of a novel hexanuclear complex of platinum(II) with 2-aminoethanethiolate
Dan Gibson and Stephen J. Lippard
pp 219 - 222; DOI:
10.1021/ic00222a025
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Structure of trichloro(diethylenetriamine)gold(III), Au(dien)Cl4, determined by single-crystal x-ray diffraction, Raman and EXAFS spectroscopies: an EXAFS caveat
R. C. Elder and J. W. Watkins
pp 223 - 226; DOI:
10.1021/ic00222a026
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Independent control of charge-transfer and metal-centered excited states in mixed-ligand polypyridine ruthenium(II) complexes via specific ligand design
William F. Wacholtz, Roy A. Auerbach, and Russell H. Schmehl
pp 227 - 234; DOI:
10.1021/ic00222a027
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Trichloro-bridged diruthenium(II,III) complexes: preparation, properties, and x-ray structure of Ru2Cl5(chiraphos)2 (chiraphos = 2(S),3(S)-bis(diphenylphosphino)butane)
Ian S. Thorburn, Steven J. Rettig, and Brian R. James
pp 234 - 240; DOI:
10.1021/ic00222a028
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Characterization of very large polyoxoanions by fast atom bombardment mass spectroscopy (FABMS)
Kenneth S. Suslick, J. Carter Cook, Brian Rapko, Michael W. Droege, and Richard G. Finke
pp 241 - 243; DOI:
10.1021/ic00222a029
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Kinetics of the reaction of palladium(II) with various dienes and the importance of the diene conformation
Jamil K. K. Sarhan, Siew Wan Foong Murray, Hasan M. Asfour, Michael Green, Richard M. Wing, and Miguel Parra-Haake
pp 243 - 244; DOI:
10.1021/ic00222a030
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Issue 3


Convenient synthesis of tris(tetraethylammonium) hexacyanoferrate(III) and its use as an oxidant with tunable redox potential
Pradip K. Mascharak
pp 245 - 247; DOI:
10.1021/ic00223a001
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Delayed fluorescence and triplet-triplet annihilation in a diplatinate(II) pyrophosphite complex
Yuki Tanaka and Tohru Azumi
pp 247 - 248; DOI:
10.1021/ic00223a002
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.pi.-Bond strengths in diphosphenes (HP:PH, H2P:P), phosphinimine, and diimine
Michael W. Schmidt and Mark S. Gordon
pp 248 - 254; DOI:
10.1021/ic00223a003
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Structure and properties of the sulfur dinitride dianion
M. Conti, M. Trsic, and W. G. Laidlaw
pp 254 - 256; DOI:
10.1021/ic00223a004
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Excited-state properties of ruthenium(II) tris chelate complexes containing the ligands 2,2'-bipyridine (bpy) and dipyrido[3,2-c:2',3'-e]pyridazine (taphen)
Alberto Juris, Peter Belser, Francesco Barigelletti, Alex Von Zelewsky, and Vincenzo Balzani
pp 256 - 259; DOI:
10.1021/ic00223a005
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Reaction of tetrakis(acetato)dirhodium with acetamide: crystal and molecular structure of tetrakis(acetamido)diaquadirhodium trihydrate
M. Q. Ahsan, I. Bernal, and John L. Bear
pp 260 - 265; DOI:
10.1021/ic00223a006
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The fate of "active" chromium hydroxide, Cr(OH)3.3H2O, in aqueous suspension. Study of the chemical changes involved in its aging
Leone Spiccia and Werner Marty
pp 266 - 271; DOI:
10.1021/ic00223a007
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A ring expansion reaction of (Me2NCN)(NSCl)2 with Me3SiNSO: preparation of the bicyclic compounds R2NCS3N5 (R = Me, Et, iso-Pr) and x-ray crystal structure of the folded eight-membered ring 1,5-Me2NC(NSN)2SCl
T. Chivers, J. F. Richardson, and N. R. M. Smith
pp 272 - 275; DOI:
10.1021/ic00223a008
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Gas-phase structures of bis(pentafluorothio)difluoromethane and tetrafluoro-1,3-dithietane octafluoride
Krishna D. Gupta, Ruediger Mews, Alfred Waterfeld, Jean'ne M. Shreeve, and Heinz Oberhammer
pp 275 - 278; DOI:
10.1021/ic00223a009
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Ternary carbides Ln2Mn17C3-x (Ln = La, Ce, Pr, Nd, Sm) with filled Th2Zn17 type structure
Guenter Block and Wolfgang Jeitschko
pp 279 - 282; DOI:
10.1021/ic00223a010
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Synthesis and structure of double-metal-layered scandium, yttrium, and zirconium chloride carbides and nitrides, M2Cl2C and M2Cl2N
Shiou Jyh Hwu, Robin P. Ziebarth, Samuel Von Winbush, Jeff E. Ford, and John D. Corbett
pp 283 - 287; DOI:
10.1021/ic00223a011
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Oxidative addition of diphenyl disulfide across a tantalum-tantalum double bond. Preparation and characterization of [TaCl3(Me2S)]2(.mu.-SPh)2
Gordon C. Campbell, Jo Ann M. Canich, F. Albert Cotton, Stan A. Duraj, and James F. Haw
pp 287 - 290; DOI:
10.1021/ic00223a012
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Synthesis and reactivity of hydroxo-bridged binuclear ethylenediamine complexes of iridium(III) and the x-ray crystal structure of [aquabis(ethylenediamine)iridium(III)](.mu.-hydroxo)hydroxobis(ethylenediamine)iridium(III) dithionate perchlorate hydrate
Frode Galsboel, Sine Larsen, Birgitte Rasmussen, and Johan Springborg
pp 290 - 297; DOI:
10.1021/ic00223a013
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Synthesis, structure, and structural dynamics of a remarkably crowded rhodium(I) dimer: [Rh2((Me2PCH2)2PMe)2(CO)2][B(C6H5)4]2
Alan L. Balch, Marilyn M. Olmstead, and Douglas E. Oram
pp 298 - 303; DOI:
10.1021/ic00223a014
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Proton nuclear magnetic resonance studies of iron(III) porphyrin complexes with axial aryl ligands
Alan L. Balch and Mark W. Renner
pp 303 - 307; DOI:
10.1021/ic00223a015
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Resonance Raman spectroscopic evidence for perturbation of vinyl modes in copper(I)-protoheme .pi.-complexes
Scott S. Sibbett, Thomas M. Loehr, and James K. Hurst
pp 307 - 313; DOI:
10.1021/ic00223a016
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Structural dependence of an electron-transfer process: nature of the products of one-electron oxidation of the lacunar cyclidene complexes of nickel(II) and cobalt(II)
Madhav Y. Chavan, Thomas J. Meade, Daryle H. Busch, and Theodore Kuwana
pp 314 - 321; DOI:
10.1021/ic00223a017
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Complexation of divalent and trivalent nickel and copper ions by rigid and flexible dioxo tetraaza macrocycles
Luigi Fabbrizzi, Thomas A. Kaden, Angelo Perotti, Barbara Seghi, and Liselotte Siegfried
pp 321 - 327; DOI:
10.1021/ic00223a018
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Gallium(III), aluminum(III), and zinc(II) pyridoxal 5'-phosphate catalyzed transamination and dephosphonylation of 2-amino-3-phosphonopropionic acid
Bruno Szpoganicz and Arthur E. Martell
pp 327 - 332; DOI:
10.1021/ic00223a019
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Reactions of auranofin and chloro(triethylphosphine)gold with bovine serum albumin
Mary T. Carlock, C. Frank Shaw, M. K. Eidsness, J. W. Watkins, and R. C. Elder
pp 333 - 339; DOI:
10.1021/ic00223a020
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Kinetics and mechanism of the reduction of rhodium(III) complexes Rh(H2O)5X2+ by chromium(2+)
Elaine F. Hills, Monika Moszner, and A. Geoffrey Sykes
pp 339 - 341; DOI:
10.1021/ic00223a021
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Mechanism of electron transfer to pentaammine(pyridine)cobalt(III) complexes by aliphatic radicals, hexaaquovanadium(II), and hexaammineruthenium(II) ions
Andreja Bakac, Vjera Butkovic, James H. Espenson, Radovan Marcec, and Matko Orhanovic
pp 341 - 345; DOI:
10.1021/ic00223a022
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A high-valent dioxoruthenium(VI) complex of 2,2'-bipyridine (bpy)-preparation and characterization of trans-bis(2,2'-bipyridine)dioxoruthenium(2+)
Chi Ming Che, Kwok Yin Wong, Wai Ho Leung, and Chung Kwong Poon
pp 345 - 348; DOI:
10.1021/ic00223a023
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Preparation, characterization, and chemistry of activated cobalt
Gary L. Rochfort and Reuben D. Rieke
pp 348 - 355; DOI:
10.1021/ic00223a024
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Potential lanthanide ion selective reagents. 3. Metal complex formation with 1,7-diaza-4,10,13-trioxacyclopentadecane-N,N'-diacetic acid
C. Allen Chang and Ven O. Ochaya
pp 355 - 358; DOI:
10.1021/ic00223a025
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Preparation of phosphorus-nitrogen-hydrogen and phosphorus-phosphorus compounds from a silylated amino(methylene)phosphine
Bei Li Li and Robert H. Neilson
pp 358 - 360; DOI:
10.1021/ic00223a026
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Chemistry of [bis(trimethylsilyl)amino]-tert-butylchloroborane: synthesis of new diborylamines and (borylamino)phosphines
Bei Li Li and Robert H. Neilson
pp 361 - 364; DOI:
10.1021/ic00223a027
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Reactions of boron hydrides with the iminium salt [Me2N:CH2]I. Synthesis and characterization of 1-X-.mu.-(Me2NCH2)B5H7 (X = H, Et, Br), a new class of bridge-substituted pentaborane derivatives
Donald F. Gaines and Darrell E. Coons
pp 364 - 367; DOI:
10.1021/ic00223a028
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Pentaborane(9) as a source for higher boron hydride systems. A new synthesis of nido-5,6-dimethyl-5,6-dicarbaoctaborane(10)
Steven H. Lawrence, Joseph R. Wermer, Simon K. Boocock, Michael A. Banks, Phillip C. Keller, and Sheldon G. Shore
pp 367 - 372; DOI:
10.1021/ic00223a029
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Methylpentaborane(11): a mixture of isomers
J. H. Osborne, R. C. P. Hill, and D. M. Ritter
pp 372 - 376; DOI:
10.1021/ic00223a030
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Synthesis and reactions of substituted alkyl trifluoromethyl ethers
Wan Ahmad Kamil, Fritz Haspel-Hentrich, and Jeanne M. Shreeve
pp 376 - 380; DOI:
10.1021/ic00223a031
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Kinetics and mechanism of the substitution reactions of the pentacyanoaquoruthenate(II) ion with nitrogen heterocycles in aqueous media
J. Mark A. Hoddenbagh and Donal H. Macartney
pp 380 - 383; DOI:
10.1021/ic00223a032
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Macrobicyclic chromium(III) hexaamine complexes
Peter Comba, Inge I. Creaser, Lawrence R. Gahan, Jack M. Harrowfield, Geoffrey A. Lawrance, Lisandra L. Martin, Albert W. H. Mau, Alan M. Sargeson, Wolfgang H. F. Sasse, and Michael R. Snow
pp 384 - 389; DOI:
10.1021/ic00223a033
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Nature of intervalence charge-transfer bands in Prussian blues
Kingo Itaya and Isamu Uchida
pp 389 - 392; DOI:
10.1021/ic00223a034
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Reaction of metal complexes with carbohydrates: nickel(II) complexes containing N-glycosides derived from a sugar and .beta.-alanine
Taro Tsubomura, Shigenobu Yano, and Sadao Yoshikawa
pp 392 - 394; DOI:
10.1021/ic00223a035
PDF
Crystal and molecular structure of bis[N-[2-(4-imidazolyl)ethyl]salicylaldiminato]iron(III) hexafluorophosphate ethanol solvate: a model for iron(III) sites with tyrosine and histidine ligands in proteins
J. C. Davis, W. J. Kung, and B. A. Averill
pp 394 - 396; DOI:
10.1021/ic00223a036
PDF
pH-Dependent metal ion selectivity by a crown ether carboxylic acid
C. Allen Chang, Jen Twu, and Richard A. Bartsch
pp 396 - 398; DOI:
10.1021/ic00223a037
PDF
Magnetic coupling in a linear-chain copper(II)-imidazolate compound. Mechanism of the exchange interaction through bridging imidazolate ligands
A. Bencini, C. Benelli, D. Gatteschi, and C. Zanchini
pp 398 - 400; DOI:
10.1021/ic00223a038
PDF

Issue 4


Synthesis, electrical properties, and crystal structure of the first organic metal-solid electrolyte hybrid: (BEDT-TTF)3AgxI8 ( x .apprx. 6.4)
Urs Geiser, Hau H. Wang, Karen M. Donega, Benjamin A. Anderson, Jack M. Williams, and James F. Kwak
pp 401 - 402; DOI:
10.1021/ic00224a001
PDF
Molecular structure of a nickel(II) complex with phenolate appended cyclam
Yoichi Iitaka, Tohru Koike, and Eiichi Kimura
pp 402 - 404; DOI:
10.1021/ic00224a002
PDF
Ferraborane cluster chemistry: reactions of [(.mu.-H)Fe3(CO)9BH3]- with Lewis bases leading to substitution via hydrogen elimination or to cluster degradation
Catherine E. Housecroft and Thomas P. Fehlner
pp 404 - 405; DOI:
10.1021/ic00224a003
PDF
The structural characterization of two isomeric hydrazido(2-) intermediates in the conversion of molybdenum-bound dinitrogen to ammonia and hydrazine
Kassu Gebreyes, Jon Zubieta, T. Adrian George, Lenore M. Koczon, and Robert C. Tisdale
pp 405 - 407; DOI:
10.1021/ic00224a004
PDF
Facile substitution of ammonia ligands in a diplatinum(III) complex of 1-methyluracil
Bernhard Lippert, Helmut Schoellhorn, and Ulf Thewalt
pp 407 - 408; DOI:
10.1021/ic00224a005
PDF
Binuclear platinum diphosphite complexes: x-ray crystal structures of K4[Pt2(pop)4Cl].3H2O and K4[Pt2(pop)4Br2].2H2O
Robin J. H. Clark, Mohamedally Kurmoo, Helen M. Dawes, and Michael B. Hursthouse
pp 409 - 412; DOI:
10.1021/ic00224a006
PDF
Synthesis, characterization, structure, and magnetic properties of the novel trinuclear copper(II) hydroxo complex [(AE)3Cu3OH](ClO4)2 (AEH = 7-amino-4-methyl-5-aza-3-hepten-2-one)
Jean Pierre Costes, Francoise Dahan, and Jean Pierre Laurent
pp 413 - 416; DOI:
10.1021/ic00224a007
PDF
Neutron scattering and optical study of the magnetic properties of the two-dimensional ionic rubidium chromium bromide chloride ferromagnets Rb2CrCl3Br and Rb2CrCl2Br2
Steven T. Bramwell, Peter Day, Michael T. Hutchings, Jonathan R. G. Thorne, and Dick Visser
pp 417 - 421; DOI:
10.1021/ic00224a008
PDF
Preparation and x-ray crystal structure of pentaiodine(1+) hexafluoroarsenate(1-) and electronic structure of the pentaiodine(1+) cation
Allen Apblett, Friedrich Grein, James P. Johnson, Jack Passmore, and Peter S. White
pp 422 - 426; DOI:
10.1021/ic00224a009
PDF
Chromium oxide trifluoride (CrOF3). Preparation and crystal structure
Mary McHughes, Roger D. Willett, H. B. Davis, and G. L. Gard
pp 426 - 427; DOI:
10.1021/ic00224a010
PDF
Synthesis and structural systematics of ethane-1,2-dithiolato complexes
C. Pulla Rao, J. R. Dorfman, and R. H. Holm
pp 428 - 439; DOI:
10.1021/ic00224a011
PDF
Interactions in CuIICuIICuII, CuIIZnIICuII, and CuIINiIICuII trinuclear species. Crystal structure of bis(N,N'-bis(3-aminopropyl)oxamido)tricopper(II) perchlorate
Yves Journaux, Jorunn Sletten, and Olivier Kahn
pp 439 - 447; DOI:
10.1021/ic00224a012
PDF
Catechol-quinone redox series involving bis(bipyridine)ruthenium(II) and tetrakis(pyridine)ruthenium(II)
Masaaki Haga, Elaine S. Dodsworth, and A. B. P. Lever
pp 447 - 453; DOI:
10.1021/ic00224a013
PDF
Copper complexes of a flexible binucleating ligand. Syntheses and spectroscopic, thermodynamic, and kinetic studies
Marie Therese Youinou, John A. Osborn, Jean Paul Collin, and Philippe Lagrange
pp 453 - 461; DOI:
10.1021/ic00224a014
PDF
Copper(I)-phenoxide complexes: synthesis and ligand-induced transformations of the copper(I)-phenoxo functionality
Paolo Fiaschi, Carlo Floriani, Marco Pasquali, Angiola Chiesi-Villa, and Carlo Guastini
pp 462 - 469; DOI:
10.1021/ic00224a015
PDF
Vanadyl ion EPR as a noninvasive probe of pH in intact vanadocytes from Ascidia ceratodes
Patrick Frank, Robert M. K. Carlson, and Keith O. Hodgson
pp 470 - 478; DOI:
10.1021/ic00224a016
PDF
.sigma.-Bonded organochromium(III) complexes. 3. Decomposition in acid solution of some chromium(III) complexes containing pyridylmethyl and polydentate amine ligands
Karen Crouse and Lai Yoong Goh
pp 478 - 484; DOI:
10.1021/ic00224a017
PDF
Hydrolysis of coordinated trifluoromethanesulfonate from cobalt(III), rhodium(III), iridium(III) and chromium(III) pentaamines
Neville J. Curtis, Geoffrey A. Lawrance, Peter A. Lay, and Alan M. Sargeson
pp 484 - 488; DOI:
10.1021/ic00224a018
PDF
Early stages of the hydrolysis of chromium(III) in aqueous solution. 3. Kinetics of dimerization of the deprotonated aqua ion
Francois P. Rotzinger, Hans Stuenzi, and Werner Marty
pp 489 - 495; DOI:
10.1021/ic00224a019
PDF
Syntheses and reactions of polyfluoroalkyl fluorosulfates
Tingji Huang and Jean'ne M. Shreeve
pp 496 - 498; DOI:
10.1021/ic00224a020
PDF
Charge-transfer and electron-transfer properties of d6 metal complexes with .mu.-pyrazine. Mononuclear and binuclear manganese(I) compounds
Renate Gross and Wolfgang Kaim
pp 498 - 506; DOI:
10.1021/ic00224a021
PDF
Chemical applications of topology and group theory. 20. Eight-vertex polyhedra and their rearrangements
R. B. King
pp 506 - 510; DOI:
10.1021/ic00224a022
PDF
Electronic structure of bimetallic "flyover-bridge" derivatives. UV-PES and ab initio study of [cyclic] Fe2(CO)6[R-C2-R)2CO] and [cyclic] Ru2(CO)6[(R-C2-R)2CO] (R = C2H5)
M. Casarin, D. Ajo, A. Vittadini, G. Granozzi, R. Bertoncello, and D. Osella
pp 511 - 514; DOI:
10.1021/ic00224a023
PDF
Cadmium-113 nuclear magnetic resonance spectroscopic study of mixed-ligand tetranuclear clusters of the type [Cd4(EPh)x(E'R)10-x]2- and of the mixed-metal clusters [CdxZn4-x(SPh)10]2-
Philip A. W. Dean and Jagadese J. Vittal
pp 514 - 519; DOI:
10.1021/ic00224a024
PDF
EPR spectrum of tetragonally compressed hexafluorocuprate(4-): ligand and metal hyperfine parameters
Michael A. Hitchman, R. G. McDonald, and D. Reinen
pp 519 - 522; DOI:
10.1021/ic00224a025
PDF
Redox reactivity of photogenerated pentacarbonylchromium species: formation of [Cr(III)(o-semiquinone)3] complexes
Antonin Vlcek
pp 522 - 526; DOI:
10.1021/ic00224a026
PDF
Resonance Raman spectroscopy of the lowest excited state of derivatives of tris(2,2'-bipyridine)ruthenium(II): substituent effects on electron localization in mixed-ligand complexes
Patricia A. Mabrouk and Mark S. Wrighton
pp 526 - 531; DOI:
10.1021/ic00224a027
PDF
Potential dependence of the stretching frequency of carbon monoxide bound to the surface of platinum dispersed in an electrode-confined redox polymer
Jean Francois Andre and Mark S. Wrighton
pp 532 - 535; DOI:
10.1021/ic00224a028
PDF
Kinetics and mechanism of the reaction of dioxochromium(2+) with hydrazinium ions in aqueous acidic solutions
Suzanne L. Bruhn, Andreja Bakac, and James H. Espenson
pp 535 - 538; DOI:
10.1021/ic00224a029
PDF
Reaction between permanganate ion and hydrogen peroxide: kinetics and mechanism of the initial phase of the reaction
Reuben H. Simoyi, Patrick De Kepper, Irving R. Epstein, and Kenneth Kustin
pp 538 - 542; DOI:
10.1021/ic00224a030
PDF
Synthesis, characterization, and x-ray structural determinations of technetium(V)-oxo-tetradentate amine oxime complexes
Silva Jurisson, E. O. Schlemper, D. E. Troutner, L. R. Canning, D. P. Nowotnik, and R. D. Neirinckx
pp 543 - 549; DOI:
10.1021/ic00224a031
PDF
Hydroquinone as a proton donor in ambient-temperature chloroaluminate ionic liquids: reaction with chloride ion
Merek Lipsztajn, Saeed Sahami, and Robert A. Osteryoung
pp 549 - 551; DOI:
10.1021/ic00224a032
PDF
Electrochemical and structural studies of nickel(II) complexes of N-alkylated cyclam ligands: x-ray structures of trans-[Ni(C14H32N4)(OH2)2]Cl2.2H2O and [Ni(C14H32N4)](O3SCF3)2
E. Kent Barefield, Gary M. Freeman, and Donald G. Van Derveer
pp 552 - 558; DOI:
10.1021/ic00224a033
PDF
Magnetic properties and structural characterizations of dichloro(2,5-dithiahexane)copper(II) and dichloro(4,7-dithiadecane)copper(II): observation of Heisenberg alternating-chain magnetism
William E. Hatfield, Leonard W. Ter Haar, Marilyn M. Olmstead, and W. Kenneth Musker
pp 558 - 563; DOI:
10.1021/ic00224a034
PDF
The XeN(SO2F)2+ and F[XeN(SO2F)2+ cations: synthesis and x-ray structure of XeN(SO2F)2+Sb3F16- and Raman and multinuclear magnetic resonance studies of the AsF6- and Sb3F16- compounds
Romolo Faggiani, Dietmar K. Kennepohl, Colin J. L. Lock, and Gary J. Schrobilgen
pp 563 - 571; DOI:
10.1021/ic00224a035
PDF
Crystal and molecular structure and magnetic properties of a trinuclear complex containing exchange-coupled GdCu2 species
A. Bencini, C. Benelli, A. Caneschi, A. Dei, and D. Gatteschi
pp 572 - 575; DOI:
10.1021/ic00224a036
PDF
Dicoordination and tricoordination at phosphorus. Ab initio study of bonding in bis(imino)phosphoranes and related compounds
Wolfgang W. Schoeller and Cornelia Lerch
pp 576 - 580; DOI:
10.1021/ic00224a037
PDF
Oligosilastyrene-supported bis(arene)metal and -dimetal complexes from metal vapor synthesis
Geoffrey A. Ozin, Mark P. Andrews, and Robert West
pp 580 - 582; DOI:
10.1021/ic00224a038
PDF
Pressure effects in scalar coupling in hexaaquocobalt(2+) and high spin-low spin equilibria in 1,4,8,11-tetraazaundecanenickel(II) studied by oxygen-17 nuclear magnetic resonance
Roger M. Nielson, Harold W. Dodgen, John P. Hunt, and Scot E. Wherland
pp 582 - 583; DOI:
10.1021/ic00224a039
PDF
Solid-state carbon-13 NMR probe for organotin(IV) structural polymorphism
Thomas P. Lockhart and William F. Manders
pp 583 - 585; DOI:
10.1021/ic00224a040
PDF
Complexes of rare-earth elements with 1,3-diamino-2-hydroxypropane-N,N,N',N'-tetraacetic acid
Jack E. Powell, Daren R. Ling, and Pui Kwan Tse
pp 585 - 586; DOI:
10.1021/ic00224a041
PDF
Effect of changes in the ligand's backbone moiety on formation constants of 1:1 nickel, copper, zinc, and cadmium chelates
J. E. Powell, D. R. Ling, and P. K. Tse
pp 587 - 588; DOI:
10.1021/ic00224a042
PDF

Issue 5


Synthesis of new tripod ligands providing a phenolate donor. Structure of a stable monomeric copper(I) phenolate complex
Thomas N. Sorrell, A. S. Borovik, and Chien Chang Shen
pp 589 - 590; DOI:
10.1021/ic00225a001
PDF
Relationship of adduct formation to bimolecular reductive elimination from rhodium polyhydrides
Rolf L. Geerts, John C. Huffman, and Kenneth G. Caulton
pp 590 - 591; DOI:
10.1021/ic00225a002
PDF
Mixed platinum-rhodium carbonyl clusters. Synthesis, reactivity, and chemical characterization of the [PtRh8(.mu.3-CO)3(.mu.-CO)9(CO)7]2- anion and x-ray crystal structure of its tetraethylammonium salt
Alessandro Fumagalli, Secondo Martinengo, Gianfranco Ciani, and Giorgio Marturano
pp 592 - 595; DOI:
10.1021/ic00225a003
PDF
Bis((diphenylphosphino)(diethylphosphino)ethane)copper(1+) chloride: a chelated copper(I) complex with tetrahedral stereochemistry. Rate of inversion compared with those of isostructural silver(I) and gold(I) complexes
S. J. Berners Price, C. Brevard, A. Pagelot, and P. J. Sadler
pp 596 - 599; DOI:
10.1021/ic00225a004
PDF
Pentacoordinated molecules. 63. Distortion coordinate for nonrigid five-coordinated germanium. Synthesis and molecular structure of spirocyclic anionic methylgermanates varying in ring composition
Robert R. Holmes, Roberta O. Day, Arjun C. Sau, and Joan M. Holmes
pp 600 - 606; DOI:
10.1021/ic00225a005
PDF
Pentacoordinated molecules. 64. Synthesis and molecular structure of five-coordinated phenyl-substituted anionic germanium(IV) complexes. Influence of the central atom on geometry
Robert R. Holmes, Roberta O. Day, Arjun C. Sau, Charles A. Poutasse, and Joan M. Holmes
pp 607 - 611; DOI:
10.1021/ic00225a006
PDF
Synthesis and characterization of palladium(II) and platinum(II) complexes of Me3MCH2SeR (M = Si, Ge; R = Me, Ph) and crystal structures of trans-(Me3SiCH2SeMe)2PdCl2 and trans-(Me3GeCH2SeMe)2PtCl2
Raj K. Chadha, Jaafar M. Chehayber, and John E. Drake
pp 611 - 615; DOI:
10.1021/ic00225a007
PDF
Phosphorus-31 NMR studies and x-ray structures of five-coordinate cobalt(I) and nickel(II) complexes of tris(2-(diphenylphosphino)ethyl)phosphine
William H. Hohman, Dennis J. Kountz, and Devon W. Meek
pp 616 - 623; DOI:
10.1021/ic00225a008
PDF
Carbon-13 and proton relaxation in paramagnetic complexes of amino acids. Structure and dynamics of copper(II)-L-histidine (1:2) in aqueous solution
Bernard Henry, Jean Claude Boubel, and Jean Jacques Delpuech
pp 623 - 631; DOI:
10.1021/ic00225a009
PDF
Preparation and characterization of pentanuclear molybdenum halide clusters
Thomas C. Zietlow and Harry B. Gray
pp 631 - 634; DOI:
10.1021/ic00225a010
PDF
(CH3C5H4)2V2S4 as an organometallic ligand: preparation of iron, cobalt, nickel, and iridium derivatives and structures of a V4Ni cluster and three V2Fe clusters
C. Mark Bolinger, Timothy D. Weatherill, Thomas B. Rauchfuss, Arnold L. Rheingold, Cynthia S. Day, and Scott R. Wilson
pp 634 - 643; DOI:
10.1021/ic00225a011
PDF
Effects of reactant ionic charges and nonlocal dielectric screening on electron transfer between bis(terpyridine)cobalt(II) and tris(phenanthroline) tris(bipyridine) and analogous, electrically neutral sulfonated cobalt(III) complexes
A. M. Kjaer and J. Ulstrup
pp 644 - 651; DOI:
10.1021/ic00225a012
PDF
Kinetics of the reaction of titanium(III) with (3-cyano-2,4-pentanedionato-N)pentaamminecobalt(III): intramolecular electron transfer between cobalt(III) and titanium(III)
Robert J. Balahura and A. Johnston
pp 652 - 656; DOI:
10.1021/ic00225a013
PDF
Oxidation-reduction and the electrocatalytic ligand substitution of tetracobalt clusters
M. G. Richmond and J. K. Kochi
pp 656 - 665; DOI:
10.1021/ic00225a014
PDF
Ruthenium(III) chloride in aqueous solution: electrochemical and spectral studies
M. M. Taqui Khan, G. Ramachandraiah, and A. Prakash Rao
pp 665 - 670; DOI:
10.1021/ic00225a015
PDF
Formation of actinide hexafluorides at ambient temperatures with krypton difluoride
L. B. Asprey, P. G. Eller, and Scott A. Kinkead
pp 670 - 672; DOI:
10.1021/ic00225a016
PDF
Photolysis of Group 6 metal hexacarbonyl solutions containing diimine ligands. Spectral characterization and reaction kinetics of a photoproduced intermediate, monodentate M(CO)5(diimine)
Mark J. Schadt and Alistair J. Lees
pp 672 - 677; DOI:
10.1021/ic00225a017
PDF
Nitroxyl adducts of copper(II) trihaloacetates. Diamagnetic copper(II) complexes with a novel dimeric structure
Leigh C. Porter, Michael H. Dickman, and Robert J. Doedens
pp 678 - 684; DOI:
10.1021/ic00225a018
PDF
Binding of Pt(NH3)32+ to nucleic acid bases
Harold Basch, M. Krauss, W. J. Stevens, and Drora Cohen
pp 684 - 688; DOI:
10.1021/ic00225a019
PDF
Azolate complexes of nitrosyl(protoporphyrin IX dimethyl esterato)iron(II)
T. Yoshimura
pp 688 - 691; DOI:
10.1021/ic00225a020
PDF
Kinetics of ternary complex formation: the (adenosine 5'-triphosphato)nickel(II) + 2,2'-bipyridine system
K. J. Butenhof, D. Cochenour, J. L. Banyasz, and J. E. Stuehr
pp 691 - 696; DOI:
10.1021/ic00225a021
PDF
Resonance Raman spectra of rubredoxin: new assignments and vibrational coupling mechanism from iron-54/iron-56 isotope shifts and variable-wavelength excitation
Roman S. Czernuszewicz, Jean LeGall, Isabel Moura, and Thomas G. Spiro
pp 696 - 700; DOI:
10.1021/ic00225a022
PDF
EXAFS study of chromium ions in the mixed-solvent system of formamide and ammonium formate
Michihiro Miyake, Nobuhiro Nakagawa, Hiroyuki Ohyanagi, and Takashi Suzuki
pp 700 - 703; DOI:
10.1021/ic00225a023
PDF
High-valent Schiff-base complexes of osmium. X-ray crystal structure of trans-bis(benzenethiolato)[N,N'-ethylenebis(salicylideneaminoato)]osmium(IV)
Chi Ming Che, Wing Kin Cheng, and Thomas C. W. Mak
pp 703 - 706; DOI:
10.1021/ic00225a024
PDF
Effects of optical density, extinction coefficient, and window area on quantum yields: application to mechanistic problems in organometallic photochemistry
Alan S. Goldman and David R. Tyler
pp 706 - 708; DOI:
10.1021/ic00225a025
PDF
Kinetics of the ligand substitution reactions of a labilized chromium(III) complex, [(NH3)5Co{(edta)Cr(H2O)}]2+
Hiroshi Ogino, Akihiko Masuko, Setsuo Ito, Naoko Miura, and Makoto Shimura
pp 708 - 710; DOI:
10.1021/ic00225a026
PDF
Reactions of coordinated molecules. 45. Identification of another isomer of (ferra-.beta.-diketonato)difluoroboron complexes
D. Afzal, P. G. Lenhert, C. M. Lukehart, and R. Srinivasan
pp 710 - 712; DOI:
10.1021/ic00225a027
PDF
First example of prototropism in iminobis(phosphines) induced by phosphorus alkylation
Anne Marie Caminade, Edgar Ocando, Jean Pierre Majoral, Michel Cristante, and Guy Bertrand
pp 712 - 714; DOI:
10.1021/ic00225a028
PDF

Issue 6


Evidence for fluxionality in solid tetracobalt dodecacarbonyl
Brian E. Hanson and Edward C. Lisic
pp 715 - 716; DOI:
10.1021/ic00226a001
PDF
Cobalt(II)-facilitated transport of dioxygen in a polystyrene membrane
Russell S. Drago and Kenneth J. Balkus
pp 716 - 718; DOI:
10.1021/ic00226a002
PDF
Rhodium-carbon bond formation by an electrochemically generated monomeric rhodium(II) porphyrin species
J. E. Anderson, C. L. Yao, and K. M. Kadish
pp 718 - 719; DOI:
10.1021/ic00226a003
PDF
Multinuclear NMR study of reactions of methylphosphonic acid, CH3PO3H2, and (aminoalkyl)phosphonic acids, NH2(CH2)nPO3H2 (n = 1-3), with the cis-diamminediaquaplatinum(II) cation and cis-diamminedihydroxoplatinum(II)
Trevor G. Appleton, John R. Hall, and Ian J. McMahon
pp 720 - 725; DOI:
10.1021/ic00226a004
PDF
NMR spectra of iminobis(methylenephosphonic acid), HN(CH2PO3H2)2, and related ligands and of their complexes with platinum(II)
Trevor G. Appleton, John R. Hall, and Ian J. McMahon
pp 726 - 734; DOI:
10.1021/ic00226a005
PDF
Ternary metal complexes of anionic and neutral pyridoxine (vitamin B6) with 2,2'-bipyridine. Syntheses and x-ray structures of (pyridoxinato)bis(2,2'-bipyridyl)cobalt(III) perchlorate and chloro(2,2'-bipyridyl)(pyridoxine)copper(II) perchlorate hydrate
S. P. Sudhakara Rao, K. I. Varughese, and H. Manohar
pp 734 - 740; DOI:
10.1021/ic00226a006
PDF
Reactivity of phosphenium ions toward 1,3- and 1,4-dienes
A. H. Cowley, R. A. Kemp, J. G. Lasch, N. C. Norman, C. A. Stewart, B. R. Whittlesey, and T. C. Wright
pp 740 - 749; DOI:
10.1021/ic00226a007
PDF
Redox reactions of chromium tetracarbonyl and tricarbonyl complexes: thermodynamic, kinetic, and catalytic aspects of isomerization in the fac/mer-tricarbonyltris(trimethyl phosphite)chromium(1+/0) system
A. M. Bond, R. Colton, and J. E. Kevekordes
pp 749 - 756; DOI:
10.1021/ic00226a008
PDF
Characterization, structure, and conformations of a dinuclear platinum(I) complex with mixed halide-phosphine ligands trans to the metal-metal bond
Reed J. Blau, James H. Espenson, Sangsoo Kim, and Robert A. Jacobson
pp 757 - 763; DOI:
10.1021/ic00226a009
PDF
Tetramethyldiplatinum(III) (Pt-Pt) complexes with 2-hydroxypyridinato bridging ligands
Daniel P. Bancroft, F. Albert Cotton, Larry R. Falvello, and Willi Schwotzer
pp 763 - 770; DOI:
10.1021/ic00226a010
PDF
Carboxysilanes and -germanes. 5. Copper(II) complexes of carboxysilanes and -germanes: structure and magnetic properties. Crystal structure of tetrakis(.mu.-phenyldimethylsilanecarboxylato)bis[aquocopper(II)]
Omar W. Steward, Richard C. McAfee, Shihchi Chang, Stephen R. Piskor, William J. Schreiber, C. Frederick Jury, Charles E. Taylor, James F. Pletcher, and Cheng San Chen
pp 771 - 777; DOI:
10.1021/ic00226a011
PDF
Preparations, Raman spectra, and crystal structures of (SCl3)(SbCl6), (SeCl3)(SbCl6), (SBr1.2Cl1.8)(SbCl6), (TeCl3)(AlCl4) (triclinic modification), (TeCl3)(SbF6), (TeCl3)(AsF6), and (TeF3)2(SO4)
Beverly H. Christian, Michael J. Collins, Ronald J. Gillespie, and Jeffery F. Sawyer
pp 777 - 788; DOI:
10.1021/ic00226a012
PDF
Crystal structures of (.alpha.,.omega.-diaminoalkane)cadmium(II) tetracyanonickelate(II)-aromatic molecule inclusion compounds. 3. (1,4-Diaminobutane)cadmium(II) tetracyanonickelate(II)-pyrrole (1/1), (1,4-diaminobutane)cadmium(II) tetracyanonickelate(II)-aniline (2/3), and (1,4-diaminobutane)cadmium(II) tetracyanonickelate(II)-N,N-dimethylaniline (1/1)
Shinichi Nishikiori and Toschitake Iwamoto
pp 788 - 794; DOI:
10.1021/ic00226a013
PDF
Crystal and molecular structure of the silver(II) and zinc(II) derivatives of meso-tetraphenylporphyrin. An exploration of crystal-packing effects on bond distance
W. Robert Scheidt, Jalal U. Mondal, C. W. Eigenbrot, Alan Adler, L. J. Radonovich, and J. L. Hoard
pp 795 - 799; DOI:
10.1021/ic00226a014
PDF
Exchange interactions in a "bicapped-cubane" Cu6O8 cluster. Crystal structure and magnetic susceptibility of tetrakis(.mu.3-2-amino-2-methyl-1-propanolato)tetrakis(.mu.-2-amino-2-methyl-1-propanolato)hexacopper(II) perchlorate
Heikki Muhonen, William E. Hatfield, and Jeffrey H. Helms
pp 800 - 805; DOI:
10.1021/ic00226a015
PDF
Structural analysis of the semibridging carbonyl
Robert H. Crabtree and Maryellen Lavin
pp 805 - 812; DOI:
10.1021/ic00226a016
PDF
Solution structure and dynamics of Co2(CO)6(L L) and Co4(CO)8(L L)2 molecules
Edward C. Lisic and Brian E. Hanson
pp 812 - 815; DOI:
10.1021/ic00226a017
PDF
Preparation and characterization of isomers of bis(2-aminoethyl 3-aminopropyl sulfide)cobalt(III) chloride
Morten J. Bjerrum, T. Laier, and Erik Larsen
pp 816 - 821; DOI:
10.1021/ic00226a018
PDF
Preparation and reactivity of monomeric (tolylimido)molybdenum(V) complexes and structure of mer-trichloro-trans-bis(ethyldiphenylphosphine)(p-tolylimido)molybdenum(V), Mo(Ntol)Cl3(EtPh2P)2
C. Y. Chou, John C. Huffman, and Eric A. Maatta
pp 822 - 826; DOI:
10.1021/ic00226a019
PDF
Electrochemical generation and study of labile 19-electron dinitrosylmolybdenum radicals
D. Ballivet-Tkatchenko, A. Boughriet, and C. Bremard
pp 826 - 831; DOI:
10.1021/ic00226a020
PDF
Electrochemistry of niobium(IV) and tantalum(IV) complexes: ligand additivity in d1 octahedral complexes
Bruce E. Bursten, M. R. Green, V. Katovic, J. R. Kirk, and D. Lightner
pp 831 - 834; DOI:
10.1021/ic00226a021
PDF
Redox behaviors of [Fe4S4(SR)4]2- and [Mo2Fe6S8X3(SR)6]3- (R = C6H4-p-n-C8H17; X = SEt, OMe) in aqueous micellar solutions
Koji Tanaka, Makoto Moriya, and Toshio Tanaka
pp 835 - 838; DOI:
10.1021/ic00226a022
PDF
Optical spectra of exchange-coupled manganese(II) pairs in cadmium chloride and cadmium bromide
Paul J. McCarthy and Hans U. Guedel
pp 838 - 842; DOI:
10.1021/ic00226a023
PDF
Crystal and molecular structure of a chiral-specific DNA-binding agent: tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II)
Barry M. Goldstein, Jacqueline K. Barton, and Helen M. Berman
pp 842 - 847; DOI:
10.1021/ic00226a024
PDF
Light-induced excited-spin-state trapping: evidence from variable temperature Fourier transform measurements
R. Herber and L. M. Casson
pp 847 - 852; DOI:
10.1021/ic00226a025
PDF
Synthesis and structures of dinuclear nickel(I) di-tert-butylarsenido complexes: x-ray crystal structures of [Ni(.mu.-tert-Bu2As)(PMe3)]2 (Ni-Ni) and [Ni(.mu.-tert-Bu2As)(CN-p-tol)2]2 (Ni-Ni) (tol = tolyl)
Richard A. Jones and Bruce R. Whittlesey
pp 852 - 856; DOI:
10.1021/ic00226a026
PDF
Spectrophotometric study of copper(II) chloride-trimethyl phosphate solutions. Thermodynamic and spectroscopic properties of copper(II) chloro complexes in nonaqueous solutions
Chisara Amuli, Max Elleb, Jean Meullemeestre, Marie Jose Schwing, and Francois Vierling
pp 856 - 861; DOI:
10.1021/ic00226a027
PDF
Bonding in zinc proto- and mesoporphyrin substituted myoglobin and model compounds studied by resonance Raman spectroscopy
Jehuda Feitelson and Thomas G. Spiro
pp 861 - 865; DOI:
10.1021/ic00226a028
PDF
Intramolecular phosphoryl transfer: chelated phosphoramidate
P. Hendry and A. M. Sargeson
pp 865 - 869; DOI:
10.1021/ic00226a029
PDF
Exchange interaction in multinuclear transition-metal complexes. 8. Structural and magnetic studies on bis(acetato)bis(N-methyl-N'-(5-methoxysalicylidene)-1,3-propanediaminato)dicopper dihydrate, a novel "structural" ladderlike compound with "magnetic" alternating-chain behavior
B. Chiari, J. H. Helms, O. Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 870 - 874; DOI:
10.1021/ic00226a030
PDF
Absolute stabilization energies for molybdenum 4d electrons based on the reference compound tetrakis(dimethylamido)molybdenum(IV)
David B. Beach and William L. Jolly
pp 875 - 876; DOI:
10.1021/ic00226a031
PDF
The oxygen-18 isotope shift in nitrogen-15 NMR spectroscopy. 2. Synthesis of nitrogen-15,oxygen-18-labeled hydroxylamine hydrochloride
Gurusamy Rajendran and Robert L. Van Etten
pp 876 - 878; DOI:
10.1021/ic00226a032
PDF
Correlations of platinum-195-phosphorus-31 coupling constants with platinum-ligand and platinum-platinum bond lengths in platinum(I) dimers and in related platinum(II) complexes
Reed J. Blau and James H. Espenson
pp 878 - 880; DOI:
10.1021/ic00226a033
PDF
Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives
Donald J. Darensbourg, Marcetta Y. Darensbourg, Robert L. Gray, Debra Simmons, and Larry W. Arndt
pp 880 - 882; DOI:
10.1021/ic00226a034
PDF
The next generation of (polyazine)ruthenium(II) complexes
Karen J. Brewer, W. Rorer Murphy, Stanford R. Spurlin, and John D. Petersen
pp 882 - 884; DOI:
10.1021/ic00226a035
PDF

Issue 7


Comparative study of hexacyanocobaltate(3-) and pentacyanohydroxocobaltate(3-). Ab initio analysis of ligand substitution effects
L. G. Vanquickenborne, M. Hendrickx, I. Hyla-Kryspin, and L. Haspeslagh
pp 885 - 892; DOI:
10.1021/ic00227a001
PDF
Structure determination by NMR spectroscopy. Dependence of |2J(119Sn,1H)| on the Me-Sn-Me angle in methyltin(IV) compounds
Thomas P. Lockhart and William F. Manders
pp 892 - 895; DOI:
10.1021/ic00227a002
PDF
EPR of chromium(3+) in tris(acetylacetonato)gallium(III) single crystals
G. Elbers, S. Remme, and G. Lehmann
pp 896 - 897; DOI:
10.1021/ic00227a003
PDF
Effect of titanium-titanium interactions on the electronic spectrum of titanium(II) ions in the layer lattice magnesium chloride
D. R. Wilson, D. H. Brown, and W. E. Smith
pp 898 - 900; DOI:
10.1021/ic00227a004
PDF
Electron-transfer studies on a series of cobalt clathrochelates in acetonitrile
Dan Borchardt and Scot Wherland
pp 901 - 905; DOI:
10.1021/ic00227a005
PDF
Comparison of the electrochemical reduction of pentadentate binucleated nickel(II) and copper(II) compounds in dimethylformamide
Waldemar Mazurek, Alan M. Bond, Maxwell J. O'Connor, and Anthony G. Wedd
pp 906 - 915; DOI:
10.1021/ic00227a006
PDF
Acid decomposition reactions of diperoxo(amine)chromium(IV) complexes
C. K. Ranganathan, T. Ramasami, D. Ramaswamy, and M. Santappa
pp 915 - 920; DOI:
10.1021/ic00227a007
PDF
Studies of phosphazenes. 28. Reactions of pentachloro- and pentafluoro(triphenylphosphazenyl)cyclotriphosphazenes with sodium methoxide. Mechanistic aspects and their implications for nucleophilic displacement at a tetrahedral phosphorus(V) center
K. C. Kumara Swamy and S. S. Krishnamurthy
pp 920 - 928; DOI:
10.1021/ic00227a008
PDF
Spectral characterization and kinetics of formation of hypoiodous acid in aqueous solution
Donald A. Palmer and R. Van Eldik
pp 928 - 931; DOI:
10.1021/ic00227a009
PDF
A convenient general synthesis of trans-[IrCl(CO)(PR3)2]
Mark J. Burk and Robert H. Crabtree
pp 931 - 932; DOI:
10.1021/ic00227a010
PDF
Surface-modified electrodes: oxidative electropolymerization and deposition of Ni[Me4(RBzo)2[14]tetraeneN4] complexes
Cynthia L. Bailey, Robert D. Bereman, D. Paul Rillema, and Robert Nowak
pp 933 - 938; DOI:
10.1021/ic00227a011
PDF
Cascade halide binding by multiprotonated 7,19,30-trioxa-1,4,10,13,16,22,27,33-octaazabicyclo[11.11.11]pentatriacontane (BISTREN) and copper(II) BISTREN cryptates
Ramunas J. Motekaitis, Arthur E. Martell, and Ichiro Murase
pp 938 - 944; DOI:
10.1021/ic00227a012
PDF
Relative stability constants of olefin-rhodium(II) vs. olefin-rhodium(I) coordination as determined by complexation gas chromatography
Volker Schurig
pp 945 - 949; DOI:
10.1021/ic00227a013
PDF
Iron(II) aryldiazene complexes: preparation, characterization, and ligand-substitution reactions with ketones, nitriles, and isocyanides. Crystal structure of the diazene precursor, the new hydride, trans-carbonylhydridotetrakis(triethyl phosphite)iron tetraphenylborate, trans-[FeH(CO){P(OEt)3}4]BPH4
Gabriele Albertin, Stefano Antoniutti, Maurizio Lanfranchi, Giancarlo Pelizzi, and Emilio Bordignon
pp 950 - 957; DOI:
10.1021/ic00227a014
PDF
Synthesis, structure, and platinum-195 NMR solution studies of a reactive binuclear platinum(III) complex: bis(ethylenediamine)nitratonitrobis(2-pyridonato)diplatinum(2+) dinitrate hemihydrate
Thomas V. O'Halloran, Michael M. Roberts, and Stephen J. Lippard
pp 957 - 964; DOI:
10.1021/ic00227a015
PDF
Cadmium-113 NMR of cadmium(II) complexes with ligands containing N-donor atoms. Dependence of the chemical shift upon the ligand basicity, chelate ring size, counteranion, and cadmium concentration
Megumu Munataka, Susumu Kitagawa, and Fujio Yagi
pp 964 - 970; DOI:
10.1021/ic00227a016
PDF
Carbon-13 NMR study of the binding of nitroprusside and hexacyanoferrate(II) to aquocobalamin, vitamin B12a
Anthony R. Butler, Christopher Glidewell, Alexis S. McIntosh, David Reed, and Ian H. Sadler
pp 970 - 973; DOI:
10.1021/ic00227a017
PDF
First definitive demonstration of ortho shielding effects on platinum-195 NMR signals. Dependence of shift on heterocyclic ligand basicity and ortho substituents in four series of complexes with chloro, dimethyl sulfoxide, and pyridine ligands
Luigi G. Marzilli, Yuiko Hayden, and Michael D. Reily
pp 974 - 978; DOI:
10.1021/ic00227a018
PDF
Application of cobalt-59 NMR to cobalt(III) porphyrins. Linear relationship between cobalt-59 and iron-57 chemical shifts
Karen I. Hagen, Catherine M. Schwab, John O. Edwards, and Dwight A. Sweigart
pp 978 - 983; DOI:
10.1021/ic00227a019
PDF
Structure, reactivity, and electrochemistry of free-base .beta.-oxoporphyrins and metallo-.beta.-oxoporphyrins
Alan M. Stolzenberg, Paul A. Glazer, and Bruce M. Foxman
pp 983 - 991; DOI:
10.1021/ic00227a020
PDF
Ligand-addition reactions of indium(III) porphyrins. Reactions of (OEP)InX and (TPP)InX with N-methylimidazole and pyridine
J. L. Cornillon, J. E. Anderson, and K. M. Kadish
pp 991 - 995; DOI:
10.1021/ic00227a021
PDF
Use of tetra-n-butylammonium permanganate for inorganic syntheses in nonaqueous solvents. Preparation and structure of a manganese(III) dimer containing bridging phenoxo oxygen atoms
John B. Vincent, Kirsten Folting, John C. Huffman, and George Christou
pp 996 - 999; DOI:
10.1021/ic00227a022
PDF
Synthesis of tetrapeptide 2iron-2sulfur complexes of Cys-X-Y-Cys segments by a ligand-exchange reaction. Peptide models of iron ferredoxin characterized by electrochemistry and spectroscopy
Satoru Ueno, Norikazu Ueyama, Akira Nakamura, and Tomitake Tukihara
pp 1000 - 1005; DOI:
10.1021/ic00227a023
PDF
Ab initio calculations of the copper(2+)-O2- interaction as a model for the mechanism of copper/zinc superoxide dismutase
M. Rosi, A. Sgamellotti, F. Tarantelli, I. Bertini, and C. Luchinat
pp 1005 - 1008; DOI:
10.1021/ic00227a024
PDF
Determination of the barrier to rotation of the cyclobutadienyl ring in solid tricarbonyl(.eta.-cyclobutadienyl)iron(0), (.eta.-C4H4)Fe(CO)3, from proton spin-lattice relaxation time measurements and vibrational spectra
Pierre D. Harvey, Ian S. Butler, and D. F. R. Gilson
pp 1009 - 1013; DOI:
10.1021/ic00227a025
PDF
Matrix isolation study of the fluoride adduct of oxalyl fluoride: evidence for a fluorine-bridged anion
Bruce S. Ault
pp 1013 - 1015; DOI:
10.1021/ic00227a026
PDF
Preparation and x-ray structures of compounds containing the tetrakis(methylhydroxypyridinato)- and tetrakis(chlorohydroxypyridinato)dipalladium(II) molecules
Daniel P. Bancroft, F. Albert Cotton, Larry R. Falvello, and Willi Schwotzer
pp 1015 - 1021; DOI:
10.1021/ic00227a027
PDF
Reactions of small molecules with tetrachlorotetrakis(triethylphosphine)dirhenium. 1. Structural and spectroscopic studies of several products resulting from the reaction with carbon monoxide
S. Bucknor, F. A. Cotton, L. R. Falvello, A. H. Reid, and C. D. Schmulbach
pp 1021 - 1027; DOI:
10.1021/ic00227a028
PDF
Mononuclear cobalt(II) complexes having alkoxide and amide ligands: synthesis and x-ray crystal structures of [Co(Cl)(OC-tert-Bu3)2.Li(THF)3], [Li(THF)4.5][Co{N(SiMe3)2}(OC-tert-Bu3)2], and [Li{Co(N(SiMe3)2)(OC-tert-Bu3)2}]
Marilyn M. Olmstead, Philip P. Power, and Gary Sigel
pp 1027 - 1033; DOI:
10.1021/ic00227a029
PDF
Syntheses and acid aquation reactions of pentakis(methylamine)cobalt(III) complexes of the neutral ligands urea, dimethyl sulfoxide, dimethylformamide, trimethyl phosphate, and acetonitrile
Neville J. Curtis and Geoffrey A. Lawrance
pp 1033 - 1037; DOI:
10.1021/ic00227a030
PDF
Nuclear magnetic resonance study of solvent exchange on hexakis(N,N-dimethylacetamide)cobalt(II), hexakis(N,N-diethylformamide)cobalt(II), and their nickel(II) analogs. Effect of solvent molecular size on lability
Stephen F. Lincoln, Andrea M. Hounslow, and Anthony N. Boffa
pp 1038 - 1041; DOI:
10.1021/ic00227a031
PDF
Mechanism of reduction of bound nitrite to ammonia
W. Rorer Murphy, Kenneth Takeuchi, Mark H. Barley, and Thomas J. Meyer
pp 1041 - 1053; DOI:
10.1021/ic00227a032
PDF
Structures and energies of diborane(4)
R. Ricki Mohr and William N. Lipscomb
pp 1053 - 1057; DOI:
10.1021/ic00227a033
PDF
Characterization and structure of [H7O3]+[As(cat)3]-.cntdot.p-diox (cat = catecholate, p-diox = p-dioxane)
Brandan A. Borgias, Glenn G. Hardin, and Kenneth N. Raymond
pp 1057 - 1060; DOI:
10.1021/ic00227a034
PDF
Anisotropic exchange in bibridged copper(II) dimers: a topological approach
Marie France Charlot, Yves Journaux, Olivier Kahn, Alessandro Bencini, Dante Gatteschi, and Claudia Zanchini
pp 1060 - 1063; DOI:
10.1021/ic00227a035
PDF
Magnetic properties and crystal structure of a linear-chain copper(II) compound with bridging acetate and oxamidate ligands
A. Bencini, C. Benelli, A. C. Fabretti, G. Franchini, and D. Gatteschi
pp 1063 - 1066; DOI:
10.1021/ic00227a036
PDF
Photochemistry of copper(II)-poly(acrylic acid) complexes: Photogeneration and photolysis of an alkyl-copper intermediate
S. Das and G. Ferraudi
pp 1066 - 1068; DOI:
10.1021/ic00227a037
PDF
Solid-state carbon-13 NMR molecular structure of microcrystalline, polymeric dimethyltin hydrogen phosphate (Me2SnHPO4)
Thomas P. Lockhart and William F. Manders
pp 1068 - 1070; DOI:
10.1021/ic00227a038
PDF
A flash photolytic study of the kinetics and mechanism of the reduction of halocobaloximes by 1-hydroxy-1-methylethyl radicals
Philip Connolly and James H. Espenson
pp 1070 - 1072; DOI:
10.1021/ic00227a039
PDF

Issue 8


Synthesis, characterization, and structure of a novel hexanuclear iron-sulfur-carbonyl cluster, the [Fe6S6(CO)12]2- ion
G. L. Lilley, E. Sinn, and B. A. Averill
pp 1073 - 1075; DOI:
10.1021/ic00228a001
PDF
High-salt and low-salt models for kinked adducts of cis-diamminedichloroplatinum(II) with oligonucleotide duplexes
Jiri Kozelka, Gregory A. Petsko, Gary J. Quigley, and Stephen J. Lippard
pp 1075 - 1077; DOI:
10.1021/ic00228a002
PDF
Triethyloxonium tetrafluoroborate as an ethylating agent in aqueous solution
Gordon J. King, Carlo Gazzola, Robert L. Blakeley, and Burt Zerner
pp 1078 - 1078; DOI:
10.1021/ic00228a003
PDF
Transition-metal hydride bond energies: first and second row
J. L. Elkind and P. B. Armentrout
pp 1078 - 1080; DOI:
10.1021/ic00228a004
PDF
Mononuclear chromium complexes of the tripod ligand (tripod = 1,1,1-[tris((dimethylphosphino)methyl)ethane)
Bruce R. Whittlesley
pp 1080 - 1084; DOI:
10.1021/ic00228a005
PDF
Protonated metal-free salt and manganese complex of a 2,9-dimethyl-3,10-diphenyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene, [14]tetraeneN4, macrocyclic ligand
Brian A. Anderson and Susan C. Jackels
pp 1085 - 1088; DOI:
10.1021/ic00228a006
PDF
Photosubstitution reactions of the ruthenium(II) arene complexes Ru(.eta.6-arene)L32+ (L = ammonia or water) in aqueous solution
Walter Weber and Peter C. Ford
pp 1088 - 1092; DOI:
10.1021/ic00228a007
PDF
The tungsten-tungsten triple bond. 12. Bis(1,3-diaryltriazenido)bis(dimethylamido)diethylditungsten (M.tplbond.M) compounds
M. H. Chisholm, H. T. Chiu, J. C. Huffman, and R. J. Wang
pp 1092 - 1096; DOI:
10.1021/ic00228a008
PDF
Chemistry and catalytic properties of ruthenium and osmium complexes. 2. Synthesis and characterization of new mononuclear and dinuclear complexes with hydride, carboxylate, and phosphine ligands. X-ray crystal and molecular structures of OsBr(OCOMe)(CO)(PPh3)2, RuCl(OCOMe)(CO)(PPh3)2, and [PPh3Me]+[Ru2Cl2(.mu.-Cl)3(CO)2(PPh3)2]-
Roberto A. Sanchez-Delgado, Ulf Thewalt, Norma Valencia, Antida Andriollo, Rosa Linda Marquez-Silva, Jose Puga, Helmut Schoellhorn, Heinz Peter Klein, and Bernardo Fontal
pp 1097 - 1106; DOI:
10.1021/ic00228a009
PDF
Chemistry and catalytic properties of ruthenium and osmium complexes. 3. Development of highly active systems for the homogeneous hydrogenation of aldehydes and ketones
Roberto A. Sanchez-Delgado, Norma Valencia, Rosalinda Marquez-Silva, Antida Andriollo, and Miriam Medina
pp 1106 - 1111; DOI:
10.1021/ic00228a010
PDF
Synthesis of hexanuclear molybdenum cluster alkyl complexes coordinated with trialkylphosphines: crystal structures of trans-[(Mo6Cl8)Cl4{P(n-C4H9)3}2] and all-trans-[(Mo6Cl8)Cl2(C2H5)2{P(n-C4H9)3}2].cntdot.2C6H5CH3
Taro Saito, Masakazu Nishida, Tsuneaki Yamagata, Yuriko Yamagata, and Yoshihiro Yamaguchi
pp 1111 - 1117; DOI:
10.1021/ic00228a011
PDF
Substitution and fragmentation reactions of dibromododecacarbonyltriosmium with phosphines. Structure of dibromodecacarbonylbis(trimethyl phosphite)triosmium
Yu Sen Chen, Sue Lein Wang, Robert A. Jacobson, and Robert J. Angelici
pp 1118 - 1122; DOI:
10.1021/ic00228a012
PDF
Cluster synthesis. 10. Reaction of Os3(CO)10(.mu.3-S) with trimethylamine N-oxide dihydrate. Syntheses and structural characterizations of Os3(CO)8(NMe3)(.mu.-OH)(.mu.3-S)(.mu.-H) and the six-atom-chain cluster Os6(CO)18(.mu.-OH)(.mu.4-S)(.mu.3-S)(.mu.-H)
Richard D. Adams, James E. Babin, and H. S. Kim
pp 1122 - 1127; DOI:
10.1021/ic00228a013
PDF
Synthesis, characterization, and crystal structure of a hexaaza macrocyclic complex of lutetium(III)
G. Bombieri, Franco Benetollo, A. Polo, L. De Cola, D. L. Smailes, and L. M. Vallarino
pp 1127 - 1132; DOI:
10.1021/ic00228a014
PDF
Complex formation in pyrosulfate melts. 2. Calorimetric investigations of the [vanadium pentoxide - potassium pyrosulfate] systems V2O5-K2S2O7, V2O5.K2S2O7-K2SO4, V2O5.2K2S2O7-K2SO4, and V2O5.3K2S2O7-K2SO4 at 430.degree.C
Rasmus Fehrmann, Marcelle Gaune-Escard, and Niels J. Bjerrum
pp 1132 - 1137; DOI:
10.1021/ic00228a015
PDF
Aromatic and antiaromatic thiazyl heterocycles. Comparison of the structural, spectroscopic, and cycloaddition properties of 1,3,2,4-benzodithiadiazine, C6H4S2N2, and 1,3,5,2,4-benzotrithiadiazepine, C6H4S3N2
A. Wallace Cordes, Masashi Hojo, Hans Koenig, Mark C. Noble, Richard T. Oakley, and William T. Pennington
pp 1137 - 1145; DOI:
10.1021/ic00228a016
PDF
Raman and resonance Raman studies of tetraphosphorus triselenide
Gary R. Burns, Joanne R. Rollo, and Robin J. H. Clark
pp 1145 - 1149; DOI:
10.1021/ic00228a017
PDF
X-ray single-crystal structure determination of copper(II), cobalt(II), and nickel(II) complexes of 2,2-bis(2'-pyridyl)- and 2,2-bis(6'-methyl-2'-pyridyl)-1,3-dioxolane
George R. Newkome, Hellen C. R. Taylor, Frank R. Fronczek, and Vinod K. Gupta
pp 1149 - 1154; DOI:
10.1021/ic00228a018
PDF
Axial ligand replacement reactions in tetrakis(.mu.-phosphato)diplatinum(III) complexes: coordination of amine, thioether and thiolate functionalities
Ramadan El-Mehdawi, Frank R. Fronczek, and D. Max Roundhill
pp 1155 - 1159; DOI:
10.1021/ic00228a019
PDF
Heats of reaction of RMo(CO)3C5H5 (R = H, Me, Et) with phosphines and phosphites: thermodynamic study of the carbonyl-insertion reaction
Steven P. Nolan, Ramon Lopez de la Vega, Shakti L. Mukerjee, and Carl D. Hoff
pp 1160 - 1165; DOI:
10.1021/ic00228a020
PDF
Kinetics and equilibria of silver(1+) and lead(2+) cryptates in dimethyl sulfoxide
B. G. Cox, J. Garcia-Rosas, H. Schneider, and Ng Van Troung
pp 1165 - 1168; DOI:
10.1021/ic00228a021
PDF
Kinetics of reduction of plutonium(VI) and neptunium(VI) by sulfide in neutral and alkaline solutions
Kenneth L. Nash, J. M. Cleveland, J. C. Sullivan, and M. Woods
pp 1169 - 1173; DOI:
10.1021/ic00228a022
PDF
Semiexhaustive determination of rate parameters for dissociative axial ligand substitution in 24 ferrous dimethylglyoxime complexes involving 7 different axial ligands
Xuening Chen and Dennis V. Stynes
pp 1173 - 1182; DOI:
10.1021/ic00228a023
PDF
Reactions of dioxygen complexes. Oxidative dehydrogenation of 2-(aminomethyl)pyridine through cobalt dioxygen complex formation
Arup K. Basak and Arthur E. Martell
pp 1182 - 1190; DOI:
10.1021/ic00228a024
PDF
Oxidation of cobalt(II) pentaamine complexes through the formation of dioxygen complex intermediates
Carl J. Raleigh and Arthur E. Martell
pp 1190 - 1195; DOI:
10.1021/ic00228a025
PDF
Luminescence properties of CsNiX3 and CsMg1-xNixX3 (X = Cl, Br)
Christian Reber and Hans U. Guedel
pp 1196 - 1201; DOI:
10.1021/ic00228a026
PDF
Electronic and intramolecular structural localization in conducting organic salts
Sason S. Shaik and Myung Hwan Whangbo
pp 1201 - 1209; DOI:
10.1021/ic00228a027
PDF
Extended x-ray absorption fine structure and powder x-ray diffraction study of iron(3+)chloride oxide intercalated with tetrathiafulvalene and related molecules
S. M. Kauzlarich, B. K. Teo, and B. A. Averill
pp 1209 - 1215; DOI:
10.1021/ic00228a028
PDF
Evidence of the complexation of the antitumor drug bleomycin with cis-[diamminedichloroplatinum] and with palladium derivatives. Physicochemical characteristics, interaction with DNA, and antitumor activity
J. P. Albertini and A. Garnier-Suillerot
pp 1216 - 1221; DOI:
10.1021/ic00228a029
PDF
Preparation, characterization, and reactivity of the early-transition-metal/late-transition-metal heterobimetallic complexes (C5H5)2Zr(.mu.-PPh2)2MLn (M = Ni, Pd, Pt)
Lucio Gelmini and Douglas W. Stephan
pp 1222 - 1225; DOI:
10.1021/ic00228a030
PDF
Factors influencing Jahn-Teller distortions in six-coordinate copper(II) and low-spin nickel(II) complexes
Robert J. Deeth and Michael A. Hitchman
pp 1225 - 1233; DOI:
10.1021/ic00228a031
PDF
Kinetics and mechanism of chloride and bromide substitution of diaquonickel(III) macrocyclic complexes
M. G. Fairbank and A. McAuley
pp 1233 - 1238; DOI:
10.1021/ic00228a032
PDF
Synthesis and tungsten-183 NMR characterization of vanadium-substituted polyoxometalates based on B-type tungstophosphate PW9O349-precursors
Peter J. Domaille and George Watunya
pp 1239 - 1242; DOI:
10.1021/ic00228a033
PDF
Structural characterization of the solvate complexes of the lithium diorganophosphides [{Li(Et2O)PPh2}.infin.], [{Li(THF)2PPh2}.infin.], and [{Li(THF)P(C6H11)2}.infin.]
Ruth A. Bartlett, Marilyn M. Olmstead, and Philip P. Power
pp 1243 - 1247; DOI:
10.1021/ic00228a034
PDF
Preparation and structural dynamics of phosphine-bridge trirhodium chains. Observation of facile bridge/terminal interchange of anionic ligands or carbon monoxide
Alan L. Balch, L. Alan Fossett, Rosalvina R. Guimerans, Marilyn M. Olmstead, Philip E. Reedy, and Fred E. Wood
pp 1248 - 1253; DOI:
10.1021/ic00228a035
PDF
N-acyl isocyanide complexes of iron(II) porphyrins: analogy between the bonding properties of N-acyl isocyanides and carbon monoxide
Maryvonne Le Plouzennec, Arnaud Bondon, Patric Sodano, and Gerard Simonneaux
pp 1254 - 1257; DOI:
10.1021/ic00228a036
PDF
Combined helium I/helium II photoelectron spectroscopic and Hartree-Fock-Slater investigation of electronic structure and bonding in uranium hexamethoxide
B. E. Bursten, M. Casarin, D. E. Ellis, I. Fragala, and T. J. Marks
pp 1257 - 1261; DOI:
10.1021/ic00228a037
PDF
Thermodynamics of azide and thiocyanate binding to bovine copper-zinc superoxide dismutase
David M. Dooley and Michele A. McGuirl
pp 1261 - 1264; DOI:
10.1021/ic00228a038
PDF
Oscillating reactions involving a nickel complex with a 13-membered tetraaza macrocyclic ligand in acidic bromate medium
Jide Xu and Shisheng Ni
pp 1264 - 1268; DOI:
10.1021/ic00228a039
PDF
Kinetics and salt effects for the oxidation of octacyanomolybdate(IV) by peroxydisulfate ions
C. Robert Dennis, Johann G. Leipoldt, Stephen S. Basson, and Abraham J. Van Wyk
pp 1268 - 1270; DOI:
10.1021/ic00228a040
PDF
Syntheses, spectral properties and substitution reactions of M(CO)3(S2CNC4H4)2 (M = Mo, W) complexes containing the electronically unique pyrrole-N-carbodithioate ligand
Richard S. Herrick and Joseph L. Templeton
pp 1270 - 1276; DOI:
10.1021/ic00228a041
PDF
Electrochemical and spectroelectrochemical studies of tetraphenylporphyrinato rhodium(III) acetyl, (TPP)Rh(COCH3)
Karl M. Kadish, J. E. Anderson, C. L. Yao, and R. Guilard
pp 1277 - 1280; DOI:
10.1021/ic00228a042
PDF
Nature of the axial bond between dimethyl sulfoxide and a series of dirhodium complexes
M. Y. Chavan, X. Q. Lin, M. Q. Ahsan, I. Bernal, J. L. Bear, and Karl M. Kadish
pp 1281 - 1288; DOI:
10.1021/ic00228a043
PDF
Corrections and additional insights to the synthesis and characterization of tetramethylammonium superoxide [(Me4N)O2]
Kenneth Yamaguchi, Thomas S. Calderwood, and Donald T. Sawyer
pp 1289 - 1290; DOI:
10.1021/ic00228a044
PDF
Synthesis and structural characterization of methylenebisphosphinic acid, CH2[PH(O)OH]2
Christopher King, D. Max Roundhill, and Frank R. Fronczek
pp 1290 - 1292; DOI:
10.1021/ic00228a045
PDF

Issue 9


Synthesis, stereochemistry, and oxygenation of cobalt(II)-pyridoxal model complexes. A new family of chiral dioxygen carriers
Luigi Casella and Michele Gullotti
pp 1293 - 1303; DOI:
10.1021/ic00229a001
PDF
Structures, hydrogen NMR spectra, and ligand-exchange properties of Costa-type organocobalt B12 models with P-donor ligands
Wallace O. Parker, Nevenka Bresciani-Pahor, Ennio Zangrando, Lucio Randaccio, and Luigi G. Marzilli
pp 1303 - 1309; DOI:
10.1021/ic00229a002
PDF
Complexes of thallium(I) and -(III) containing 1,4,7-triazacyclononane (L) ligands. Kinetics and mechanism of the reduction of [L2TlIII]3+. Crystal structure of (N,N',N"-trimethyl-1,4,7-triazacyclononane)thallium(I) hexafluorophosphate
Karl Wieghardt, Michael Kleine-Boymann, Bernhard Nuber, and Johannes Weiss
pp 1309 - 1313; DOI:
10.1021/ic00229a003
PDF
Complex formation between copper(2+) and 1,N6-ethenoadenosine 5'-triphosphate (.epsilon.-ATP)
Thomas A. Kaden, Kurt H. Scheller, and Helmut Sigel
pp 1313 - 1315; DOI:
10.1021/ic00229a004
PDF
Platinum(II) complexes of (cyanoethyl)phosphines
Mark S. Holt and John H. Nelson
pp 1316 - 1320; DOI:
10.1021/ic00229a005
PDF
Kinetics of aquation of potentially strained chromium(III) complexes containing tetradentate macrocyclic ligands
R. G. Swisher and E. L. Blinn
pp 1320 - 1323; DOI:
10.1021/ic00229a006
PDF
Kinetics and mechanism of the reactions of sulfito complexes in aqueous solution. Formation, aquation, and intramolecular electron-transfer reactions of the trans-aquo(sulfito-O)bis(ethylenediamine)cobalt(III) ion
Abbas A. El-Awady and Gordon M. Harris
pp 1323 - 1329; DOI:
10.1021/ic00229a007
PDF
The basis of aryl substituent effects on charge-transfer absorption intensities
Carol C. Phifer and David R. McMillin
pp 1329 - 1333; DOI:
10.1021/ic00229a008
PDF
Structures and mechanism of multiple ligand substitutions in bicapped tetracobalt clusters
M. G. Richmond and J. K. Kochi
pp 1334 - 1345; DOI:
10.1021/ic00229a009
PDF
Organometallic chemistry of fluorocarbon acids. Synthesis, structure, and solvolysis of a sulfinate-bridged diruthenium dihydride cluster, [(Ph3P)4Ru2(.mu.-H)2(.mu.-CF3SO2)(CO)2][HC(SO2CF3)2]
Allen R. Siedle, R. A. Newmark, and L. H. Pignolet
pp 1345 - 1351; DOI:
10.1021/ic00229a010
PDF
Photophysics and electrochemistry of hexanuclear tungsten halide clusters
Thomas C. Zietlow, Daniel G. Nocera, and Harry B. Gray
pp 1351 - 1353; DOI:
10.1021/ic00229a011
PDF
Emission and photochemistry of M(CO)4(diimine) (M = chromium, molybdenum, tungsten) complexes in room-temperature solution
David M. Manuta and Alistair J. Lees
pp 1354 - 1359; DOI:
10.1021/ic00229a012
PDF
Oxygen-17 nuclear magnetic resonance studies on the acetic acid exchange of manganese(II), iron(II), cobalt(II), nickel(II), and copper(II) perchlorates in acetic acid
Akiharu Hioki, Shigenobu Funahashi, Masao Ishii, and Motoharu Tanaka
pp 1360 - 1364; DOI:
10.1021/ic00229a013
PDF
EPR studies of the electronic structure and dynamic Jahn-Teller effect in cobalt(II) mixed-sandwich compounds
B. L. Ramakrishna, A. K. Salzer, U. Ruppli, J. H. Ammeter, and U. Koelle
pp 1364 - 1368; DOI:
10.1021/ic00229a014
PDF
Crystal structure and EPR/ENDOR study of the nonplanar system bis(tetraphenylarsonium) bis(maleonitriledithiolato)zincate(II) doped with copper(II)
J. Stach, R. Kirmse, J. Sieler, U. Abram, W. Dietzsch, R. Boettcher, L. K. Hansen, H. Vergoossen, M. C. M. Gribnau, and et al.
pp 1369 - 1373; DOI:
10.1021/ic00229a015
PDF
Low-lying electronic energy levels in a series of heterodinuclear complexes containing octahedral nickel(II) and tetrahderal metal(II) (copper, cobalt, and manganese) species
A. Bencini, A. Caneschi, A. Dei, D. Gatteschi, C. Zanchini, and O. Kahn
pp 1374 - 1378; DOI:
10.1021/ic00229a016
PDF
Crystal structure of (azacapten)cobalt(II) diperchlorate and strain energy minimization analyses of the (azacapten)cobalt(III) and (azacapten)cobalt(II) cations (azacapten = 1-methyl-3,13,16-trithia-6,8,10-19-tetraazabicyclo[6.6.6]eicosane)
Trevor W. Hambley and Michael R. Snow
pp 1378 - 1382; DOI:
10.1021/ic00229a017
PDF
A (trimethylphosphine)cobalt(III) complex, Co(NCS)3(PMe3)3. Synthesis from the reaction of nitric oxide with Co(NCS)2(PMe3)2. Crystal and molecular structure
O. Alnaji, Y. Peres, F. Dahan, M. Dartiguenave, and Y. Dartiguenave
pp 1383 - 1386; DOI:
10.1021/ic00229a018
PDF
A strongly chelating bidentate perchlorate. New synthesis route and crystal structure determination of titanium(4+) perchlorate
Mohieddine Fourati, Moncef Chaabouni, Claude Henri Belin, Monique Charbonnel, Jean Louis Pascal, and Jacqueline Potier
pp 1386 - 1390; DOI:
10.1021/ic00229a019
PDF
Correlation among the structural, electronic and magnetic properties of [Fe4(.mu.3-S)3(.mu.3-S2)Cp4]n+ (n = 0-2) clusters at various oxidation states
N. Dupre, P. Auric, H. M. J. Hendriks, and J. Jordanov
pp 1391 - 1396; DOI:
10.1021/ic00229a020
PDF
X-ray crystal structure and structural dynamics of [Ir3{.mu.-(Ph2PCH2)2AsPh}2(.mu.-CO)2(CO)2(.mu.-Cl)Cl]+ and related rhodium complexes
Alan L. Balch, L. Alan Fossett, Rosalvina R. Guimerans, Marilyn M. Olmstead, and Philip E. Reedy
pp 1397 - 1404; DOI:
10.1021/ic00229a021
PDF
Coordination chemistry of the lamellar MPS3 materials: metal-ligand cleavage as the source of an unusual "cation-transfer" intercalation process
Rene Clement, Odile Garnier, and Jocelyne Jegoudez
pp 1404 - 1409; DOI:
10.1021/ic00229a022
PDF
Bonding mode of axial thiocyanate ligands of iron macrocyclic complexes. Crystal structure of [Fe(TIM)(SCN)2]PF6
M. J. Maroney, E. O. Fey, D. A. Baldwin, R. E. Stenkamp, L. H. Jensen, and N. J. Rose
pp 1409 - 1414; DOI:
10.1021/ic00229a023
PDF
Crystal structure and iodine-127 Moessbauer spectrum of diphenyliodonium-2-carboxylate hydrate, C13H9IO2.cntdot.H2O: secondary vs. hydrogen bonding
Raymond J. Batchelor, Thomas Birchall, and Jeffery F. Sawyer
pp 1415 - 1420; DOI:
10.1021/ic00229a024
PDF
Manganese(II) complexes of polydentate Schiff bases. 1. Synthesis, characterization, magnetic properties, and molecular structure
Bouchra Mabad, Patrick Cassoux, Jean Pierre Tuchagues, and David N. Hendrickson
pp 1420 - 1431; DOI:
10.1021/ic00229a025
PDF
Atom transfer and chelate fragmentation reactions of bis(cyclopentadienyl)titanium thiophosphoryls. Part 2
Gregg A. Zank and Thomas B. Rauchfuss
pp 1431 - 1435; DOI:
10.1021/ic00229a026
PDF
Thermodynamic studies on equilibria between the branched hexaamine N,N,N',N'-tetrakis(3-aminopropyl)ethylenediamine (tapen) and hydrogen manganese(II), iron(II), cobalt(II), nickel(II), copper(II), and zinc(II) ions
Enrique Garcia-Espana, Mauro Micheloni, Piero Paoletti, and Antonio Bianchi
pp 1435 - 1438; DOI:
10.1021/ic00229a027
PDF
Rapid, reversible heterolytic cleavage of the cobalt-rhodium bond in carbonylbis(triethylphosphine)(tetracarbonylcobalt)rhodium
David A. Roberts, William C. Mercer, Gregory L. Geoffroy, and Cortlandt G. Pierpont
pp 1439 - 1444; DOI:
10.1021/ic00229a028
PDF
Intrazeolite chemistry of cobalt carbonyls
Melissa C. Connaway and Brian E. Hanson
pp 1445 - 1451; DOI:
10.1021/ic00229a029
PDF
Chemistry and stereochemistry of reactions of organophosphorus ligands in chiral Mo(CO)5L complexes
Louis P. Reiff, David I. Rossman, Leonard J. Szafraniec, and Herbert S. Aaron
pp 1451 - 1455; DOI:
10.1021/ic00229a030
PDF
Trivalent nickel bis(triaza macrocyclic) complexes. Ligand ring size and medium effects on the nickel(III)/nickel(II) redox couple potential
Armando Buttafava, Luigi Fabbrizzi, Angelo Perotti, Antonio Poggi, Gianluigi Poli, and Barbara Seghi
pp 1456 - 1461; DOI:
10.1021/ic00229a031
PDF
Reactions of molybdenum trisulfide, tungsten trisulfide, tungsten triselenide, and niobium triselenide with lithium. Metal cluster rearrangement revealed by EXAFS
Robert A. Scott, Allan J. Jacobson, Russ R. Chianelli, W. H. Pan, Edward I. Stiefel, Keith O. Hodgson, and Stephen P. Cramer
pp 1461 - 1466; DOI:
10.1021/ic00229a032
PDF
Structural evidence concerning the frontier orbitals in [Fe2E2(CO)6]2- (E = S, Se): redox-active dichalcogen ligands
Timothy D. Weatherill, Thomas B. Rauchfuss, and Robert A. Scott
pp 1466 - 1472; DOI:
10.1021/ic00229a033
PDF
Equilibria and kinetics of chelation of nickel(II) by a solubilized 1-(2-pyridylazo)-2-naphthol (.beta.-PAN) dye
Richard L. Reeves
pp 1473 - 1478; DOI:
10.1021/ic00229a034
PDF
Enthalpy of formation of nitrosylpentaamineruthenium(II) from nitrosium (aq) and aquopentaammineruthenium(II)
James F. Wishart, Henry Taube, Kenneth J. Breslauer, and Stephan S. Isied
pp 1479 - 1481; DOI:
10.1021/ic00229a035
PDF
Partial molal volumes of spin-equilibrium metal complexes
Robert A. Binstead and James K. Beattie
pp 1481 - 1484; DOI:
10.1021/ic00229a036
PDF
Low-temperature IR MCD using modified PTFE films and applications to the Creutz-Taube complex
Elmars R. Krausz and Albert W. H. Mau
pp 1484 - 1488; DOI:
10.1021/ic00229a037
PDF
Electronic structure of Nb3X4 type compounds
Enric Canadell and Myung Hwan Whangbo
pp 1488 - 1491; DOI:
10.1021/ic00229a038
PDF
Can M6X8 clusters form intercluster metal metal bonds?
Timothy Hughbanks
pp 1492 - 1497; DOI:
10.1021/ic00229a039
PDF
A novel type of tetradentate uracil derivative in a dodecahedral eight-coordinate chelate complex: catena-bis(.mu.-6-amino-3-methyl-5-nitrosouracilato-N5,O4,N1,O2)cadmium(II)
Maria A. Romero, Miguel N. Moreno, Jose Ruiz, Maria P. Sanchez, and Fernando Nieto
pp 1498 - 1501; DOI:
10.1021/ic00229a040
PDF
Dioxomolybdenum(VI)-substituted 2,6-pyridinedimethanol complexes: new five-coordinate species
Joel M. Hawkins, John C. Dewan, and K. Barry Sharpless
pp 1501 - 1503; DOI:
10.1021/ic00229a041
PDF
Single-crystal polarized electronic absorption spectra and ligand field parameters for the trichloro(triethylphosphine)platinate(II) ion
Julia R. Phillips and Jeffrey I. Zink
pp 1503 - 1505; DOI:
10.1021/ic00229a042
PDF
Kinetics of formation and decomposition of the methyl-copper(II) complex in aqueous solutions. A pulse-radiolysis study
Haim Cohen and Dan Meyerstein
pp 1505 - 1506; DOI:
10.1021/ic00229a043
PDF
Electronic states of rhodium(I) binuclear A-frame complexes
M. Inga S. Kenney, John W. Kenney, and G. A. Crosby
pp 1506 - 1508; DOI:
10.1021/ic00229a044
PDF
Hydrostannolysis reactions of M2(NMe2)6 (M = W, Mo)
Paul R. Sharp and Michael T. Rankin
pp 1508 - 1510; DOI:
10.1021/ic00229a045
PDF
Doubly-charged ion mass spectrometry of metallocenes
P. R. Nelson, J. R. Appling, E. Kent Barefield, and T. F. Moran
pp 1510 - 1511; DOI:
10.1021/ic00229a046
PDF
Additions and Corrections - Kinetics and Mechanism of Chelation of Nickel(II) by a Tridentate α-[(2-Hydroxyphenyl)azo]-α-acetoacetonitrile Dye.
Gregg A. Meyers, Frank M. Michaels, Richard L. Reeves, and Philip J. Trotter
pp 1512 - 1512; DOI:
10.1021/ic00229a600
PDF
Additions and Corrections - Application of Factor Analysis to the Spectrophotometric Determination of Formation Constants of Complexes of Nickel(II) with Tridentate Dyes.
Richard L. Reeves, Mary S. Maggio, Shelley A. Harkaway, and Gregg A. Meyers
pp 1512 - 1512; DOI:
10.1021/ic00229a601
PDF
Additions and Corrections - Synthesis and Antibody-Labeling Studies with the p-Isothiocyanatobenzene Derivatives of 1,2-Dicarba-closo-dodecaborane(12) and the Dodecahydro-7,8-dicarba-nido-undecaborate(1-) Ion for Neutron-Capture Therapy of Human Cancer. Crystal and Molecular Structure of Cs+[nido-7-(p-C6H4NCS)-9-I-7-8-C2B9H11]-
Eugene A. Mizusawa, Michael R. Thompson, and M. Frederick Hawthorne
pp 1512 - 1512; DOI:
10.1021/ic00229a602
PDF
Additions and Corrections - Outer-Sphere Electron-Transfer Reactions Involving the Rh2(O2CCH3)4(OH2)20/+ Couple. Determination of the Rh20/+ Self-Exchange Rate Constant.
John W. Herbert, and Donal H. Macartney
pp 1512 - 1512; DOI:
10.1021/ic00229a603
PDF

Issue 10


Epoxidation and catalytic oxidation of olefins based on a RuIV:O/RuII-OH2 couple
John C. Dobson, Won K. Seok, and Thomas J. Meyer
pp 1513 - 1514; DOI:
10.1021/ic00230a001
PDF
Reduction of dirhodium(II) complexes of the type [Rh2(O2CCH3)3(L)]+. An ESR investigation
J. L. Bear, L. K. Chau, M. Y. Chavan, F. Lefoulon, R. P. Thummel, and K. M. Kadish
pp 1514 - 1516; DOI:
10.1021/ic00230a002
PDF
Interligand repulsion energy and the twisting of hexadentate chelating ligands
Igor Gladstone, N. J. Rose, and E. C. Lingafelter
pp 1516 - 1518; DOI:
10.1021/ic00230a003
PDF
Examination of mercury dithiocarbamate-trialkylphosphine mixed-ligand complexes by electrochemical techniques at mercury electrodes and multinuclear magnetic resonance spectroscopy
Alan M. Bond, Ray Colton, Anthony F. Hollenkamp, and John E. Moir
pp 1519 - 1526; DOI:
10.1021/ic00230a004
PDF
Hexacyclen complexes of sulfate anion
Robert I. Gelb, Lowell M. Schwartz, and Leverett J. Zompa
pp 1527 - 1535; DOI:
10.1021/ic00230a005
PDF
Multinuclear NMR characterization of anionic clusters of the main-group elements germanium, tin, antimony, thallium, lead, and bismuth in nonaqueous solution
William L. Wilson, Ralph W. Rudolph, Lawrence L. Lohr, R. Craig Taylor, and Pekka Pyykko
pp 1535 - 1541; DOI:
10.1021/ic00230a006
PDF
Kinetic investigation of uranyl-uranophile complexation. 1. Macrocyclic kinetic effect and macrocyclic protection effect
Iwao Tabushi and Atsushi Yoshizawa
pp 1541 - 1546; DOI:
10.1021/ic00230a007
PDF
Correlation between the hyperfine coupling constants of donor nitrogens and the structures of the first coordination sphere in copper complexes as studied by nitrogen-14 ENDOR spectroscopy
Masamoto Iwaizumi, Takanori Kudo, and Shouichi Kita
pp 1546 - 1550; DOI:
10.1021/ic00230a008
PDF
A reinvestigation of the mass spectra of zinc acetate and cobalt acetate
G. C. DiDonato and K. L. Busch
pp 1551 - 1556; DOI:
10.1021/ic00230a009
PDF
Synthesis and structure of three (tricyclohexylphosphine)rhodium complexes and their interconversion with carbon monoxide and hydrogen
Michael A. Freeman and David A. Young
pp 1556 - 1560; DOI:
10.1021/ic00230a010
PDF
Conversion of nido-[(CH3)3Si]2C2B4H6 to nido-[(CH3)3Si]C2B4H7 and molecular structure of 2-(trimethylsilyl)-2,3-dicarba-nido-hexaborane(8), studied by gas-phase electron diffraction
Narayan S. Hosmane, Noormahmad N. Maldar, Stephen B. Potts, David W. H. Rankin, and Heather E. Robertson
pp 1561 - 1565; DOI:
10.1021/ic00230a011
PDF
Structure determination and investigation of the high-spin .tautm. low-spin transition of tris[2-(aminomethyl)pyridine]iron(2+) dibromide.monoethanol
L. Wiehl, G. Kiel, C. P. Koehler, H. Spiering, and P. Guetlich
pp 1565 - 1571; DOI:
10.1021/ic00230a012
PDF
Crystal structure and infrared and Raman spectra of potassium vanadium sulfate (KV(SO4)2)
Rasmus Fehrmann, Bernt Krebs, G. N. Papatheodorou, Rolf W. Berg, and Niels J. Bjerrum
pp 1571 - 1577; DOI:
10.1021/ic00230a013
PDF
Heteropolyanions of the types M3(W9PO34)212- and MM'M"(W9PO34)212-: novel coordination of nitrate and nitrite
W. H. Knoth, P. J. Domaille, and R. L. Harlow
pp 1577 - 1584; DOI:
10.1021/ic00230a014
PDF
Synthesis, spectroscopy, and x-ray structure of chlorotetrakis(6-chloro-2-hydroxypyridinato)diosmium: an unusual Os25+ complex with a polar arrangement of 6-chloro-2-hydroxypyridinato ligands and one axial chloride
F. Albert Cotton, Kim R. Dunbar, and Marek Matusz
pp 1585 - 1589; DOI:
10.1021/ic00230a015
PDF
Preparation and structural characterization of Os2Cl4(chp)2(L) (chp = 6-chloro-2-hydroxypridinato; L = water, pyridine): a new class of M2X4(LL)2 complexes possessing an eclipsed conformation where LL is a substituted hydroxypyridinato ligand
F. Albert Cotton, Kim R. Dunbar, and Marek Matusz
pp 1589 - 1594; DOI:
10.1021/ic00230a016
PDF
Synthesis, structure, and interconversion of polypyrazolylborate complexes of molybdenum(V)
Sandra Lincoln and Stephen A. Koch
pp 1594 - 1602; DOI:
10.1021/ic00230a017
PDF
Catalytic carbon dioxide methanation by alumina-supported mono- and polynuclear ruthenium carbonyls
Donald J. Darensbourg and Cesar Ovalles
pp 1603 - 1609; DOI:
10.1021/ic00230a018
PDF
Stereodynamics of trans-[tert-C4H9)2PR]2M(CO)X systems (R = H, CH3; M = Rh(I), Ir(I); X = Cl, Br, I). Assignment of conformational preferences and conformational exchange itineraries
C. Hackett Bushweller, Christopher D. Rithner, and David J. Butcher
pp 1610 - 1616; DOI:
10.1021/ic00230a019
PDF
Cluster synthesis. 11. Role of sulfido ligands in the synthesis of heteronuclear clusters. Synthesis and crystal and molecular structures of PtOs4(CO)11(PMe2Ph)2(.mu.3-S)2 and PtOs3(CO)9(PMe2Ph)2(.mu.3-S)2
Richard D. Adams, Istvan T. Horvath, and Suning Wang
pp 1617 - 1623; DOI:
10.1021/ic00230a020
PDF
Cluster syntheses. 12. Metal-metal exchange reactions. Systematics of the synthesis of platinum-osmium carbonyl clusters containing quadruply bridging sulfido ligands
Richard D. Adams, James E. Babin, Rahina Mathab, and Suning Wang
pp 1623 - 1631; DOI:
10.1021/ic00230a021
PDF
Synthesis, structures and nonrigidity of heterotrimetallic alkyne clusters of the type CpNiCoM(CO)6(C2RR') (M = Fe, Ru, Os)
Frederick W. B. Einstein, Kenneth G. Tyers, Alan S. Tracey, and Derek Sutton
pp 1631 - 1640; DOI:
10.1021/ic00230a022
PDF
Copper(II) complexes of diastereoisomeric dipeptides in aqueous solution. Effect of side-chain groups on the thermodynamic stereoselectivity
Raffaele P. Bonomo, Rosario Cali, Vincenzo Cucinotta, Giuseppe Impellizzeri, and Enrico Rizzarelli
pp 1641 - 1646; DOI:
10.1021/ic00230a023
PDF
Macrocyclic complexes of lead(II): crystal structures of LPb(ClO4)2 and LPb(NO3)2 (L = 1,4,7-triazacyclononane)
Karl Wieghardt, Michael Kleine-Boymann, Bernhard Nuber, Johannes Weiss, Laszlo Zsolnai, and Gottfried Huttner
pp 1647 - 1650; DOI:
10.1021/ic00230a024
PDF
Crystal structure of bis[bis(1,4,7-triazacyclononane)nickel(III)] dithionate heptahydrate and its single-crystal EPR spectrum
Karl Wieghardt, Wolfgang Walz, Bernhard Nuber, Johannes Weiss, Andrej Ozarowski, Horst Stratemeier, and Dirk Reinen
pp 1650 - 1654; DOI:
10.1021/ic00230a025
PDF
Macrocyclic complexes of indium(III): novel .mu.-hydroxo- and .mu.-oxo-bridged complexes. Crystal structures of [L4In4(.mu.-OH)6](S2O6)3.4H2O and [L2In2(CH3CO2)4(.mu.-O)].2NaClO4 (L = 1,4,7-triazacyclononane)
Karl Wieghardt, Michael Kleine-Boymann, Bernhard Nuber, and Johannes Weiss
pp 1654 - 1659; DOI:
10.1021/ic00230a026
PDF
Syntheses of [LRe(CO)3]+ and [LRe(NO)(CO)2]2+ and their oxidative decarbonylation product [LReO3]+. Crystal structure of [LReO3]Cl (L = 1,4,7-triazacyclononane)
Karl Wieghardt, Christa Pomp, Bernhard Nuber, and Johannes Weiss
pp 1659 - 1661; DOI:
10.1021/ic00230a027
PDF
Theoretical analysis of the bonding in octahedral transition-metal clusters containing .mu.-acceptor and .mu.-donor bridging ligands and their nido and arachno derivatives
Roy L. Johnston and D. Michael P. Minggos
pp 1661 - 1671; DOI:
10.1021/ic00230a028
PDF
Chloro complexes of cobalt(III) and chromium(III) with 2,2-dimethyl-1,3-diaminopropane. Synthesis, characterization, and acid hydrolysis kinetics
Donald A. House
pp 1671 - 1674; DOI:
10.1021/ic00230a029
PDF
Polyaza cavity-shaped molecules. 7. Dirhodium complexes of triaza and tetraaza cavities
Randolph P. Thummel, Francois Lefoulon, Darwin Williamson, and Madhav Chavan
pp 1675 - 1679; DOI:
10.1021/ic00230a030
PDF
Studies of metal-carbonate complexes. 13. Composition and equilibria of trinuclear neptunium(VI)- and plutonium(VI)-carbonate complexes
Grenthe Ingmar, Chantal Riglet, and Pierre Vitorge
pp 1679 - 1684; DOI:
10.1021/ic00230a031
PDF
Synthesis and spectral characterization of tetracyanoferrate(II) and tetracyanoferrate(III) chelates with 1,3-diamines
Masafumi Goto, Hiroko Nakayabu Kogure, Hitoshi Ito, Hisao Tsubamoto, Kyoko Nakabayashi, Yoshitaka Kuroda, and Tomoya Sakai
pp 1684 - 1691; DOI:
10.1021/ic00230a032
PDF
Multielectron reductions of alkyl azides with [Mo2Fe6S8(SPh)9]3- and [Mo2Fe6S8(.mu.-SEt)3(SCH2CH2OH)6]3- in homogeneous systems and with a (Bu4N)3[Mo2Fe6S8(SPh)9] modified glassy-carbon electrode in water
Susumu Kuwabata, Koji Tanaka, and Toshio Tanaka
pp 1691 - 1697; DOI:
10.1021/ic00230a033
PDF
Electronic absorption and magnetic circular dichroism spectra of monomeric and dimeric platinum(II) and palladium(II) iodide complexes
Lars Fride Olsson
pp 1697 - 1704; DOI:
10.1021/ic00230a034
PDF
Anisotropic exchange interactions in the copper(II) and vanadium(IV) dimers [(L')Cu(.mu.-OH)2Cu(L')](ClO4)2 and [(L)VO(.mu.-OH)2VO(L)]Br2 with 1,4,7-triazacyclononane (L) and its N,N',N"-trimethyl derivative (L'): a single-crystal EPR study
A. Ozarowski and D. Reinen
pp 1704 - 1708; DOI:
10.1021/ic00230a035
PDF
Mechanism for chiral recognition of a prochiral center and for asymmetric induction in asymmetric syntheses of .alpha.-amino acids using chiral cobalt(III) complexes. Crystal and molecular structures of (.alpha.-amino-.alpha.-methylmalonato)(4,6-dimethyl-1,9-diamino-3,7-diazanonane)cobalt perchlorate monohydrate and (.alpha.-amino-.alpha.-methylmalonato)(6,8-dimethyl-2,5,9,12-tetraazatridecane)cobalt bromide trihydrate
Morio Yashiro, Masanobu Ajioka, Shigenobu Yano, Koshiro Toriumi, Tasuku Ito, and Sadao Yoshikawa
pp 1709 - 1715; DOI:
10.1021/ic00230a036
PDF
Ruthenium complexes of N,S- and C,N,S-coordinating azo ligands: synthesis, reactions, and structure
Amiya K. Mahapatra, Sachchidananda Datta, Sreebrata Goswami, Monika Mukherjee, Alok Kumar Mukherjee, and Animesh Chakravorty
pp 1715 - 1721; DOI:
10.1021/ic00230a037
PDF
Molten lithium sulfate-sodium sulfate-potassium sulfate eutectic: oxidation-reduction reactions of some transition-metal compounds
R. I. Dearnaley, D. H. Kerridge, and D. J. Rogers
pp 1721 - 1725; DOI:
10.1021/ic00230a038
PDF
Tetraamine complexes of chromium(III). 5. Preparation of bis(carboxylato)bis(1,2-ethanediamine)chromium(III) complexes
James C. Chang
pp 1725 - 1726; DOI:
10.1021/ic00230a039
PDF
The unusual structural feature of binuclear platinum chains [Pt2(L-L)4X]n-.infin.
Myung Hwan Whangbo and Enric Canadell
pp 1726 - 1728; DOI:
10.1021/ic00230a040
PDF
Proposed reformulation of the recently reported tribromobis(dimethylphenylphosphine)tantalum
F. Albert Cotton, Michael P. Diebold, and Wieslaw J. Roth
pp 1728 - 1729; DOI:
10.1021/ic00230a041
PDF
Hexaaza macrocyclic complexes of the lanthanides
L. De Cola, D. L. Smailes, and L. M. Vallarino
pp 1729 - 1732; DOI:
10.1021/ic00230a042
PDF
Emission from tris(2,2'-bipyridine)ruthenium(3+) in solids and the question of delocalization
P. S. Braterman
pp 1732 - 1732; DOI:
10.1021/ic00230a043
PDF

Issue 11


Novel diisopropylamino triphosphine hexacarbonyldiiron complexes
R. B. King, F. J. Wu, and E. M. Holt
pp 1733 - 1734; DOI:
10.1021/ic00231a001
PDF
An x-ray photoelectron spectroscopic study of uranium compounds
David B. Beach, Kenneth D. Bomben, Norman M. Edelstein, David C. Eisenberg, William L. Jolly, Ron Shinomoto, and Andrew Streitwieser
pp 1735 - 1737; DOI:
10.1021/ic00231a002
PDF
Photoinduced electron-transfer reactions of poly(pyridine)ruthenium(II) complexes with europium(III/II) cryptates
N. Sabbatini, S. Dellonte, A. Bonazzi, M. Ciano, and V. Balzani
pp 1738 - 1742; DOI:
10.1021/ic00231a003
PDF
Mechanistic information from the effect of pressure on outer-sphere electron-transfer reactions involving the reduction of cobalt(III) by iron(II) complexes in aqueous solution
I. Krack and R. Van Eldik
pp 1743 - 1747; DOI:
10.1021/ic00231a004
PDF
Competitive NMR study of the complexation of several cations with 18-crown-6, 1,10-diaza-18-crown-6, and cryptand-2,2,2 in nonaqueous solutions
Roger D. Boss and Alexander I. Popov
pp 1747 - 1750; DOI:
10.1021/ic00231a005
PDF
Mixed-valence nickel(II)/platinum(IV) chain complexes. Electronic, infrared, Raman, and resonance Raman studies
Robin J. H. Clark and Vincent B. Croud
pp 1751 - 1756; DOI:
10.1021/ic00231a006
PDF
Chemistry of trivalent uranium metallocenes: electron-transfer reactions with carbon disulfide. Formation of [(RC5H4)3U]2[.mu.-.eta.1.eta.2-CS2]
John G. Brennan, Richard A. Andersen, and Allan Zalkin
pp 1756 - 1760; DOI:
10.1021/ic00231a007
PDF
Chemistry of trivalent uranium metallocenes: electron-transfer reactions. Synthesis and characterization of [(MeC5H4)3U]2E (E = S, Se, Te) and the crystal structures of hexakis(methylcyclopentadienyl)sulfidodiuranium and tris(methylcyclopentadienyl)(triphenylphosphine oxide)uranium
John G. Brennan, Richard A. Andersen, and Allan Zalkin
pp 1761 - 1765; DOI:
10.1021/ic00231a008
PDF
A tetraphosphorus chain as part of a P8-containing ligand. Synthesis and properties of the .eta.4-phosphabutadiene cobalt complex [Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)]BF4 and of its carbonyl derivatives {[Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)][Cr(CO)5]2}BF4 and {[Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)][W(CO)5]}Y (Y = BPh4, BF4). X-ray crystal structure of [Co(Ph2PCH2P(Ph)2P4P(Ph)2CH2PPh2)]BF4
Franco Cecconi, Carlo A. Ghilardi, Stefano Midollini, and Annabella Orlandini
pp 1766 - 1770; DOI:
10.1021/ic00231a009
PDF
Boron-nitrogen compounds. 110. Reactions of boroxins and diboroxanes with pyrazole
J. Bielawski and K. Niedenzu
pp 1771 - 1774; DOI:
10.1021/ic00231a010
PDF
New complexes of ruthenium(II) with a tetrapyrazolic macrocycle
M. Gal, C. Marzin, G. Tarrago, I. Zidane, T. Hours, D. Lerner, C. Andrieux, H. Gampp, and J. M. Saveant
pp 1775 - 1778; DOI:
10.1021/ic00231a011
PDF
New ligand-bridged polyruthenium(II) complexes with cofacial tetrapyrazolic macrocycles
C. Marzin, G. Tarrago, I. Zidane, E. Bienvenue, P. Seta, C. Andrieux, H. Gamp, and J. M. Saveant
pp 1778 - 1781; DOI:
10.1021/ic00231a012
PDF
Carbon-13 NMR study of the synergistic anion in transferrins
Ivano Bertini, Claudio Luchinat, Luigi Messori, Andrea Scozzafava, Giancarlo Pellacani, and Marco Sola
pp 1782 - 1786; DOI:
10.1021/ic00231a013
PDF
Magnetochemistry of copper(II): exchange interactions in catenated acetatodiamminebromocopper
Richard L. Carlin, Klaas Kopinga, Olivier Kahn, and Michel Verdaguer
pp 1786 - 1789; DOI:
10.1021/ic00231a014
PDF
Coordination chemistry of higher oxidation states. 19. Synthesis and properties of diphosphine and diarsine complexes of iron(IV), and iron K-edge EXAFS data on [Fe(o-C6H4(PMe2)2)2Cl2]n+[BF4]n (n = 0-2)
Stephen K. Harbron, Simon J. Higgins, William Levason, Martinus C. Feiters, and Andrew T. Steel
pp 1789 - 1794; DOI:
10.1021/ic00231a015
PDF
Preparation and structural comparison of the ruthenium(0) derivatives Ru(DMPE)2L (L = PMe3, CO; DMPE = 1,2-bis(dimethylphosphino)ethane)
William D. Jones and Manuela Libertini
pp 1794 - 1800; DOI:
10.1021/ic00231a016
PDF
A binuclear copper(II) complex with a bridging thioether ligand. Crystal and molecular structure of dicopper (thiobis(ethylenenitrilo)tetraacetate) pentahydrate
Jeremy M. Berg and Keith O. Hodgson
pp 1800 - 1803; DOI:
10.1021/ic00231a017
PDF
Soluble zinc bis(aryloxides)
Rolf L. Geerts, John C. Huffman, and Kenneth G. Caulton
pp 1803 - 1805; DOI:
10.1021/ic00231a018
PDF
Reactions of coordination compounds in the solid state. I. Behavior of cobalt(III) bis(ethylenediamine) diammine salts
Terufumi Fujiwara and John C. Bailar
pp 1806 - 1809; DOI:
10.1021/ic00231a019
PDF
Stabilization of transition-metal complexes in high oxidation states by macrocyclic tertiary amines. Electrochemical generation and spectroscopic properties of novel dihalogeno and pseudohalogeno tetraamine complexes of ruthenium(IV)
Chi Ming Che, Kwok Yin Wong, and Chung Kwong Poon
pp 1809 - 1813; DOI:
10.1021/ic00231a020
PDF
Ruthenium(II)-catalyzed thioether oxidation. 1. Synthesis of mixed sulfide and sulfoxide complexes
Dennis P. Riley and Joel D. Oliver
pp 1814 - 1821; DOI:
10.1021/ic00231a021
PDF
Ruthenium(II)-catalyzed thioether oxidation. 2. Syntheses and crystal structures of two ruthenium(II) complexes with the new linear tridentate ligand 3-(ethylthio)-1-((3-(ethylthio)propyl)sulfinyl)propane
Dennis P. Riley and Joel D. Oliver
pp 1821 - 1825; DOI:
10.1021/ic00231a022
PDF
Ruthenium(II)-catalyzed thioether oxidation. 3. Syntheses and structure of model complexes with the new linear tridentate ligand bis(3-(ethylsulfinyl)propyl) sulfide
Dennis P. Riley and Joel D. Oliver
pp 1825 - 1830; DOI:
10.1021/ic00231a023
PDF
Dynamic, static, and theoretical electron deformation density for binuclear transition-metal complexes: dicobalt hexacarbonyl acetylene
F. Baert, A. Guelzim, J. M. Poblet, R. Wiest, J. Demuynck, and M. Benard
pp 1830 - 1841; DOI:
10.1021/ic00231a024
PDF
Cyclometalated complexes of ruthenium. 3. Spectral, electrochemical and two-dimensional proton NMR of [Ru(bpy)2(cyclometalating ligand)]+
P. Reveco, W. R. Cherry, J. Medley, A. Garber, R. J. Gale, and J. Selbin
pp 1842 - 1845; DOI:
10.1021/ic00231a025
PDF
Electrochemistry of carbonyl(fulvalene) dimetal complexes of chromium, molybdenum, tungsten, ruthenum, and molybdenum-ruthenium
Roger Moulton, Timothy W. Weidman, K. Peter C. Vollhardt, and Allen J. Bard
pp 1846 - 1851; DOI:
10.1021/ic00231a026
PDF
Steric and electronic effects on atom transfer reactions of Re(CO)4L.cntdot. radicals with organic halides and tributylstannane
John M. Hanckel, Kang Wook Lee, Paul Rushman, and Theodore L. Brown
pp 1852 - 1856; DOI:
10.1021/ic00231a027
PDF
The inert-pair effect on electronegativity
R. T. Sanderson
pp 1856 - 1858; DOI:
10.1021/ic00231a028
PDF
Reduction of nitric oxide by hydroxylamine. 1. Kinetics and mechanism
Francis T. Bonner and Nun Yii Wang
pp 1858 - 1862; DOI:
10.1021/ic00231a029
PDF
Reduction of nitric oxide by hydroxylamine. 2. Reactions of the alkylated hydroxylamines
Nun Yii Wang and Francis T. Bonner
pp 1863 - 1866; DOI:
10.1021/ic00231a030
PDF
Photophysics and photochemistry of 2,2'-bipyridine and 1,10-phenanthroline complexes of vanadium(II)
S. Sadiq Shah and Andrew W. Maverick
pp 1867 - 1871; DOI:
10.1021/ic00231a031
PDF
Exact results for EPR g and A tensors in the S1 = 1, 3/2, 2, 5/2 and S2 = 1/2 spin-coupled systems. The effect when S is not a good quantum number
William B. Euler
pp 1871 - 1875; DOI:
10.1021/ic00231a032
PDF
Electronic ground states and spectra of square-planar nickel(II) complexes with aromatic dithiocarboxylato ligands
Michael P. Sigalas and Constantinos A. Tsipis
pp 1875 - 1880; DOI:
10.1021/ic00231a033
PDF
Octahedral d3 and d4 complexes of molybdenum with 1,2-bis(dimethylphosphino)ethane
Lawrence K. Fong, James R. Fox, Bruce M. Foxman, and N. John Cooper
pp 1880 - 1886; DOI:
10.1021/ic00231a034
PDF
Oxygenated titanium sulfide clusters. Synthesis and structures of (CH3C5H4)4Ti4S8Ox (x = 1, 2)
Gregg A. Zank, Catherine A. Jones, Thomas B. Rauchfuss, and Arnold L. Rheingold
pp 1886 - 1891; DOI:
10.1021/ic00231a035
PDF
Synthesis of an iron(III) porphyrin dimer with a trans-dicyanoethylenedithiolate bridging ligand: structural and magnetic studies on (.mu.-trans-1,2-dicyanoethylenedithiolato-S,S')bis(tetraphenylporphyrinato)diiron bis(benzene)
C. Michael Elliott, Kozo Akabori, Oren P. Anderson, Cynthia K. Schauer, William E. Hatfield, P. B. Sczaniecki, Samarash Mitra, and K. Spartalian
pp 1891 - 1896; DOI:
10.1021/ic00231a036
PDF
Gallium analogs of iron-sulfide-thiolate compounds. Analysis of the structural parameters in gallium(III) and iron(III) chalcogenide compounds
Lynn E. Maelia and Stephen A. Koch
pp 1896 - 1904; DOI:
10.1021/ic00231a037
PDF
Synthesis and characterization of tetrafluoroammonium(1+) tetrafluorobromate(1-) and tetrafluoroammonium(1+) tetrafluorooxobromate(1-)
Karl O. Christe and William W. Wilson
pp 1904 - 1906; DOI:
10.1021/ic00231a038
PDF
Photochemical studies of [.eta.5-C5R5)M(.eta.6-COT)]PF6 and [(.eta.5-C5R5)M(.eta.4-1,5-COT)L]PF6 complexes of iron and ruthenium
Janet L. Schrenk and Kent R. Mann
pp 1906 - 1908; DOI:
10.1021/ic00231a039
PDF
Rapid pulse-radiolytic reduction of iron(III) complexes of tetrakis(4-sulfonatophenyl)porphine anion and tetrakis(N-methylpyrid-4-yl)porphine cation
P. C. Wilkins and R. G. Wilkins
pp 1908 - 1910; DOI:
10.1021/ic00231a040
PDF
Influence of closed-shell cations on the LMCT transition of pentacyanoferrate(III) complexes
L. William Warner, M. Fazlul Hoq, Terry K. Myser, Wayne W. Henderson, and Rex E. Shepherd
pp 1911 - 1914; DOI:
10.1021/ic00231a041
PDF
Volumes of activation and mechanistic assignment for chelate ring replacement at tetracarbonylchromium(0) centers
H. T. Macholdt, R. Van Eldik, and G. R. Dobson
pp 1914 - 1916; DOI:
10.1021/ic00231a042
PDF
Solvent-dependent redox thermodynamics as a probe of solvent shielding in lanthanide cryptates
Jila Tabib, Joseph T. Hupp, and Michael J. Weaver
pp 1916 - 1918; DOI:
10.1021/ic00231a043
PDF
The magnetic susceptibility of paraquat hexabromodicuprate(II): a comparison of the magnetochemistry of copper(II) chloride and copper(II) bromide salts
Roger D. Willett
pp 1918 - 1920; DOI:
10.1021/ic00231a044
PDF

Issue 12


Ring-induced rhombicity in chlorin and isobacteriochlorin complexes of square-planar iron(II)
Steven H. Strauss and Michael J. Pawlik
pp 1921 - 1923; DOI:
10.1021/ic00232a001
PDF
Substituted cyclopentadienyl(dithiolene)tungsten(IV) products from alkyne addition to tungsten(II) dithiocarbamate reagents
J. R. Morrow, J. L. Templeton, J. A. Bandy, C. Bannister, and C. K. Prout
pp 1923 - 1925; DOI:
10.1021/ic00232a002
PDF
Transmetalation of tetranuclear copper complexes. 4. Structural implications of the kinetics of direct transmetalation of tetranuclear copper(II) complexes by Ni(NS)2 reagents
Geoffrey Davies, Mohamed A. El-Sayed, and Ahmed El-Toukhy
pp 1925 - 1928; DOI:
10.1021/ic00232a003
PDF
Transmetalation of tetranuclear copper complexes. 5. Transmetalation of copper(I) complexes and stoichiometry and kinetics of oxidation of neutral tetranuclear (DENC)3Cu3M(NS)X4 (DENC = N,N-diethylnicotinamide) complexes by dioxygen in aprotic solvents
Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Thomas R. Gilbert, and Khadija Nabih
pp 1929 - 1934; DOI:
10.1021/ic00232a004
PDF
Transmetalation of tetranuclear copper complexes. 6. Transmetalation of copper dioxo L4Cu4O2 complexes (L = 6-methyl-2-hydroxypyridinate) by M(NS)2 reagents
Guang Zuan Cai, Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Thomas R. Gilbert, and Kay D. Onan
pp 1935 - 1940; DOI:
10.1021/ic00232a005
PDF
Dissociation and isomerization kinetics of (C-meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) (red) cation in strongly acidic, aqueous media
Jy Wann Chen, Der Shin Wu, and Chung Sun Chung
pp 1940 - 1943; DOI:
10.1021/ic00232a006
PDF
Acidic properties of (dimethyl sulfoxide)(1,5-diamino-3-azapentane)platinum(II) perchlorate and kinetics of the displacement of dimethyl sulfoxide from the conjugate base
Raffaello Romeo, Domenico Minniti, Giuseppe Alibrandi, Luisa De Cola, and Martin L. Tobe
pp 1944 - 1947; DOI:
10.1021/ic00232a007
PDF
The elimination-condensation reaction between dimethylaluminum hydride and methylphenylphosphine
O. T. Beachley and L. Victoriano
pp 1948 - 1951; DOI:
10.1021/ic00232a008
PDF
Opening of the .beta.-alaninate chelate (.beta.-alaninato)bis(ethylenediamine)cobalt(2+) in alkali and the properties of cis- and trans-(.beta.-alaninato)bis(ethylenediamine)hydroxocobalt(1+)
Eveline Baraniak, David A. Buckingham, Charles R. Clark, and Alan M. Sargeson
pp 1952 - 1956; DOI:
10.1021/ic00232a009
PDF
Mercury(2+)- and hydroxide-induced reactions of cis-[Co(en)xX(.beta.-alaOR)]2+ and cis-[Co(en)2Br(.beta.-alaO)]+ (X = Cl, Br; R = H, Me, iso-Pr)
Eveline Baraniak, David A. Buckingham, Charles R. Clark, and Alan M. Sargeson
pp 1956 - 1961; DOI:
10.1021/ic00232a010
PDF
Electrochemical behavior of tungsten(VI) aryloxides and catecholates
Sharon M. Beshouri and Ian P. Rothwell
pp 1962 - 1964; DOI:
10.1021/ic00232a011
PDF
Volumes of activation for electron exchange by hexakis(alkyl isocyanide)manganese(+/2+) complexes in acetonitrile
Roger M. Nielson, John P. Hunt, Harold W. Dodgen, and Scot Wherland
pp 1964 - 1968; DOI:
10.1021/ic00232a012
PDF
Stopped-flow study of ligand-exchange kinetics between terbium(III) ion and calcium(II) ethylenediaminetetraacetate(4-)
Patrick J. Breen, William D. Horrocks, and Kenneth A. Johnson
pp 1968 - 1971; DOI:
10.1021/ic00232a013
PDF
Formation constants of copper(I) chloride complexes with cis,cis-1,5-cyclooctadiene and other cyclic olefins
Ilmarie Rencken and S. Walter Orchard
pp 1972 - 1976; DOI:
10.1021/ic00232a014
PDF
Heterobimetallic dicyclohexylphosphido-bridged complexes of MoNi, MoPd, MoPt, WNi, WPd, and WPt. Crystal and molecular structure of bis(.mu.-dicyclohexylphosphido)(triphenylphosphine)(tetracarbonylmolybdenum)palladium (Mo-Pd)
Stephen J. Loeb, Hilary A. Taylor, Lucio Gelmini, and Douglas W. Stephan
pp 1977 - 1982; DOI:
10.1021/ic00232a015
PDF
Comparative spectra and kinetics of ferrous bis(dioxime) complexes of .pi.-acid ligands
Nafees Siddiqui and Dennis V. Stynes
pp 1982 - 1987; DOI:
10.1021/ic00232a016
PDF
Phosphorus-31 and platinum-195 NMR studies and the crystal and molecular structure of chloro(triethylphosphine)[tris(diphenylphosphinothioyl)methyl]platinum(II) ([PtCl(PEt3){C(PPh2S)3}]), an S,S-bonded chelate with dynamic stereochemistry controlled by one labile and one inert platinum-sulfur bond
Jane Browning, Kathryn Anne Beveridge, Gordon William Bushnell, and Keith Roger Dixon
pp 1987 - 1992; DOI:
10.1021/ic00232a017
PDF
Raman spectroscopic studies of dioxouranium(2+) association with hydrolytic species of group IV metals
Susan A. Sherrow, L. M. Toth, and G. M. Begun
pp 1992 - 1996; DOI:
10.1021/ic00232a018
PDF
Coordination chemistry of higher oxidation states. 20. Synthesis and cobalt-59 NMR studies of tris(diphosphine)cobalt(3+), tris(diarsine)cobalt(3+) and related complexes. Crystal structure of tris[o-phenylenebis(dimethylarsine)]cobalt(III) tetrafluoroborate-2-water
Hilary C. Jewiss, William Levason, and Michael Webster
pp 1997 - 2001; DOI:
10.1021/ic00232a019
PDF
Spin state of cobalt(II) in five- and six-coordinate Lewis base adducts of N,N'-ethylenebis(3-carboxysalicylaldiminato)cobalt(II). New spin-crossover complexes
Pierre Thuery and Jacqueline Zarembowitch
pp 2001 - 2008; DOI:
10.1021/ic00232a020
PDF
Gold-197 Moessbauer analysis of alkali-metal-gold intermetallics and (2,2,2-crypt-M+)Au- compounds: existence of Au- in the solid state
Raymond J. Batchelor, Thomas Birchall, and Robert C. Burns
pp 2009 - 2015; DOI:
10.1021/ic00232a021
PDF
Synthesis and redox properties of a bipyridyl analog of ruthenium red
Daniel A. Geselowitz, Wlodzimierz Kutner, and Thomas J. Meyer
pp 2015 - 2023; DOI:
10.1021/ic00232a022
PDF
Redox properties of the water oxidation catalysts diaquatetrakis(2,2'-bipyridine)oxoderuthenium(4+) in thin polymeric films. Electrocatalytic oxidation of chloride to chlorine
William J. Vining and Thomas J. Meyer
pp 2023 - 2033; DOI:
10.1021/ic00232a023
PDF
Crystal and molecular structure of bis(4,4',6,6'-tetramethyl-2,2'-bipyridine)silver(I) tetrafluoroborate. Origin of flattening distortions in d10 complexes of the type M(NN)2+
Kevin V. Goodwin, David R. McMillin, and William R. Robinson
pp 2033 - 2036; DOI:
10.1021/ic00232a024
PDF
Absorption spectra of d10 metal ion derivatives of plastocyanin
Ramasamy Tamilarasan and David R. McMillin
pp 2037 - 2040; DOI:
10.1021/ic00232a025
PDF
Binding constants for neodymium(III) and samarium(III) with human serum transferrin
Wesley R. Harris
pp 2041 - 2045; DOI:
10.1021/ic00232a026
PDF
Mixed poly(pyrazolyl)borate-cyclopentadienyl zirconium(IV) complexes. Crystal and molecular structure of [dihydrobis(1-pyrazolyl)borato]dichloro(cyclopentadienyl)zirconium(IV)
Daniel L. Reger, Rahina Mahtab, Janet C. Baxter, and Lukasz Lebioda
pp 2046 - 2048; DOI:
10.1021/ic00232a027
PDF
Syntheses and phosphorus-31 NMR studies of five-coordinate nickel(II) complexes of the new ligand tris(o-(dimethylarsino)phenyl)phosphine
Eugene Grimley and Devon W. Meek
pp 2049 - 2053; DOI:
10.1021/ic00232a028
PDF
Selenium-77 NMR and Raman study of SxSe4x2+ cations and crystal structure of (S3.0Se1.0)2(Sb4F17)(SbF6)3 containing a disordered mixture of SxSe4x2+ cations
Michael J. Collins, R. J. Gillespie, J. F. Sawyer, and G. J. Schrobilgen
pp 2053 - 2057; DOI:
10.1021/ic00232a029
PDF
Preparation and structure of decacarbonyldi(.mu.-diselenido)ditungsten(2+) hexafluoroarsenati(1-) and related compounds
M. J. Collins, R. J. Gillespie, J. W. Kolis, and J. F. Sawyer
pp 2057 - 2061; DOI:
10.1021/ic00232a030
PDF
Dissociation kinetics of 1,7-diaza-4,10-,13-trioxacyclopentadecane-N,N'-diacetic acid complexes of lanthanides
V. Chandra Sekhar and C. Allen Chang
pp 2061 - 2065; DOI:
10.1021/ic00232a031
PDF
Activation of triiron clusters by electron transfer. Radical anions and dianions of nonacarbonylbis(.mu.3-phenylphosphinidene)triiron and its derivatives
H. H. Ohst and J. K. Kochi
pp 2066 - 2074; DOI:
10.1021/ic00232a032
PDF
Electrochemistry of dimanganese decacarbonyl, pentacarbonylmanganese(1+), pentacarbonylmanganate(1-), and manganese pentacarbonyl
D. A. Lacombe, J. E. Anderson, and K. M. Kadish
pp 2074 - 2079; DOI:
10.1021/ic00232a033
PDF
Synthesis and characterization of an iron carbonyl cluster containing lead: crystal and molecular structure of [Et4N]2[Pb{Fe(CO)4}2{Fe2(CO)8}]
Craig B. Lagrone, Kenton H. Whitmire, Melvyn Rowen Churchill, and James C. Fettinger
pp 2080 - 2085; DOI:
10.1021/ic00232a034
PDF
Nitrosyl complexes of technetium: synthesis and characterization of [TcI(NO)(CNCMe3)5](PF6)2 and Tc(NO)Br2(CNCMe3)3 and the crystal structure of Tc(NO)Br2(CNCMe3)3
Karen E. Linder, Alan Davison, John C. Dewan, Catherine E. Costello, and Simin Maleknia
pp 2085 - 2089; DOI:
10.1021/ic00232a035
PDF
Redox chemistry of hydrogen peroxide in anhydrous acetonitrile
Pablo Cofre and Donald T. Sawyer
pp 2089 - 2092; DOI:
10.1021/ic00232a036
PDF
Reactions of carbon monoxide with nitrato(triphenylphosphine)gold(I). Crystal structures of (isocyanato)(triphenylphosphine)gold(I) (AuC19H15NOP) and (fulminato)(triphenylphosphine)gold(I) (AuC19H15NOP)
W. P. Bosman, W. Bos, J. M. M. Smits, Paul T. Beurskens, J. J. Bour, and J. J. Steggerda
pp 2093 - 2096; DOI:
10.1021/ic00232a037
PDF
Pulse-radiolysis study of the reduction of oxovanadium(2+) by the hydrated electron
B. Fourest, K. H. Schmidt, and J. C. Sullivan
pp 2096 - 2097; DOI:
10.1021/ic00232a038
PDF
Structure of tetracarbonylbis[.mu.-bis(dimethylphosphino)methane]dinickel
Klaus R. Poerschke, Yi Hung Tsay, and Carl Krueger
pp 2097 - 2099; DOI:
10.1021/ic00232a039
PDF
Kinetics and mechanism of the ligand substitution reactions of pentacyano(ligand)ruthenate(II) complexes
J. Mark A. Hoddenbagh and Donal H. Macartney
pp 2099 - 2101; DOI:
10.1021/ic00232a040
PDF
Synthesis and photobehavior of chromium(III) and rhodium(III) complexes of the macrocyclic ligand C-meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane
Noel A. P. Kane-Maguire, Kevin C. Wallace, Daryl P. Cobranchi, James M. Derrick, and David G. Speece
pp 2101 - 2104; DOI:
10.1021/ic00232a041
PDF
Crystal structures of the tetra-n-butylammonium salts of the dichloroaurate(1-), dibromoaurate(1-), and diiodoaurate(1-) ions
Pierre Braunstein, Achim Mueller, and Hatmut Boegge
pp 2104 - 2106; DOI:
10.1021/ic00232a042
PDF

Issue 13


(Porphyrinato)bis(phthalocyaninato)dilanthanide(III) complexes presenting a sandwich triple-decker-like structure
M. Moussavi, A. De Cian, J. Fischer, and R. Weiss
pp 2107 - 2108; DOI:
10.1021/ic00233a001
PDF
Synthesis, properties and the structure of tetraethylammonium tris(pyridine-2-thiolato)ferrate(II). An example of an exceptionally short "bite" of the ligand
S. G. Rosenfield, S. A. Swedberg, S. K. Arora, and P. K. Mascharak
pp 2109 - 2114; DOI:
10.1021/ic00233a002
PDF
Disubstituted tungstosilicates. 1. Synthesis, stability, and structure of the lacunary precursor polyanion of a tungstosilicate .gamma.-SiW10O368-
Jacqueline Canny, Andre Teze, Rene Thouvenot, and Gilbert Herve
pp 2114 - 2119; DOI:
10.1021/ic00233a003
PDF
Synthesis and electronic structure of the R2NCS2N3 ring: x-ray crystal structure of the bicyclic compound iso-Pr2NCS3N5 and preparation of R2NCS2N3.C7H8 (R = Me, Et, iso-Pr), Et2NCS2N2+ Cl-, and salts of the (R2NCN)(NSCl)(NS)+ cation
Tristram Chivers, Frank Edelmann, John F. Richardson, Nigel R. M. Smith, Oswaldo Treu, and Milan Trsic
pp 2119 - 2125; DOI:
10.1021/ic00233a004
PDF
Crystal and molecular structures of mer-trifluorotriphenyltellurium and stereoselective fluorine exchange in the mer-trifluorotriphenyltellurium-difluorotriphenyltellurium(1+) system
Anthony S. Secco, Kohrshed Alam, Barry J. Blackburn, and Alexander F. Janzen
pp 2125 - 2129; DOI:
10.1021/ic00233a005
PDF
Synthesis and characterization of the three geometrical isomers of difluoro(1,3-propanediamine-N,N'-diacetato)chromate(III). Crystal structure of trans-Li[CrF2(1,3-pdda)].2H2O
Robert J. Bianchini, Urs Geiser, Helen Place, Sumio Kaizaki, Yasuyo Morita, and J. Ivan Legg
pp 2129 - 2134; DOI:
10.1021/ic00233a006
PDF
Photocatalyzed transformation of cyanide to thiocyanate by rhodium-loaded cadmium sulfide in alkaline aqueous sulfide media
Enrico Borgarello, Rita Terzian, Nick Serpone, Ezio Pelizzetti, and Massimo Barbeni
pp 2135 - 2137; DOI:
10.1021/ic00233a007
PDF
Electrochemistry and spectroscopy of dicyanobis(phenanthroline)iron, tetracarbonyltetrakis(cyclopentadienyl)tetrairon and dicarbonylcyano(cyclopentadienyl)iron in an acidic molten salt
Carrie Woodcock and Duward F. Shriver
pp 2137 - 2142; DOI:
10.1021/ic00233a008
PDF
Synthesis and magnetic resonance spectroscopy of novel phenolato-bridged manganese(III) and iron(III)-manganese(III) porphyrin complexes
Gregory M. Godziela, David Tilotta, and Harold M. Goff
pp 2142 - 2146; DOI:
10.1021/ic00233a009
PDF
Cobalt(III) complexes of L-histidylglycylglycinate: preparation, characterization, and conformation
Clifford J. Hawkins and Jill Martin
pp 2146 - 2154; DOI:
10.1021/ic00233a010
PDF
Reactions of molybdenum(V) tetraphenylporphyrins with superoxide. Mechanism of the reactions and the characterization of an isolated dioxygen complex
Koichi Hasegawa, Taira Imamura, and Masatoshi Fujimoto
pp 2154 - 2160; DOI:
10.1021/ic00233a011
PDF
Secondary anion binding to the dicopper(II) complex of N,N',N",N'''-tetrakis(2-aminoethyl)cyclam
Ann Evers, Robert D. Hancock, and Ichiro Murase
pp 2160 - 2163; DOI:
10.1021/ic00233a012
PDF
Synthesis and characterization of CrF4O, KrF2.CrF4O, and NO+CrF5O-
Karl O. Christe, William W. Wilson, and Roland A. Bougon
pp 2163 - 2169; DOI:
10.1021/ic00233a013
PDF
Kinetics and mechanism of electron transfer to transition-metal complexes by photochemically produced tris(bipyridyl)ruthenium(1+) ion
Philip Connolly, James H. Espenson, and Andreja Bakac
pp 2169 - 2175; DOI:
10.1021/ic00233a014
PDF
Crown ether-lanthanide complexes studied by circularly polarized and total luminescence. 2. Solution species in (2R,3R,11R,12R)-2,3,11,12-tetramethyl-18-crown-6-europium nitrate and perchlorate systems in acetonitrile, trifluoroethanol, and hexafluoroisopropyl alcohol
David H. Metcalf, Rodney C. Carter, Robert G. Ghirardelli, and Richard Alan Palmer
pp 2175 - 2180; DOI:
10.1021/ic00233a015
PDF
High-resolution He I and He II photoelectron spectra of the indium trihalides: structure of indium triiodide from indium 4d ligand field splittings and MS-X.alpha. calculations
Jo Ann E. Bice, G. Michael Bancroft, and Leighton L. Coatsworth
pp 2181 - 2184; DOI:
10.1021/ic00233a016
PDF
R2PCR: .lambda.3-phosphinocarbene vs. .lambda.5-phosphaacetylene. theoretical study of the CH3P isomers
Nguyen Minh Tho, Michael A. McGinn, and Anthony F. Hegarty
pp 2185 - 2190; DOI:
10.1021/ic00233a017
PDF
Ligating properties of platinum(II) ions in mixed-metal (Pt2M) trimers (M = copper(II), nickel(II), cobalt(II), iron(II))
David M. L. Goodgame, Michael A. Hitchman, and Bernhard Lippert
pp 2191 - 2194; DOI:
10.1021/ic00233a018
PDF
Hexanuclear tungsten cluster structures: tetradecachlorohexatungstate(2-), tetradecabromohexatungstate(2-), and tetradecaiodohexatungstate(2-) relevance to unusual emissive behavior
Thomas C. Zietlow, William P. Schaefer, Behzad Sadeghi, Nhi Hua, and Harry B. Gray
pp 2195 - 2198; DOI:
10.1021/ic00233a019
PDF
Preparation and properties of bis(triphenylphosphine)iminium tetradecabromohexatungstate
Thomas C. Zietlow, William P. Schaefer, Behzad Sadeghi, Daniel G. Nocera, and Harry B. Gray
pp 2198 - 2201; DOI:
10.1021/ic00233a020
PDF
Synthesis and spectroscopic characterization of dithiocarbamate derivatives of methyl-, dimethyl- and trimethylgermane and crystal structure of dimethylbis(N,N'-dimethyldithiocarbamato)germanium
Raj K. Chadha, John E. Drake, and Anil B. Sarkar
pp 2201 - 2206; DOI:
10.1021/ic00233a021
PDF
Neutron diffraction analysis (T = 120 K) of chloro(ethene)(tetramethylethylenediamine)platinum(1+) perchlorate
Giuliana Gervasio, Sax A. Mason, Luciana Maresca, and Giovanni Natile
pp 2207 - 2211; DOI:
10.1021/ic00233a022
PDF
Anisotropic exchange in transition-metal dinuclear complexes. 8. Bis(.mu.-pyridine N-oxide)bis[dichloro(dimethyl sulfoxide)copper(II)]
A. Bencini, D. Gatteschi, and C. Zanchini
pp 2211 - 2214; DOI:
10.1021/ic00233a023
PDF
Palladated azobenzenes and regiospecific aromatic metaloxylation
Amiya K. Mahapatra, Debkumar Bandyopadhyay, Pinaki Bandyopadhyay, and Animesh Chakravorty
pp 2214 - 2221; DOI:
10.1021/ic00233a024
PDF
Electron-transfer reactions of oxovanadium(IV) and dioxovanadium(V) ions with metal tris(polypyridine) complexes in aqueous media
Donal H. Macartney
pp 2222 - 2225; DOI:
10.1021/ic00233a025
PDF
Photoaquation of trans-difluorobis(1,3-propanediamine)chromium(1+) in acidic aqueous solution
A. D. Kirk, C. Namasivayam, and T. Ward
pp 2225 - 2229; DOI:
10.1021/ic00233a026
PDF
Kinetics and mechanism of the reactions of sulfito complexes in aqueous solution. 7. Formation and redox reactions of sulfur-bonded aqua(sulfito)- and bis(sulfito)[bis(phenanthroline) or- bis(bipyridine)]cobalt(III) complex ions
V. K. Joshi, R. Van Eldik, and G. M. Harris
pp 2229 - 2237; DOI:
10.1021/ic00233a027
PDF
Mechanistic information from the micellar effect on the base hydrolysis of (.alpha..beta.s)-(3-nitro)salicylato)(tetraethylenepentamine)cobalt(III) ion
Anadi C. Dash and Ramesh C. Nayak
pp 2237 - 2241; DOI:
10.1021/ic00233a028
PDF
Complexes of the histamine H2-antagonist cimetidine with divalent and monovalent copper ions
Eiichi Kimura, Tohru Koike, Yasuko Shimizu, and Mutsuo Kodama
pp 2242 - 2246; DOI:
10.1021/ic00233a029
PDF
Electrochemistry of molybdenum and tungsten cyclopentadienyl carbonyl complexes, [M(CO)3Cp]2, [M(CO)3Cp]+, [M(CO)3Cp]-, and M(CO)3Cp where M = Mo and W
K. M. Kadish, D. A. Lacombe, and J. E. Anderson
pp 2246 - 2250; DOI:
10.1021/ic00233a030
PDF
Electrochemical studies of dimeric niobium(V) porphyrins. Reactions of [(OEP)Nb]2O3 and [(TpTP)Nb]2O3 in nonaqueous media
J. E. Anderson, Y. H. Liu, R. Guilard, J. M. Barbe, and K. M. Kadish
pp 2250 - 2255; DOI:
10.1021/ic00233a031
PDF
Polarized x-ray absorption near-edge structure of highly oxidized chromium porphyrins
James E. Penner-Hahn, Maurizio Benfatto, Britt Hedman, Tadashi Takahashi, Sebastian Doniach, John T. Groves, and Keith O. Hodgson
pp 2255 - 2259; DOI:
10.1021/ic00233a032
PDF
Proton NMR investigation of the electron-exchange reaction between hexaammineruthenium(II) and hexaammineruthenium(III) ions
Peter J. Smolenaers and James K. Beattie
pp 2259 - 2262; DOI:
10.1021/ic00233a033
PDF
Weak Curie-type paramagnetism of high-nuclearity platinum carbonyl clusters: anomalous magnetic behavior
Boon K. Teo, F. J. DiSalvo, J. V. Waszczak, G. Longoni, and A. Ceriotti
pp 2262 - 2265; DOI:
10.1021/ic00233a034
PDF
Novel peroxo complexes of zirconium containing organic ligands
M. T. H. Tarafder and M. A. Latif Miah
pp 2265 - 2268; DOI:
10.1021/ic00233a035
PDF
Transmetalation of tetranuclear copper complexes. 7. Spectral evidence for the substoichiometric transmetalation of (.mu.4-O)[(DENC)Cu]4X6 complexes (DENC = N,N-diethylnicotinamide; X = Cl or Br) by a bis(acetone S-methyl hydrazonecarbodithioato)nickel reagent
Geoffrey Davies, Mohamed A. El-Sayed, and Ahmed El-Toukhy
pp 2269 - 2271; DOI:
10.1021/ic00233a036
PDF
A sequential double Arbuzov-like demethylation of cis-PtX2(P(OMe)3)2 by added halide ion
Christopher King and D. Max Roundhill
pp 2271 - 2273; DOI:
10.1021/ic00233a037
PDF
Synthesis and properties of some ethylenebis(dithiocarbamate) diorganotin(IV) complexes. The structure of [(tert-Bu)2Sn(ebdtc)]2.4THF [tetra-tert-butylbis(ethylenebis(dithiocarbamato)ditin.tetrakis(tetrahydrofuran)]
Ok Sang Jung, Youn Soo Sohn, and James A. Ibers
pp 2273 - 2275; DOI:
10.1021/ic00233a038
PDF
Convenient synthetic route to [Fe2S2(SR)4]2- via reaction of [Fe(SR)4]- with sulfur
Sanghwa Han, Roman S. Czernuszewicz, and Thomas G. Spiro
pp 2276 - 2277; DOI:
10.1021/ic00233a039
PDF
Stereoselectivity induced by an optically active cationic cobalt(III) complex ion on the outer-sphere redox reaction between racemic binuclear molybdenum(V) anions and hexachloroiridate(IV) in water
Yoichi Sasaki, Katsuhiko Meguro, and Kazuo Saito
pp 2277 - 2278; DOI:
10.1021/ic00233a040
PDF

Issue 14


Synthesis of open-framework transition-metal phosphates using organometallic precursors in acidic media. Preparation and structural characterization of Fe5P4O20H10 and NaFe3P3O12
D. R. Corbin, J. F. Whitney, W. C. Fultz, G. D. Stucky, M. M. Eddy, and A. K. Cheetham
pp 2279 - 2280; DOI:
10.1021/ic00234a001
PDF
Quaternized cyclic and high polymeric phosphazenes and their interactions with tetracyanoquinodimethane
Harry R. Allcock, Michael L. Levin, and Paul E. Austin
pp 2281 - 2288; DOI:
10.1021/ic00234a002
PDF
Four- and five-coordinate platinum complexes of divinylphenylphosphine
Mark S. Holt, John H. Nelson, and Nathaniel W. Alcock
pp 2288 - 2295; DOI:
10.1021/ic00234a003
PDF
Structure, conductivity, and magnetic properties of (phthalocyaninato)nickel(II) bromide
Sharon M. Palmer, Judith M. Stanton, Brian M. Hoffman, and James A. Ibers
pp 2296 - 2300; DOI:
10.1021/ic00234a004
PDF
Binuclear molecules incorporating small molecules as bridging ligands. Magnetic properties and molecular structure of [Cu2L(B)]2+ where B = hydroxide or bromide and HL = 2,6-bis(N-(2-pyridylmethyl)formimidoyl)-4-methylphenol
Charles J. O'Connor, Dale Firmin, Arun K. Pant, B. Ram Babu, and Edwin D. Stevens
pp 2300 - 2307; DOI:
10.1021/ic00234a005
PDF
Vanadium(III)-Schiff base complexes: a synthetic and structural study
Sandro Gambarotta, Marinella Mazzanti, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 2308 - 2314; DOI:
10.1021/ic00234a006
PDF
Atomic arrangements and electronic requirements for close-packed circular and spherical clusters
Boon K. Teo and N. J. A. Sloane
pp 2315 - 2322; DOI:
10.1021/ic00234a007
PDF
Systems exhibiting spin equilibrium. Do different chromophores really coexist in the lattice?
M. Bacci
pp 2322 - 2327; DOI:
10.1021/ic00234a008
PDF
Thermodynamics of complexation of lanthanide ions by N-methylethylenediamine-N,N',N'-triacetic acid
E. N. Rizkalla, G. R. Choppin, and W. D. Olieslager
pp 2327 - 2330; DOI:
10.1021/ic00234a009
PDF
Successful photocatalytic reduction of methylviologen (MV2+) with [Cu(NN)(PPh3)2]+ (NN = 2,9-dimethyl-1,10-phenanthroline or 4,4',6,6'-tetramethyl-2,2'-bipyridine) upon near-UV-light irradiation and a novel solvent effect on its catalytic activity
Shigeyoshi Sakaki, Genji Koga, and Katsutoshi Ohkubo
pp 2330 - 2333; DOI:
10.1021/ic00234a010
PDF
Effect of meso substituents on exchange-coupling interactions in .mu.-oxo iron(III) porphyrin dimers
Jeffrey H. Helms, Leonard W. Ter Haar, William E. Hatfield, David L. Harris, K. Jayaraj, Glen E. Toney, Avram Gold, Tabitha D. Mewborn, and Jeanne E. Pemberton
pp 2334 - 2337; DOI:
10.1021/ic00234a011
PDF
Spectroelectrochemistry of (.mu.-oxo)bis[phthalocyaninato)iron(III)]
Lawrence A. Bottomley, Claudio Ercolani, Jean Noel Gorce, Giovanna Pennesi, and Gentilina Rossi
pp 2338 - 2342; DOI:
10.1021/ic00234a012
PDF
Multiple-equilibria model describing the axial ligand dependence of the dioxygen affinity of an iron(II) lacunar complex. An approach to the regulation of dioxygen affinity
Kenneth A. Goldsby, Brian D. Beato, and Daryle H. Busch
pp 2342 - 2347; DOI:
10.1021/ic00234a013
PDF
Kinetic stability of the cysteine adduct with [tris(2-(2-pyridyl)ethyl)amine]copper(II)
Haesun Kang Baek, Kenneth D. Karlin, and Robert A. Holwerda
pp 2347 - 2349; DOI:
10.1021/ic00234a014
PDF
Crystal structures of (glycinamido)- and (glycinato)tetraammineruthenium(III) chelates. Effects of the metal center electronic configuration on coordinated amido and carboxylato groups
Yigal Ilan and Moshe Kapon
pp 2350 - 2354; DOI:
10.1021/ic00234a015
PDF
Complex peroxyuranates. Synthesis and structural assessment of alkali dioxoxperoxy(sulfato)aquouranates(VI), A2[UO2(O2)SO4(H2O)] (A = NH4, Na), and alkali dioxoperoxy(oxalato)uranate(VI) hydrates, A2[UO2(O2)C2O4].H2O
Manish Bhattacharjee, Mihir K. Chaudhuri, and Ranendra N. Dutta Purkayastha
pp 2354 - 2357; DOI:
10.1021/ic00234a016
PDF
Redox and spectral properties of the cis and trans isomers of the bis(2,2'-bipyridine)dioxoosmium(VI) perchlorate
John C. Dobson, Kenneth J. Takeuchi, David W. Pipes, Daniel A. Geselowitz, and Thomas J. Meyer
pp 2357 - 2365; DOI:
10.1021/ic00234a017
PDF
2N framework electron clusters: diamagnetic polyhedral boron chlorides, BnCln (n = 8-12), from the thermal disproportionation of diboron tetrachloride
T. Davan and J. A. Morrison
pp 2366 - 2372; DOI:
10.1021/ic00234a018
PDF
Transmetalation of tetranuclear copper complexes. 8. Transmetalation of tetranuclear copper(I) complexes with a Co(NS)3 reagent
Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Maher Henary, and Thomas R. Gilbert
pp 2373 - 2377; DOI:
10.1021/ic00234a019
PDF
Influence of isomeric form, chelated ring size, and the metal on the oxidation of facial and meridional chromium, molybdenum, and tungsten tricarbonyl bis(bis(diphenylphosphino)methane) and bis(1,2-bis(diphenylphosphino)ethane) complexes
Alan M. Bond, Ray Colton, and Katherine McGregor
pp 2378 - 2384; DOI:
10.1021/ic00234a020
PDF
(Dialkylamido)phosphorus metal carbonyls. 1. Mononuclear derivatives from reactions of bis(diisopropylamino)phosphine with metal carbonyls
R. B. King and W. K. Fu
pp 2384 - 2389; DOI:
10.1021/ic00234a021
PDF
(Dialkylamido)phosphorus metal carbonyls. 2. Bis(diisopropylamino)phosphido and (diisopropylamino)phosphinidene metal carbonyl complexes from reactions of manganese and cobalt carbonyls with bis(diisopropylamino)phosphine
R. B. King, W. K. Fu, and E. M. Holt
pp 2390 - 2394; DOI:
10.1021/ic00234a022
PDF
(Dialkylamido)phosphorus metal carbonyls. 3. Heterobimetallic .mu.-phosphido derivatives from reactions of (diisopropylamino)halophosphine metal carbonyl complexes with sodium cyclopentadienyldicarbonylferrate
R. B. King, W. K. Fu, and E. M. Holt
pp 2394 - 2400; DOI:
10.1021/ic00234a023
PDF
Electron-transfer barriers in cobalt(III) and cobalt(II) bis complexes of 1,4,7-triazacyclononane (tacn) and 1,4,7-trithiacyclononane (ttcn). Crystal structures of [CoII(tacn)2]I2.H2O and of [CoIII(ttcn)2](ClO4)3
Heinz Josef Kueppers, Ademir Neves, Christa Pomp, Dirk Ventur, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 2400 - 2408; DOI:
10.1021/ic00234a024
PDF
Exchange interaction in multinuclear transition-metal complexes. 9. Magnetostructural correlations in one-atom acetato-bridged copper(II) dimers
B. Chiari, J. H. Helms, O. Piovesana, T. Tarantelli, and P. F. Zanazzi
pp 2408 - 2413; DOI:
10.1021/ic00234a025
PDF
Equilibrium quotient for the isomerization of bisulfite ion from HSO3- to SO3H-
David A. Horner and Robert E. Connick
pp 2414 - 2417; DOI:
10.1021/ic00234a026
PDF
Divalent metal ion binding sites on yeast inorganic pyrophosphatase as studied by CW-EPR and electron-spin-echo measurements on the copper(II) enzyme
Amit Banerjee, Russell LoBrutto, and Barry S. Cooperman
pp 2417 - 2424; DOI:
10.1021/ic00234a027
PDF
Band electronic structure of the molybdenum blue bronze A0.30MoO3 (A = K, Rb)
M. H. Whangbo and L. F. Schneemeyer
pp 2424 - 2429; DOI:
10.1021/ic00234a028
PDF
Variable-temperature platinum-195 NMR spectroscopy, a new technique for the study of stereodynamics. Sulfur inversion in a platinum(II) complex with methionine
David D. Gummin, Eva Marie A. Ratilla, and Nenad M. Kostic
pp 2429 - 2433; DOI:
10.1021/ic00234a029
PDF
Nuclear magnetic resonance studies of the solution chemistry of metal complexes. 23. Complexation of methylmercury by selenohydryl-containing amino acids and related molecules
Alan P. Arnold, Khoon Sin Tan, and Dallas L. Rabenstein
pp 2433 - 2437; DOI:
10.1021/ic00234a030
PDF
Electron self-exchange by hexakis(aryl isocyanide)manganese(I/II): concentration, electrotype, and temperature dependences
Roger M. Nielson and Scot Wherland
pp 2437 - 2440; DOI:
10.1021/ic00234a031
PDF
Formation and photophysical properties of iron-ruthenium tetranuclear bipyridyl complexes of the type {[(bpy)2Ru(L-L)]3Fe}
R. H. Schmehl, R. A. Auerbach, W. F. Wacholtz, C. M. Elliott, R. A. Freitag, and J. W. Merkert
pp 2440 - 2445; DOI:
10.1021/ic00234a032
PDF
Redox chemistry of 1,2,4,6-thiatriazinyls: preparation and crystal structures of 3,5-diphenyl-1,2,4,6-thiatriazinium hexafluorophosphate [Ph2C2N3S]+ [PF6]- and 3,5-diphenyl-4-hydro-1,2,4,6-thiatriazine, [Ph2C2N3SH]
Rene T. Boere, A. Wallace Cordes, Patrick J. Hayes, Richard T. Oakley, Robert W. Reed, and William T. Pennington
pp 2445 - 2450; DOI:
10.1021/ic00234a033
PDF
Oxidative alkylation of cobalt complexes with hydrazines
E. G. Samsel and J. K. Kochi
pp 2450 - 2457; DOI:
10.1021/ic00234a034
PDF
Jahn-Teller activity of dx systems in tetrahedral symmetry
Keith D. Warren
pp 2458 - 2460; DOI:
10.1021/ic00234a035
PDF
Chemistry of iron-sulfido [Fe6S6]3+ prismatic cages. Synthesis, structural characterization, and electronic structures of the [Et4N]3[Fe6S6L6] clusters (L = p-CH3C6H4O-, Br-)
M. G. Kanatzidis, A. Salifoglou, and D. Coucouvanis
pp 2460 - 2468; DOI:
10.1021/ic00234a036
PDF
Intramolecular electron transfer in the one-electron oxidation product of (tetraphenylporphinato)nickel(II), as studied by resonance Raman spectroscopy
Dongho Kim, Lisa A. Miller, and Thomas G. Spiro
pp 2468 - 2470; DOI:
10.1021/ic00234a037
PDF
Visible-light production of molecular hydrogen by sensitization of a cobalt dihydride complex
Karen J. Brewer, W. Rorer Murphy, Kathy J. Moore, Eva C. Eberle, and John D. Petersen
pp 2470 - 2472; DOI:
10.1021/ic00234a038
PDF
Lewis basicity of carbonyl oxygen in the presence of a heteroatom: reaction of decacarbonylbismuthtriferrate(1-) with trifluoromethyl methylsulfonate
Kenton H. Whitmire, Craig B. Lagrone, and A. L. Rheingold
pp 2472 - 2474; DOI:
10.1021/ic00234a039
PDF
Reaction of matrix-isolated iron atoms with carbon disulfide
Marca M. Doeff
pp 2474 - 2476; DOI:
10.1021/ic00234a040
PDF
Laser photolysis studies of nickel(II) tetraphenylporphyrin in a mixed solvent of pyridine and toluene in the temperature range 180-300 K
Mikio Hoshino
pp 2476 - 2478; DOI:
10.1021/ic00234a041
PDF
Photoinduced radical formation of bis(phthalocyaninato)lanthanoid(III) in a solvent mixture of dichloromethane and acetonitrile
Kuninobu Kasuga, Hideharu Morimoto, and Motonori Ando
pp 2478 - 2479; DOI:
10.1021/ic00234a042
PDF
Weak chloro complex formation by copper(II) in aqueous chloride solutions
Jannik Bjerrum and L. H. Skibsted
pp 2479 - 2481; DOI:
10.1021/ic00234a043
PDF
Copper(II) complexes with chloride ion
R. W. Ramette
pp 2481 - 2482; DOI:
10.1021/ic00234a044
PDF

Issue 15


Synthesis and crystal structure of tris(dimesitylarsino)gallane, a monomeric tricoordinate gallium-arsenic compound
Colin G. Pitt, Kelvin T. Higa, Andrew T. McPhail, and Richard L. Wells
pp 2483 - 2484; DOI:
10.1021/ic00235a001
PDF
A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper
Gary V. Goeden, John C. Huffman, and Kenneth G. Caulton
pp 2484 - 2485; DOI:
10.1021/ic00235a002
PDF
Numerical analysis of aqueous polysulfide solutions and its application to cadmium chalcogenide/polysulfide photoelectrochemical solar cells
Stuart Licht, Gary Hodes, and Joost Manassen
pp 2486 - 2489; DOI:
10.1021/ic00235a003
PDF
Pentacoordinated molecules. 65. Discrete, dimeric, and polymeric structures of triphenyltin esters of chlorobenzoic acids
Robert R. Holmes, Roberta O. Day, V. Chandrasekhar, Jean F. Vollano, and Joan M. Holmes
pp 2490 - 2494; DOI:
10.1021/ic00235a004
PDF
Pentacoordinated molecules. 66. Chain structures of trimethyltin esters of salicylic acid and o-anisic acid. Tin-119m Moessbauer study of a series of trimethyltin and triphenyltin carboxylates
Peter J. Smith, Roberta O. Day, V. Chandrasekhar, Joan M. Holmes, and Robert R. Holmes
pp 2495 - 2499; DOI:
10.1021/ic00235a005
PDF
Hydridic atom arrangement and bonding in the molecular structure of (C2H5)4N+[Re2(.mu.-H)3H6{CH3C(CH2P(C6H5)2)3}]-.cntdot.CH3CN: a complex containing 10-coordinated rhenium
S. C. Abrahams, A. P. Ginsberg, T. F. Koetzle, S. P. Marsh, and C. R. Sprinkle
pp 2500 - 2510; DOI:
10.1021/ic00235a006
PDF
Syntheses, structures, and circular dichroism spectra of .beta.-Mo2X4(S,S-dppb)2 (X = Cl, Br; S,S-dppb .ident. (2S,3S)-bis(diphenylphosphino)butane)
Pradyot A. Agaskar, F. Albert Cotton, Iain F. Fraser, Ljubica Manojlovic-Muir, Kenneth W. Muir, and Robert D. Peacock
pp 2511 - 2519; DOI:
10.1021/ic00235a007
PDF
Synthesis and reactivity of ruthenium cyclopentadienyl [(.eta.5-C5R5)Ru(.eta.6-arene)]PF6 (R = H, CH3) complexes of naphthalene, anthracene, pyrene, chrysene and azulene. Kinetic studies of arene displacement reactions in acetonitrile solutions
Amy M. McNair and Kent R. Mann
pp 2519 - 2527; DOI:
10.1021/ic00235a008
PDF
Polyaza cavity-shaped molecules. 9. Ruthenium(II) complexes of annelated derivatives of 2,2':6,2"-terpyridine and related systems: synthesis, properties, and structure
Randolph P. Thummel and Yurngdong Jahng
pp 2527 - 2534; DOI:
10.1021/ic00235a009
PDF
Facile addition of small molecules to the osmium carbonyl sulfido cluster Os4(CO)12(.mu.3-S). Syntheses and crystal and molecular structures of Os4(CO)12(NHMe2)(.mu.3-S) and Os4(CO)12(.mu.-H)2(.mu.3-S)
Richard D. Adams and Suning Wang
pp 2534 - 2538; DOI:
10.1021/ic00235a010
PDF
Spin states in iron(III) phthalocyanines studied by Moessbauer, magnetic susceptibility, and ESR measurements
Brendan J. Kennedy, Keith S. Murray, Peter R. Zwack, Heinrich Homborg, and Winfried Kalz
pp 2539 - 2545; DOI:
10.1021/ic00235a011
PDF
Photochemical consequences of the manipulation of the lowest energy excited states by substitution of the Cp (Cp = .eta.5-cyclopentadienyl) ligands in titanium Cp2TiX2 (X = Br, I) complexes
Mitchell R. M. Bruce, Anthony Sclafani, and David R. Tyler
pp 2546 - 2549; DOI:
10.1021/ic00235a012
PDF
Solvent exchange in hexakis(methanol)copper(II) ion. Oxygen-17 NMR variable-temperature, pressure, and frequency study
Lothar Helm, Stephen F. Lincoln, Andre E. Merbach, and Donald Zbinden
pp 2550 - 2552; DOI:
10.1021/ic00235a013
PDF
NMR studies of the reactions of dimethylarsine with (dimethylamino)dimethylarsine and its borane adduct Me2AsNMe2.BH3: synthetic routes to tetramethyldiarsine
Virendra K. Gupta, Larry K. Krannich, and Charles L. Watkins
pp 2553 - 2556; DOI:
10.1021/ic00235a014
PDF
Kinetics and mechanism of molecular A-frame formation. Reactions of cyclo-octasulfur and sulfur dioxide with dichlorobis(.mu.-bis(diphenylphosphino)methane)diplatinum Pt2Cl2(.mu.-Ph2PCH2PPh2)2 and related binuclear platinum complexes
S. Muralidharan, James H. Espenson, and Scott A. Ross
pp 2557 - 2562; DOI:
10.1021/ic00235a015
PDF
Kinetics of reduction of a series of pentaaquo(pyridine)chromium(III) ions by 1-hydroxy-1-methylethyl radicals: evidence for electron transfer to pyridine
Andreja Bakac, Vjera Butkovic, James H. Espenson, Radovan Marcec, and Matko Orhanovic
pp 2562 - 2566; DOI:
10.1021/ic00235a016
PDF
Kinetic studies on the perchlorate oxidation of aqua molybdenum(3+) and Mo(III)2
Elaine F. Hills, Christopher Sharp, and A. Geoffrey Sykes
pp 2566 - 2569; DOI:
10.1021/ic00235a017
PDF
Alkaline hydrolysis of t-ammine[tris(aminoethyl)amine]thiocyanatocobalt(2+) and other t- and p-[Co(tren)(NH3)X]2+ complexes
Margot J. Gaudin, Charles R. Clark, and David A. Buckingham
pp 2569 - 2575; DOI:
10.1021/ic00235a018
PDF
Characterization of perchlorate adduct formation with copper(II)-cyclic polythia ether complexes and determination of corrected stability constants
Ian R. Young, L. A. Ochrymowycz, and D. B. Rorabacher
pp 2576 - 2582; DOI:
10.1021/ic00235a019
PDF
Kinetics and mechanism of the substitution of dibenzoylmethanate for acetylacetonate in the uranyl complex (UO2(acac)2L (L = dimethyl sulfoxide, N,N-dimethylformamide, and trimethyl phosphate)
Woo Sik Jung, Hiroshi Tomiyasu, and Hiroshi Fukutomi
pp 2582 - 2587; DOI:
10.1021/ic00235a020
PDF
Reactions of transition-metal atoms with arenes, arene-functionalized alkanes, oligo(ethylene oxides), and polysiloxanes
Mark P. Andrews and Geoffrey A. Ozin
pp 2587 - 2595; DOI:
10.1021/ic00235a021
PDF
Bis(nitroxyl) adducts of bis(hexafluoroacetylacetonato)manganese(II). Preparation, structures, and magnetic properties
Michael H. Dickman, Leigh C. Porter, and Robert J. Doedens
pp 2595 - 2599; DOI:
10.1021/ic00235a022
PDF
N7/06 chelation in a complex with an analog of guanine. Preparation, spectroscopic study, and crystal structure of bis(.eta.5-cyclopentadienyl)(theophyllinato)titanium(III)
Daniel Cozak, Abdelhakim Mardhy, Marc J. Olivier, and Andre L. Beauchamp
pp 2600 - 2606; DOI:
10.1021/ic00235a023
PDF
Electrochemistry of nitrite reductase model compounds. 2. Formation of an iron bis-nitro porphyrin complex
John B. Fernandes, DiWei Feng, Andrew Chang, Amy Keyser, and Michael D. Ryan
pp 2606 - 2610; DOI:
10.1021/ic00235a024
PDF
Electrochemistry of indium(III) porphyrins in pyridine and in dichloromethane pyridine and dichloromethane/N-methylimidazole mixtures
J. L. Cornillon, J. E. Anderson, and Karl M. Kadish
pp 2611 - 2617; DOI:
10.1021/ic00235a025
PDF
Circularly polarized luminescence from racemic lanthanide(III) complexes with achiral ligands in aqueous solution using circularly polarized excitation
Gary L. Hilmes and James P. Riehl
pp 2617 - 2622; DOI:
10.1021/ic00235a026
PDF
Studies of copper(I) olefin complexes. Formation constants of copper olefin complexes with 2,2'-bipyridine, 1,10-phenanthroline, and their derivatives
Megumu Munakata, Susumu Kitagawa, Shigeru Kosome, and Akio Asahara
pp 2622 - 2627; DOI:
10.1021/ic00235a027
PDF
Hydrolysis of nucleoside phosphates. Part 10. Comparison of the metal ion facilitated hydrolysis for the 5'-triphosphates of 1,N6-ethenoadenosine (.epsilon.-ATP), adenosine (ATP), and cytidine (CTP). Dephosphorylation of .epsilon.-ATP proceeding with zinc(2+) and copper(2+) via structurally different species: evidence for a long-sought, monomeric, back-bound complex with copper(2+)/.epsilon.-ATP
Verena Scheller-Krattiger and Helmut Sigel
pp 2628 - 2634; DOI:
10.1021/ic00235a028
PDF
Cyclic voltammetric study of a series of related mono- and binuclear nickel complexes of .beta.-di- and triketonates and their diamine Schiff bases
R. L. Lintvedt, G. Ranger, and L. Stecher Kramer
pp 2635 - 2637; DOI:
10.1021/ic00235a029
PDF
Metal-nitroxyl interactions. 47. EPR spectra of two-spin-labeled derivatives of EDTA coordinated to paramagnetic metal ions
Kundalika M. More, Gareth R. Eaton, and Sandra S. Eaton
pp 2638 - 2646; DOI:
10.1021/ic00235a030
PDF
Coordination of lanthanides by two polyamino polycarboxylic macrocycles: formation of highly stable lanthanide complexes
M. F. Loncin, J. F. Desreux, and E. Merciny
pp 2646 - 2648; DOI:
10.1021/ic00235a031
PDF
Transformation of a terminal to a bridging carbonyl ligand accompanied by iridium-iridium bond cleavage: an example of transmission of electronic effects from one metal center to another
Martin Cowie, Giuseppe Vasapollo, Bruce R. Sutherland, and Jimmie P. Ennett
pp 2648 - 2653; DOI:
10.1021/ic00235a032
PDF
Steric and electronic effects in associative substitution reactions of dodecacarbonyltetrairidium
Karl Dahlinger, Fernando Falcone, and Anthony J. Poe
pp 2654 - 2658; DOI:
10.1021/ic00235a033
PDF
Steric and electronic effects in cobalt(II) disproportionation with phosphorus ligands
S. M. Socol and J. G. Verkade
pp 2658 - 2663; DOI:
10.1021/ic00235a034
PDF
Estimation of exchange integrals for antiferromagnetically coupled binuclear copper(II) complexes from room-temperature magnetic moments
Laurence K. Thompson and Baratham S. Ramaswamy
pp 2664 - 2665; DOI:
10.1021/ic00235a035
PDF
Crystal structure of bis(p-toluidine)bis(acetonitrile)tetraiodotetracopper: correction of space group
William P. Schaefer
pp 2665 - 2665; DOI:
10.1021/ic00235a036
PDF
Synthesis and characterization of a ruthenium(II) clathrochelate complex
J. G. Muller, J. J. Grzybowski, and K. J. Takeuchi
pp 2665 - 2667; DOI:
10.1021/ic00235a037
PDF
Reaction of nitrosoarenes with trinuclear metal carbonyl clusters of iron, ruthenium, and osmium
Joanne A. Smieja and Wayne L. Gladfelter
pp 2667 - 2670; DOI:
10.1021/ic00235a038
PDF

Issue 16


Ditopic receptors for transition-metal ions: a heterobimetallic nickel(II)-copper(II) bis(macrocyclic) complex and its stepwise oxidation to the tervalent state
Luigi Fabbrizzi, Laura Montagna, Antonio Poggi, Thomas A. Kaden, and Liselotte C. Siegfried
pp 2671 - 2672; DOI:
10.1021/ic00236a001
PDF
Generation and reactions of chiral, pyramidal, transition-metal Lewis acids, .eta.5-cyclopentadienylnitrosyl(triphenylphosphine)rhenium(1+) complexes
Jesus M. Fernandez and J. A. Gladysz
pp 2672 - 2674; DOI:
10.1021/ic00236a002
PDF
Trivalent nickel: sulfur coordination (NiN2O2S2) vs. oxygen coordination (NiN2O4)
Debashis Ray, Samudranil Pal, and Animesh Chakravorty
pp 2674 - 2676; DOI:
10.1021/ic00236a003
PDF
Photolysis of the nitrogen-nitrogen double bond in trioxodinitrate: reaction between triplet oxonitrate(1-) and molecular oxygen to form peroxonitrite
Caroline E. Donald, Martin N. Hughes, Janet M. Thompson, and Francis T. Bonner
pp 2676 - 2677; DOI:
10.1021/ic00236a004
PDF
Substituent effects on the dicarbaborane closo-2,4-C2B5H7 derivative rearrangement rates. Comparison of rearrangement pattern and rate constants of a mixed disubstituted carborane, 5-CH3-6-Cl-2,4-C2B5H5, with those of monosubstituted 5-X-2,4-C2B5H6 and disubstituted 5,6-X2-C2B5H5 (X = CH3, Cl): mechanistic implications and isomer stability correlations
Zahid J. Abdou, Gaby Abdou, Thomas Onak, and Sharon Lee
pp 2678 - 2683; DOI:
10.1021/ic00236a005
PDF
Cobalt-catalyzed evolution of molecular hydrogen
Philip Connolly and James H. Espenson
pp 2684 - 2688; DOI:
10.1021/ic00236a006
PDF
Electrochemical reduction of protonated cyclopentadienylcobalt phosphine complexes
U. Koelle and S. Paul
pp 2689 - 2694; DOI:
10.1021/ic00236a007
PDF
Phosphonitriles: versatile intermediates
Juergen Boeske, Edgar Niecke, Edgar Ocando-Mavarez, Jean Pierre Majoral, and Guy Bertrand
pp 2695 - 2698; DOI:
10.1021/ic00236a008
PDF
Polydentate ligands containing phosphorus. 11. Synthesis of three new anionic tripod ligands, their neutral precursors, and related compounds
Samuel O. Grim, Samuel A. Sangokoya, Ian J. Colquhoun, William McFarlane, and Raj K. Khanna
pp 2699 - 2704; DOI:
10.1021/ic00236a009
PDF
A chronoamperometric and cyclic voltammetric study of the sequential two-electron-transfer process induced in binuclear copper(II) 1,3,5-triketonates by simple cations. Effect of cation variation and ligand substitution on the transfer of two electrons at very similar potentials
R. L. Lintvedt, B. A. Schoenfelner, and K. A. Rupp
pp 2704 - 2707; DOI:
10.1021/ic00236a010
PDF
Possible mechanisms for the isomerization of nonahydrononaborate(2-) and nonahydrodicarbaheptaborane
Benjamin M. Gimarc and Jane J. Ott
pp 2708 - 2711; DOI:
10.1021/ic00236a011
PDF
On the electronic structure of metal tetrahydroborates: quasi-relativistic X.alpha.-SW study of M(BH4)4 (M = zirconium, hafnium, thorium, uranium)
D. Hohl and N. Roesch
pp 2711 - 2718; DOI:
10.1021/ic00236a012
PDF
Photoelectron spectra of metal tetrakis(methyltrihydroborates) and thorium tetrakis(tetrahydroborate)
Jennifer C. Green, Ron Shinomoto, and Norman Edelstein
pp 2718 - 2720; DOI:
10.1021/ic00236a013
PDF
Coordination geometries and relative donor-acceptor abilities of CX and X2 (X = O, S, Se, Te) and CX2 and H2CX (X = O, S) complexed to Ru(CO)4. Theoretical study by the Hartree-Fock-Slater transition-state method
Tom Ziegler
pp 2721 - 2727; DOI:
10.1021/ic00236a014
PDF
Calculated spectra of hydrated ions of the first transition-metal series
Wayne P. Anderson, W. Daniel Edwards, and Michael C. Zerner
pp 2728 - 2732; DOI:
10.1021/ic00236a015
PDF
Circular dichroism of chromium(III) complexes. 11. Chiroptical evidence for solution structure of a sexidentate chelate coordination mode in chromium(III) complexes with EDTA and related ligands
Sumio Kaizaki and Hitomi Mizuuchi
pp 2732 - 2736; DOI:
10.1021/ic00236a016
PDF
Single-crystal polarized electronic absorption spectra and ligand field parameters for triphenylphosphine and triphenylarsine in platinum PtCl3L- complexes
Tsu Hsin Chang and Jeffrey I. Zink
pp 2736 - 2741; DOI:
10.1021/ic00236a017
PDF
ESR and ENDOR study of the electronic structure of the radical anion [[CH3N(PF2)2]3Co2(CO)2]- dicarbonyltris[bis(difluorophosphino)methylamine]dicobaltate(1-)
F. Babonneau and J. Livage
pp 2741 - 2745; DOI:
10.1021/ic00236a018
PDF
Kinetic aspects of the iron(III)- and iron(II)-tetrakis(N-methylpyridinium-4-yl)porphine systems
G. A. Tondreau and R. G. Wilkins
pp 2745 - 2750; DOI:
10.1021/ic00236a019
PDF
FT-IR and fluorometric investigation of rare-earth and metallic ion solutions. 7. FT-IR investigation of the interaction between perchlorate and trivalent neodymium, europium, terbium, and erbium ions in anhydrous acetonitrile
Jean Claude G. Buenzli and Catherine Mabillard
pp 2750 - 2754; DOI:
10.1021/ic00236a020
PDF
Characterization of the binding, kinetics, and redox stability of vanadium(IV) and vanadium(V) protein complexes in serum
N. Dennis Chasteen, John K. Grady, and Clive E. Holloway
pp 2754 - 2760; DOI:
10.1021/ic00236a021
PDF
Complexation of copper(II) with a macrocyclic peptide containing histidyl residues: novel observation of NMR spectra of paramagnetic copper(II) compounds
Jean Pierre Laussac, Anne Robert, Raymond Haran, and Bibudhendra Sarkar
pp 2760 - 2765; DOI:
10.1021/ic00236a022
PDF
Oxygen atom transfer in the oxidation of triphenylphosphine by molecular oxygen catalyzed by a ruthenium(III)-EDTA-triphenylphosphine complex
M. M. Taqui Khan, M. R. H. Siddiqui, Amjad Hussain, and M. A. Moiz
pp 2765 - 2771; DOI:
10.1021/ic00236a023
PDF
Synthesis of 1-(p-isothiocyanatobenzyl) derivatives of DTPA and EDTA. Antibody labeling and tumor-imaging studies
Martin W. Brechbiel, Otto A. Gansow, Robert W. Atcher, Jeffrey Schlom, Jose Esteban, Diane Simpson, and David Colcher
pp 2772 - 2781; DOI:
10.1021/ic00236a024
PDF
X-ray absorption studies of the purple acid phosphatase from beef spleen
S. M. Kauzlarich, B. K. Teo, T. Zirino, S. Burman, J. C. Davis, and B. A. Averill
pp 2781 - 2785; DOI:
10.1021/ic00236a025
PDF
The second isomer of dichloro(2,2'-bipyridine)iron(II): syntheses and spectroscopic and magnetic characterizations of three related dichloro(.alpha.-diimine)iron(II) complexes containing five-coordinate, high-spin iron(II)
Francis F. Charron and William Michael Reiff
pp 2786 - 2790; DOI:
10.1021/ic00236a026
PDF
New route to bimetallic imidazolate-bridged complexes. 1. Synthesis and solid-state properties of an homodinuclear (copper-copper) complex and its heterodinuclear (copper-nickel) homolog. Structure of the heterodinuclear complex
Jean Pierre Costes, Jean Francois Serra, Francoise Dahan, and Jean Pierre Laurent
pp 2790 - 2795; DOI:
10.1021/ic00236a027
PDF
Coordination mode of tris(2-pyridyl)carbinol to cobalt(III): crystal structure of Li[Co{(2-py)3COH}2](S2O6)2.cntdot.10H2O
David J. Szalda and F. Richard Keene
pp 2795 - 2799; DOI:
10.1021/ic00236a028
PDF
Structural and theoretical discussion of tridecacarbonyltetrabismuthtetraferrate(2-): application of MO and Teo electron counting theories to a Zintl-metal carbonylate
Kenton H. Whitmire, Thomas A. Albright, Sung Kwon Kang, Melvyn Rowen Churchill, and James C. Fettinger
pp 2799 - 2805; DOI:
10.1021/ic00236a029
PDF
An unusual hydrogen bond between oxygen atoms: preparation and characterization of tetrabutylammonium hydrogen bis(pentafluorooxotellurate)
Steven H. Strauss, Kent D. Abney, and Oren P. Anderson
pp 2806 - 2812; DOI:
10.1021/ic00236a030
PDF
Synthesis and structure of metal complexes of triaza macrocycles with three pendant pyridylmethyl arms
Lise Christiansen, David N. Hendrickson, Hans Toftlund, Scott R. Wilson, and Chuan Liang Xie
pp 2813 - 2818; DOI:
10.1021/ic00236a031
PDF
Magnetic exchange interactions in some novel .mu.-azido-bridged copper(II) dimers. Crystal structures of [L2Cu2(.mu.-N3)(N3)2](ClO4).cntdot.H2O, LCu(N3)2, [L2Cu2(.mu.-N3)2(ClO4)2], and L'Cu(N3)2 (L = N,N',N"-trimethyl-1,4,7-triazacyclononane and L' = 1,4,7-triazacyclononane)
Phalguni Chaudhuri, Karen Oder, Karl Wieghardt, Bernhard Nuber, and Johannes Weiss
pp 2818 - 2824; DOI:
10.1021/ic00236a032
PDF
Crystal and molecular structure of a lithium-C222B cryptate complex isolated from N-butylpyridinium chloride-aluminum(III) chloride molten salt medium
Donald L. Ward, Rick R. Rhinebarger, and Alexander I. Popov
pp 2825 - 2827; DOI:
10.1021/ic00236a033
PDF
The chlorofluorophosphoranes PClnF5-n (n = 1-4). Gas-phase structures and vibrational analyses
C. Macho, R. Minkwitz, J. Rohmann, B. Steger, V. Woelfel, and H. Oberhammer
pp 2828 - 2835; DOI:
10.1021/ic00236a034
PDF
Solution structure of chromium [CrIII(L)(O-O)]n complexes (L = nitrilotriacetate, N,N-.beta.-alaninediacetate; O-O = malonate, oxalate, acetylacetonate, 2H2O) and characterization of (.mu.-OH)2[Cr(nta)(OH)]22- by deuteron NMR spectroscopy
Norio Koine, Robert J. Bianchini, and J. Ivan Legg
pp 2835 - 2841; DOI:
10.1021/ic00236a035
PDF
Conformational characterization of the stereoisomers of a nickel(II) macrocyclic tetraamine complex
Jy Wann Chen and Chung Sun Chung
pp 2841 - 2846; DOI:
10.1021/ic00236a036
PDF
Vibrational spectroscopic studies of .mu.-hydrido-bridged metal clusters. 1. Dodecacarbonyltrihydridotrimanganese
Martin W. Howard, Philip Skinner, Raj K. Bhardwaj, Upali A. Jayasooriya, Donald B. Powell, and Norman Sheppard
pp 2846 - 2850; DOI:
10.1021/ic00236a037
PDF
Vibrational spectroscopic studies of .mu.-hydrido-bridged metal clusters. 2. Resonance Raman spectrum of dodecacarbonyltrihydridotrimanganese and likely excited-state geometry
Upali A. Jayasooriya and Philip Skinner
pp 2850 - 2852; DOI:
10.1021/ic00236a038
PDF
Vibrational spectroscopic studies of .mu.-hydrido-bridged metal clusters. 3. Dodecacarbonyltrihydridotrirhenium
Upali A. Jayasooriya, Stephen J. Stotesbury, Roger Grinter, Donald B. Powell, and Norman Sheppard
pp 2853 - 2857; DOI:
10.1021/ic00236a039
PDF
Factors affecting aluminum-carbon bond reactivity of tetradentate Schiff-base organoaluminum complexes
Sharlene J. Dzugan and Virgil L. Goedken
pp 2858 - 2864; DOI:
10.1021/ic00236a040
PDF
Trans influence across a rhodium-rhodium bond. Effect of a series of Lewis bases on the stretching frequency of coordinated carbon monoxide
Carl Bilgrien, Russell S. Drago, Glenn C. Vogel, and James Stahlbush
pp 2864 - 2866; DOI:
10.1021/ic00236a041
PDF
Electrochemical, spectral, and base-binding studies of heterodinuclear ruthenium-iron complexes of meso-.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(nicotinamidophenyl)porphine
C. Michael Elliott and J. Kenneth Arnette
pp 2867 - 2872; DOI:
10.1021/ic00236a042
PDF
UV photoelectron spectra and pseudopotential ab initio calculations on trans-dihalobis(triethylphosphine)platinum complexes (halo = chloro, bromo, iodo)
Giovanni Zangrande, Gaetano Granozzi, Maurizio Casarin, Jean Pierre Daudey, and Domenico Minniti
pp 2872 - 2877; DOI:
10.1021/ic00236a043
PDF
Dinuclear iron, ruthenium, and cobalt complexes with carbon- and sulfur-bonded bridging C(SR)2 carbene ligands
John R. Matachek and Robert J. Angelici
pp 2877 - 2883; DOI:
10.1021/ic00236a044
PDF
Bidentate and unidentate formato ligands in dicarbonylbis(formato)bis(triethylphosphine)molybdenum
Douglas C. Brower, Paul B. Winston, Teresa L. Tonker, and Joseph L. Templeton
pp 2883 - 2888; DOI:
10.1021/ic00236a045
PDF
Cobalt(II) cyanides in aprotic media: effect of varying counterion and solvent
Stephen J. Carter, Bruce M. Foxman, and Louis S. Stuhl
pp 2888 - 2894; DOI:
10.1021/ic00236a046
PDF
Deprotonation of molybdenum carbonyl hydrido diphosphine [HMo(CO)2(PP)2]BF4 complexes: hard anions as proton carriers
Marcetta Y. Darensbourg and Maria M. Ludvig
pp 2894 - 2898; DOI:
10.1021/ic00236a047
PDF
Mechanistic study on the complex formation of aluminum(III), gallium(III), and indium(III) ions in dimethyl sulfoxide and N,N-dimethylformamide
Koji Ishihara, Shigenobu Funahashi, and Motoharu Tanaka
pp 2898 - 2901; DOI:
10.1021/ic00236a048
PDF
Tridentate facially coordinated L-aspartate ion complexation with the copper(II) ion: spectroscopic and structural properties of aqua(L-aspartato)(1,10-phenanthroline)copper(II) tetrahydrate
L. Antolini, L. P. Battaglia, A. Bonamartini Corradi, G. Marcotrigiano, L. Menabue, G. C. Pellacani, M. Saladini, and M. Sola
pp 2901 - 2904; DOI:
10.1021/ic00236a049
PDF
Metal complexes in acetic acid. 9. Kinetic study of acetic acid exchange on manganese(II), cobalt(II), and copper(II) acetates in acetic acid by oxygen-17 nuclear magnetic resonance
Akiharu Hioki, Shigenobu Funahashi, and Motoharu Tanaka
pp 2904 - 2907; DOI:
10.1021/ic00236a050
PDF
Ring-substituted derivatives of .eta.5-cyclopentadienyltetracarbonylvanadium: synthesis and vanadium-51 NMR spectroscopic characteristics
Martin Hoch, Andreas Duch, and Dieter Rehder
pp 2907 - 2909; DOI:
10.1021/ic00236a051
PDF
Preparative-scale matrix isolation: application to the direct synthesis of binary metal carbonyls using metal atomic reagents
John Godber, Helmut X. Huber, and Geoffrey A. Ozin
pp 2909 - 2910; DOI:
10.1021/ic00236a052
PDF
Multielectron-photoinduced reduction of chloroplatinum complexes: visible light deposition of platinum metal
Randy E. Cameron and Andrew B. Bocarsly
pp 2910 - 2913; DOI:
10.1021/ic00236a053
PDF
A new form of ruthenium tetracarbonyl
W. Ross Hastings and Michael C. Baird
pp 2913 - 2915; DOI:
10.1021/ic00236a054
PDF
Differentiation between metal-metal stretching and ligand-sensitive vibrations in dimetal tetraacetates by ligand deuteration
Andrew J. Hempleman, Robin J. H. Clark, and Colin D. Flint
pp 2915 - 2916; DOI:
10.1021/ic00236a055
PDF
Synthesis and molecular structure of hexacarbonyl-.mu.-iodo(.mu.-diphenylphosphido)diosmium. High-yield syntheses of hexacarbonyldi-.mu.-iododiosmium and octacarbonyldiiododiosmium
Gregory L. Geoffroy, Steven Rosenberg, Albert W. Herlinger, and Arnold L. Rheingold
pp 2916 - 2919; DOI:
10.1021/ic00236a056
PDF
Oxide-dependent deposition and hydrogen-promoted aggregation of organorhodium complexes
Gregory S. McNulty, Kevin Cannon, and Jeffrey Schwartz
pp 2919 - 2922; DOI:
10.1021/ic00236a057
PDF

Issue 17


Synthesis and structure of trans-bis[[pentacarbonyl(N-(2-((diphenylphosphino)aminoethyl)salicylaldiminato-P)]molybdenum(0)-N,O]copper(II): a novel trimetallic complex with a mixed P-donor-Schiff-base bridging ligand
Gary M. Gray, Alan L. Zell, and Howard Einspahr
pp 2923 - 2925; DOI:
10.1021/ic00237a001
PDF
Magnetic circular dichroism spectra for the tetraammineplatinum(II) and bis(ethylenediamine)platinum(II) cations
W. Roy Mason
pp 2925 - 2929; DOI:
10.1021/ic00237a002
PDF
Synthesis, structural characterization, and magnetic properties of vanadium(3+) dimer compounds. Neutron scattering and magnetic circular dichroism study of cesium chlorovanadate (Cs3V2Cl9) and rubidium bromovanadate (Rb3V2Br9)
Bruno Leuenberger, Bernard Briat, Jean Claude Canit, Albert Furrer, Peter Fischer, and Hans U. Guedel
pp 2930 - 2935; DOI:
10.1021/ic00237a003
PDF
Further study of the low-temperature magnetic properties of the complex bimetallic salt hexaamminecobalt hexachloroferrate(3-)
J. H. Zhang, William M. Reiff, Jeffrey H. Helms, William E. Hatfield, N. Dixon, and L. Fritz
pp 2936 - 2939; DOI:
10.1021/ic00237a004
PDF
Synthesis and tin-119 Moessbauer spectra of novel cationic tin(II) and dimethyltin(IV) compounds
S. P. Mallela, S. T. Tomic, K. Lee, J. R. Sams, and F. Aubke
pp 2939 - 2946; DOI:
10.1021/ic00237a005
PDF
Single-crystal luminescence study of the layered compound potassium dicyanoaurate
N. Nagasundaram, G. Roper, J. Biscoe, J. W. Chai, H. H. Patterson, N. Blom, and A. Ludi
pp 2947 - 2951; DOI:
10.1021/ic00237a006
PDF
Variable-temperature single-crystal electron spin resonance study and crystal structure of bis(1,4,7-triazacyclononane)copper(2+) tricyanocuprate(2-) dihydrate at 110 and 293 K. Static and dynamic Jahn-Teller distortions in the CuN6 polyhedron
Phalguni Chaudhuri, Karen Oder, Karl Wieghardt, Johannes Weiss, Jan Reedijk, Winfried Hinrichs, John Wood, Andrej Ozarowski, Horst Stratemaier, and Dirk Reinen
pp 2951 - 2958; DOI:
10.1021/ic00237a007
PDF
Crystal structure, Moessbauer spectra, and magnetic properties of bis[N-(1-acetyl-2-propylidene)(2-pyridylmethyl)aminato]iron(1+) hexafluorophosphate and crystallographic changes in fast electronic relaxation between S = 1/2 and S = 5/2
Yonezo Maeda, Hiroki Oshio, Yoshimasa Takashima, Masahiro Mikuriya, and Masanori Hidaka
pp 2958 - 2962; DOI:
10.1021/ic00237a008
PDF
Structure-NMR correlations in halo(ligand)bis(dioximato)cobalt(III) complexes
Concepcion Lopez, Santiago Alvarez, Xavier Solans, and Manuel Font-Altaba
pp 2962 - 2969; DOI:
10.1021/ic00237a009
PDF
Stereochemistry and metal-centered rearrangements of eight-coordinate niobium(V) and tantalum(V) dithiocarbamates and monothiocarbamates
John R. Weir and Robert C. Fay
pp 2969 - 2976; DOI:
10.1021/ic00237a010
PDF
Photochemical disproportionation of decacarbonyldimanganese. Nineteen-electron intermediates and ligand and intensity dependence
Albert E. Stiegman, Alan S. Goldman, Cecelia E. Philbin, and David R. Tyler
pp 2976 - 2979; DOI:
10.1021/ic00237a011
PDF
Solution chemistry of ethane-1,2-dithiolate complexes: equilibria and electron-transfer reactions
R. N. Mukherjee, C. Pulla Rao, and R. H. Holm
pp 2979 - 2989; DOI:
10.1021/ic00237a012
PDF
Solution chemistry of rhodium trifluoroacetate in the presence of phosphorus donors
Joshua Telser and Russell S. Drago
pp 2989 - 2992; DOI:
10.1021/ic00237a013
PDF
Small macrocyclic ligands with mixed nitrogen- and oxygen-donor atoms
Vivienne J. Thom, M. Salim Shaikjee, and Robert D. Hancock
pp 2992 - 3000; DOI:
10.1021/ic00237a014
PDF
Structure and dynamic behavior in solution of binuclear nickel(II) face-to-face complexes with bis(cyclidene) ligands
Naomi Hoshino, Kenneth A. Goldsby, and Daryle H. Busch
pp 3000 - 3006; DOI:
10.1021/ic00237a015
PDF
Multifrequency ESR of copper(II)-(His)n (His = histidine). 1. Immobile phase
Riccardo Basosi, Gianni Valensin, Elena Gaggelli, Wojciech Froncisz, Marta Pasenkiewicz-Gierula, William E. Antholine, and James S. Hyde
pp 3006 - 3010; DOI:
10.1021/ic00237a016
PDF
Moessbauer and EPR studies of a synthetic analog for the iron-sulfur Fe4S4 core of oxidized and reduced high-potential iron proteins
Vasilios Papaefthymiou, Michelle M. Millar, and Eckard Muenck
pp 3010 - 3014; DOI:
10.1021/ic00237a017
PDF
Convenient synthesis and properties of (R4N)2[Ni(SAr)4] (Ar = C6H5, p-C6H4Cl, p-C6H4CH3, and m-C6H4Cl) and the structure of tetraethylammonium tetrakis(p-chlorobenzenethiolato)nickelate(II)
Steven G. Rosenfield, William H. Armstrong, and Pradip K. Mascharak
pp 3014 - 3018; DOI:
10.1021/ic00237a018
PDF
Assimilatory and dissimilatory reduction of nitrate and nitrite with a tris(tetrabutylammonium) nonakis(benzenethiolato)octasulfidohexaferratedimolybdate(3-) modified glassy-carbon electrode in water
Susumu Kuwabata, Satoshi Uezumi, Koji Tanaka, and Toshio Tanaka
pp 3018 - 3022; DOI:
10.1021/ic00237a019
PDF
Equilibrium and electrochemical studies on the ruthenium complexes formed by the interaction of K[Ru(EDTA-H)Cl].cntdot.2H2O with oxygen and hydrogen peroxide
M. M. Taqui Khan, Amjad Hussain, G. Ramachandraiah, and M. A. Moiz
pp 3023 - 3030; DOI:
10.1021/ic00237a020
PDF
Oxidative-addition/addition reactions of perfluoro-tert-butyl hypochlorite with perfluoromono- or -diiodoalkanes, pentafluoroiodobenzene, and hexafluorobenzene
Jo Ann M. Canich, Megan E. Lerchen, Gary L. Gard, and Jean'ne M. Shreeve
pp 3030 - 3033; DOI:
10.1021/ic00237a021
PDF
Hexaamminecobalt electron-self-exchange reaction
Sven Larsson, Kenny Staahl, and Michael C. Zerner
pp 3033 - 3037; DOI:
10.1021/ic00237a022
PDF
Mechanisms of ligand-to-metal intramolecular electron transfer in cobalt(III)-amine complexes containing a coordinated radical
Kevin D. Whitburn, Morton Z. Hoffman, Nina V. Brezniak, and Michael G. Simic
pp 3037 - 3043; DOI:
10.1021/ic00237a023
PDF
Micellar effects on the kinetics of the aquation and the base hydrolysis of tris(1,10-phenanthroline)iron(II) and chloropentaamminecobalt(III) ions
Satoshi Tachiyashiki and Hideo Yamatera
pp 3043 - 3047; DOI:
10.1021/ic00237a024
PDF
Effects of alcohols on kinetics of substitution at cis-bis(pyridine)tetracarbonylmolybdenum(0)
Horst Elias, Hans Tobias Macholdt, Klaus J. Wannowius, Michael J. Blandamer, John Burgess, and Barbara Clark
pp 3048 - 3053; DOI:
10.1021/ic00237a025
PDF
.pi.-Arene complexes. 3. End-to-end bridging thiocarbonyl complexes. Crystal and molecular structure of (.eta.6-toluene)heptacarbonyl(thiocarbonyl)dichromium
Simon Lotz, Rainer R. Pille, and Petrus H. Van Rooyen
pp 3053 - 3057; DOI:
10.1021/ic00237a026
PDF
Crystal structures and magnetic properties of .mu.-phenolato copper(II) binuclear complexes with hydroxo, azido, and cyanato-O exogenous bridges
Talal Mallah, Marie Laure Boillot, Olivier Kahn, Jacqueline Gouteron, Suzanne Jeannin, and Yves Jeannin
pp 3058 - 3065; DOI:
10.1021/ic00237a027
PDF
Characterization of [rac-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane]copper(II) 3-sulfidopropionate dimethanolate, [Cu(tet b)SCH2CH2CO2].2CH3OH, a stable copper(II)-aliphatic thiolate complex
Elizabeth John, Parimal K. Bharadwaj, Joseph A. Potenza, and Harvey J. Schugar
pp 3065 - 3069; DOI:
10.1021/ic00237a028
PDF
Counter ligand dependence of charge distribution in copper-quinone complexes. Structural and magnetic properties of (3,5-di-tert-butylcatecholato)(bipyridine)copper(II)
Robert M. Buchanan, Cheryl Wilson-Blumenberg, Charles Trapp, Scott K. Larsen, David L. Greene, and Cortlandt G. Pierpont
pp 3070 - 3076; DOI:
10.1021/ic00237a029
PDF
Synthesis and IR, UV, NMR (1H and 11B), and mass spectral studies of new .beta.-ketoamine complexes of boron: crystal an molecular structure of OC6H4OBOC(R)CHC(R')NR" (R = p-ClC6H4, R' = C6H5, R" = CH3)
Yash P. Singh, P. Rupani, Anirudh Singh, Audhesh K. Rai, Ram C. Mehrotra, Robin D. Rogers, and Jerry L. Atwood
pp 3076 - 3081; DOI:
10.1021/ic00237a030
PDF
Organotin intercalation compounds of iron chloride oxide (FeOCl): synthesis, iron-57 and tin-119m Moessbauer and infrared spectroscopy, and powder x-ray diffraction studies
J. E. Phillips and R. H. Herber
pp 3081 - 3088; DOI:
10.1021/ic00237a031
PDF
Observations on the formation of undecacarbonylhydridoferrate(1-) on hydroxylated .gamma.-alumina
Brian E. Hanson, Joseph J. Bergmeister, John T. Petty, and Melissa C. Connaway
pp 3089 - 3092; DOI:
10.1021/ic00237a032
PDF
Effect of pressure on the photochemical formation and thermal back-isomerization of a sulfinato-O complex of cobalt(III)
W. Weber, H. Maecke, and R. Van Eldik
pp 3093 - 3095; DOI:
10.1021/ic00237a033
PDF
Fluorides and fluoro acids. 10. Crystal structures of acid hydrates and oxonium salts. 23. Crystal structure of the low-temperature form of oxonium hexafluoroarsenate(V)
Dietrich Mootz and Michael Wiebcke
pp 3095 - 3097; DOI:
10.1021/ic00237a034
PDF
Binuclear complexes of platinum(II) and palladium(II) with bis(isopropylphosphino)methane and related ligands
Wanda Radecka-Paryzek, Alistair J. McLennan, and Richard J. Puddephatt
pp 3097 - 3100; DOI:
10.1021/ic00237a035
PDF
Insertion of tin dichloride into an osmium-osmium bond of undecarbonyl(.mu.-methylidene)triosmium to give the planar cluster Os3SnCl2(CO)11(.mu.-CH2) with a pentacoordinate tin atom
Nathan Viswanathan, Eric D. Morrison, Gregory L. Geoffroy, Steven J. Geib, and Arnold L. Rheingold
pp 3100 - 3102; DOI:
10.1021/ic00237a036
PDF
Oxidative addition reactions of potassium tetrachloroplatinate(II) with N,N-dialkylacetamides under mild reaction conditions. Synthesis of [cis-Pt(CH2N(CH3)C(CH3)O)2-trans-Cl2] and [trans-Pt(OC(CH3)N(CH3)2)2-trans-Cl2]
R. M. Roat, S. Yolles, and A. L. Rheingold
pp 3102 - 3105; DOI:
10.1021/ic00237a037
PDF
Oxidative chlorination of aldehydes and ketones by molybdenum(IV): a synthetic route to molybdenum(III) halide complexes
ShiYoung Roh and Joseph W. Bruno
pp 3105 - 3106; DOI:
10.1021/ic00237a038
PDF
Effects of mixed-ligand complexation on the geometry of copper(II) complexes. X-ray study of (hexafluoroacetylacetonato)(acetylacetonato)copper(II)
P. C. Le Brun, W. D. Lyon, and Henry A. Kuska
pp 3106 - 3108; DOI:
10.1021/ic00237a039
PDF
Characterization of hexacarbonyl(hexahydrotriborato)diferrate(1-): a comment on the dynamic structure of hexacarbonyl(heptahydrotriborato)diiron
Catherine E. Housecroft
pp 3108 - 3110; DOI:
10.1021/ic00237a040
PDF

Issue 18


Heteronuclear NMR studies of cobalamins. 5. Proton-coupled phosphorus-31 NMR
Kenneth L. Brown
pp 3111 - 3113; DOI:
10.1021/ic00238a001
PDF
Synthesis and x-ray crystal structure of (dicyanodihydroborato)bis(triphenylphosphine)copper(I): a new linear polymer
Karen W. Morse, David G. Holah, and Mamoru Shimoi
pp 3113 - 3114; DOI:
10.1021/ic00238a002
PDF
Oxidative microelectrode voltammetry of tetraphenylporphyrin and copper tetraphenylporphyrin in toluene solvent
L. Geng and Royce W. Murray
pp 3115 - 3120; DOI:
10.1021/ic00238a003
PDF
Synthesis of [bis(salicylaldehyde)ethylenediiminato]diphenylvanadium(IV)-methanol, a novel organovanadium compound
R. Seangprasertkij and Thomas L. Riechel
pp 3121 - 3124; DOI:
10.1021/ic00238a004
PDF
Organometallic crown ethers. 2. Syntheses of phosphino aza crown ether ligands
Stephan J. McLain
pp 3124 - 3127; DOI:
10.1021/ic00238a005
PDF
New perfluoroalkylphosphonic and bis(perfluoroalkyl)phosphinic acids and their precursors
Tariq Mahmood and Jean'ne M. Shreeve
pp 3128 - 3131; DOI:
10.1021/ic00238a006
PDF
Kinetics of the reaction of nitric oxide with sulfite and bisulfite ions in aqueous solution
David Littlejohn, K. Y. Hu, and S. G. Chang
pp 3131 - 3135; DOI:
10.1021/ic00238a007
PDF
Reactions of oxygen with hemerythrin, myoglobin and hemocyanin: effects of deuterium oxide on equilibration rate constants and evidence for hydrogen-bonding
Graeme D. Armstrong and A. Geoffrey Sykes
pp 3135 - 3139; DOI:
10.1021/ic00238a008
PDF
Reactions of the metallodrug auranofin [(1-thio-.beta.-D-glucopyranose-2,3,4,6-tetraacetato-S)(triethylphosphine)gold] with biological ligands studied by radioisotope methodology
D. J. Ecker, J. C. Hempel, B. M. Sutton, R. Kirsch, and S. T. Crooke
pp 3139 - 3143; DOI:
10.1021/ic00238a009
PDF
Kinetic studies on substitution reactions of Delepine's triangular mixed-valence iridium(III, IV, IV) complex triaqua(.mu.3-nitrido)(hexa-.mu.-sulfato)triiridate(4-)
Elaine F. Hills, David T. Richens, and A. Geoffrey Sykes
pp 3144 - 3148; DOI:
10.1021/ic00238a010
PDF
Redox and spectral properties of cobalt(II) and copper(II) tetraazaannulene complexes: {H2[Me4(RBzo)2[14]tetraeneN4]} (R = H, CO2CH3). Evidence for superoxide ligation and reduction
Cynthia L. Bailey, Robert D. Bereman, and D. Paul Rillema
pp 3149 - 3153; DOI:
10.1021/ic00238a011
PDF
Acyclic polythioether complexes: preparation and crystal structure of tricarbonyl(2,5,8-trithianonane)molybdenum(0)
Michael T. Ashby, John H. Enemark, Dennis L. Lichtenberger, and Richard B. Ortega
pp 3154 - 3157; DOI:
10.1021/ic00238a012
PDF
Proton and carbon-13 NMR spectra of a series of methyl-substituted imidazole complexes of pentaamminecobalt(III) and crystal structure of the remote isomer of [(4-methylimidazole)pentaamminecobalt(III)] trichloride dihydrate
Wayne W. Henderson, Rex E. Shepherd, and Jaime Abola
pp 3157 - 3163; DOI:
10.1021/ic00238a013
PDF
Molecular structures of zinc dichloride, zinc dibromide, and zinc diiodide from electron diffraction reinvestigation
Magdolna Hargittai, J. Tremmel, and Istvan Hargittai
pp 3163 - 3166; DOI:
10.1021/ic00238a014
PDF
Solid-state kinetic parameters for the deaquation-anation of the double complex salts pentaammineaquacobalt(3+) acidopentacyanocobaltate (acido = CN, Cl, Br, I, NO2, N3) and the preparation of dinuclear derivatives with .mu.-cyano bridges
J. Casabo, T. Flor, F. Teixidor, and J. Ribas
pp 3166 - 3171; DOI:
10.1021/ic00238a015
PDF
Low-dimensional bimetallic ordered systems: synthesis and characterization of the isomorphous series of the cobalt nickel complexes CoxNi2-xEDTA.2H20. Crystal structure of Co2EDTA.2H20 and preferential site occupation in CoNiEDTA.H20
Pedro Gomez-Romero, Geoffrey B. Jameson, Nieves Casan-Pastor, Eugenio Coronado, and Daniel Beltran
pp 3171 - 3176; DOI:
10.1021/ic00238a016
PDF
Reactive E:C (p-p) systems. 7. Gas-phase structures of perfluoro-2-phosphapropene, CF3P:CF2, and its cyclic dimer, (CF3PCF2)2
Bernd Steger, Heinz Oberhammer, Joseph Grobe, and Le Van Duc
pp 3177 - 3181; DOI:
10.1021/ic00238a017
PDF
EPR evidence for an unexpected symmetric dinuclear species present in the lattice of an asymmetric dinuclear copper complex
Alessandro Bencini, Dante Gatteschi, Claudia Zanchini, Olivier Kahn, Michel Verdaguer, and Miguel Julve
pp 3181 - 3183; DOI:
10.1021/ic00238a018
PDF
Crown ether complexed ion pairs: solution and solid-state structures of the (2S,6S)-2,6-dimethyl-1,4,7,10,13,16-hexaoxacyclooctadecane complex of potassium nitrate
R. Brian Dyer, Robert G. Ghirardelli, Richard A. Palmer, and Elizabeth M. Holt
pp 3184 - 3188; DOI:
10.1021/ic00238a019
PDF
(Diethoxyphosphoryl)phosphines as ligands toward molybdenum hexacarbonyl
Mark M. Turnbull, Edward H. Wong, Eric J. Gabe, and Florence L. Lee
pp 3189 - 3194; DOI:
10.1021/ic00238a020
PDF
Magnetic circular dichroism of cyclic .pi.-electron systems. 28. Sulfur-nitrogen heterocycles
Heinz Peter Klein, Richard T. Oakley, and Josef Michl
pp 3194 - 3201; DOI:
10.1021/ic00238a021
PDF
Solid-state phosphorus-31 cross-polarization magic-angle spinning NMR study of phosphine complexes of mercury(II)
Tim Allman and R. E. Lenkinski
pp 3202 - 3204; DOI:
10.1021/ic00238a022
PDF
FTIR spectra of dialkyl sulfide and alkanethiol complexes with hydrogen fluoride in solid argon
Lester Andrews, Robert T. Arlinghaus, and Rodney D. Hunt
pp 3205 - 3209; DOI:
10.1021/ic00238a023
PDF
Hydrophobic and steric effects on the ion-pair formation of tris(1,10-phenanthroline)iron(II) and arenesulfonate ions. Kinetic determination of the formation constants of the ion pairs and a proton NMR study of their structures
Satoshi Tachiyashiki and Hideo Yamatera
pp 3209 - 3211; DOI:
10.1021/ic00238a024
PDF
Solvatochromism of the metal to ligand charge-transfer transitions of zerovalent tungsten carbonyl complexes
David M. Manuta and Alistair J. Lees
pp 3212 - 3218; DOI:
10.1021/ic00238a025
PDF
Reversible carbon monoxide binding by Rh2(O2CCH3)n(HNOCCH3)4-n. A spectroscopic and electrochemical investigation
M. Y. Chavan, M. Q. Ahsan, R. S. Lifsey, J. L. Bear, and K. M. Kadish
pp 3218 - 3223; DOI:
10.1021/ic00238a026
PDF
Electroreduction of the dioxygen adduct of rhodium tetraphenylporphyrin: (TTP)Rh(O2)
J. E. Anderson, C. L. Yao, and K. M. Kadish
pp 3224 - 3228; DOI:
10.1021/ic00238a027
PDF
Electrochemistry and spectroelectrochemistry of oxo- and peroxomolybdenum porphyrin complexes
T. Malinski, P. M. Hanley, and K. M. Kadish
pp 3229 - 3235; DOI:
10.1021/ic00238a028
PDF
A reinvestigation of silver porphyrin electrochemistry. Reactions of silver(III), silver(II), and silver(I)
K. M. Kadish, X. Q. Lin, J. Q. Ding, Y. T. Wu, and C. Araullo
pp 3236 - 3242; DOI:
10.1021/ic00238a029
PDF
Electrochemistry, spectroelectrochemistry, and ligand addition reactions of an easily reducible cobalt porphyrin. Reactions of (Tetracyanotetraphenylporphinato)cobalt(II) (((CN)4TPF)Co(II)) in pyridine and in pyridine/methylene chloride mixtures
X. Q. Lin, B. Boisselier-Cocolios, and K. M. Kadish
pp 3242 - 3248; DOI:
10.1021/ic00238a030
PDF
Three forms of a copper(III) tripeptideamide and a comparison of their photochemistry
Joanna P. Hinton and Dale W. Margerum
pp 3248 - 3256; DOI:
10.1021/ic00238a031
PDF
Electrochemistry of trans-dioxo complexes of rhenium(V) in water
David W. Pipes and Thomas J. Meyer
pp 3256 - 3262; DOI:
10.1021/ic00238a032
PDF
Deuteron nuclear magnetic resonance study of chromium [Cr(edda)(X)2]n complexes (X2 = two monodentates or a bidentate; edda = ethylenediamine-N,N'-diacetato) and complete assignment of the deuteron NMR spectrum of (1,2-propylenediamine-N,N,N',N'-tetraacetato)chromate [Cr(1,2-pdta-.alpha.-d8]-
Robert J. Bianchini and J. Ivan Legg
pp 3263 - 3267; DOI:
10.1021/ic00238a033
PDF
Free-radical pathways to alkyl complexes of a nickel tetraaza macrocycle
M. S. Ram, Andreja Bakac, and James H. Espenson
pp 3267 - 3272; DOI:
10.1021/ic00238a034
PDF
Electronic "d-d" spectra of the planar tetrachlorocuprate(2-) ions in bis(methadonium) tetrachlorocuprate(II) and bis(creatininium) tetrachlorocuprate(II): analysis of the temperature dependence and vibrational fine structure
Robbie G. McDonald and Michael A. Hitchman
pp 3273 - 3281; DOI:
10.1021/ic00238a035
PDF
Ligand substitution processes in tetranuclear carbonyl clusters. 10. X-ray structural characterization of products resulting from reactions of nonacarbonyl[tris(diphenylphosphino)methane]tetracobalt with phosphine ligands
Donald J. Darensbourg, David J. Zalewski, Arnold L. Rheingold, and Rebecca L. Durney
pp 3281 - 3290; DOI:
10.1021/ic00238a036
PDF
Substituent effects in the hydrolysis of quinoline-boranes
David E. Minter, Curtis R. Kelly, and Henry C. Kelly
pp 3291 - 3294; DOI:
10.1021/ic00238a037
PDF
Vibrational fine structure of the lowest spin-allowed absorption band of trans-dicyanobis(1,3-propanediamine)cobalt(1+). Structures of trans-[Co(CN)2(tn2)]Cl.H2O and trans-[Co(CN)2(tn)2]Cl.3H2O (tn = 1,3-propanediamine)
Hans Kupka, Joachim Degen, Akio Urushiyama, Klaus Angermund, and Carl Krueger
pp 3294 - 3301; DOI:
10.1021/ic00238a038
PDF
Coordination behavior of N-protected aspartic acid in binary and ternary copper(II) complexes. Crystal and molecular structure of bis(2,2'-bipyridine)bis(.mu.-N-(benzyloxycarbonyl)-L-aspartato-O,O',O")dicopper(II)-2.5-water-0.5-sodium perchlorate
L. Antolini, L. P. Battaglia, A. Bonamartini Corradi, L. Menabue, G. Micera, and M. Saladini
pp 3301 - 3306; DOI:
10.1021/ic00238a039
PDF
Exceptionally variable solvatochromism of centrosymmetric octacarbonyldimolybdenum(0) complexes. Rules to estimate the solvent sensitivity of charge-transfer absorption energies
Wolfgang Kaim and Stephan Kohlmann
pp 3306 - 3310; DOI:
10.1021/ic00238a040
PDF
Reactions at a dimolybdenum(V) sulfur bridge. Formation of disulfide (S22-), monosubstituted organic disulfide (RSS-) and tetrasulfide (S42-) bridges
Mark E. Noble
pp 3311 - 3317; DOI:
10.1021/ic00238a041
PDF
A very short ruthenium(II)-nitrogen heterocycle bond: Crystal structures of pentaammine(N-methylpyrazinium)ruthenium(II) iodide and pentaammine(N-methylpyrazinium)ruthenium(III) p-toluenesulfonate pentahydrate
James F. Wishart, Avi Bino, and Henry Taube
pp 3318 - 3321; DOI:
10.1021/ic00238a042
PDF
Molecular orbital calculations relevant to the hypercloso vs. iso-closo controversy in metallaboranes
Roy L. Johnston and D. Michael P. Mingos
pp 3321 - 3323; DOI:
10.1021/ic00238a043
PDF
Tungsten(IV)/(V) eight-coordinate mixed-ligand-chelate electrochemistry
Robert J. Nowak and Ronald D. Archer
pp 3323 - 3325; DOI:
10.1021/ic00238a044
PDF
An oxotungsten(V) dimer with unusual stereochemistry: synthesis and structure of anti-bis(.mu.-isobutylthiolato)bis[oxodichloro(triphenylphosphine oxide)tungsten(V)], 1
Joanne M. Ball, P. Michael Boorman, and John F. Richardson
pp 3325 - 3327; DOI:
10.1021/ic00238a045
PDF
Studies on interactions of isocyanides with transition-metal complexes. 30. X-ray crystal structure of dichlorobis(2,6-dimethylphenyl isocyanide)bis(pyridine)dipalladium. Unusual carbon-nitrogen-carbon bond angles and infrared spectrum in bridging isocyanide groups
Yasuhiro Yamamoto and Hiroshi Yamazaki
pp 3327 - 3329; DOI:
10.1021/ic00238a046
PDF
Can F2H+ exist in the topological form FHF+?
Roger L. DeKock, Remo Dutler, Arvi Rauk, and Roger D. Van Zee
pp 3329 - 3330; DOI:
10.1021/ic00238a047
PDF

Issue 19


Preparation, characterization, and oxidation chemistry of the dirhodium complex [Rh2(dimen)2(dppm)2](PF6)2 (dimen = 1,8-diisocyanomenthane; dppm = bis(diphenylphosphino)methane). Electrochemical generation of a stable d7-d8 radical
Marlene M. Mixa, Pamela A. Matsch, David C. Boyd, and Kent R. Mann
pp 3331 - 3333; DOI:
10.1021/ic00239a001
PDF
Magnetically circular-polarized luminescence (MCPL) evidence for the transition from delocalized to localized luminescent states of tris(2,2'-bipyridine)ruthenium(2+) in glass-fluid media
James Ferguson and Elmars Krausz
pp 3333 - 3335; DOI:
10.1021/ic00239a002
PDF
Bimetallic ruthenium hydride borohydride complex with unusually short ruthenium-boron distances. X-ray crystal structure of (.mu.,.eta.2-tetrahydroborato)dihydridobis[tris(diphenylphosphinomethyl)ethane]diruthenium(1+) tetraphenylborate
Larry F. Rhodes, Luigi M. Venanzi, Carla Sorato, and Alberto Albinati
pp 3335 - 3337; DOI:
10.1021/ic00239a003
PDF
Spectroscopic evidence for stacking and electrostatic interactions between nucleoside 5'-monophosphates and a platinum DNA intercalator, (2,2'-bipyridine)(ethylenediamine)platinum(II) in dilute aqueous solution
Osamu Yamauchi, Akira Odani, Reiko Shimata, and Yuko Kosaka
pp 3337 - 3339; DOI:
10.1021/ic00239a004
PDF
Rules for predicting the boron-11 NMR spectra of closo-boranes and closo-heteroboranes
Francesc Teixidor, Clara Vinas, and Ralph W. Rudolph
pp 3339 - 3345; DOI:
10.1021/ic00239a005
PDF
Convenient synthesis, separation, and x-ray crystal structure determinations of 1(e),3(e),5(e)-trimethylcycloborazane and 1(e),3(e),5(a)-trimethylcycloborazane
Chaitanya K. Narula, Jerzy F. Janik, Eileen N. Duesler, Robert T. Paine, and Riley Schaeffer
pp 3346 - 3349; DOI:
10.1021/ic00239a006
PDF
Electron transfer. 78. Reduction of carboxylato-bound chromium(V) with bisulfite. A "clock reaction" involving chromium(IV)
Rathindra N. Bose, N. Rajasekar, Dorena M. Thompson, and Edwin S. Gould
pp 3349 - 3353; DOI:
10.1021/ic00239a007
PDF
Electron transfer. 79. Reductions of organic disulfides by vitamin B12s (cob(I)alamin)
G. Chithambarathanu Pillai and Edwin S. Gould
pp 3353 - 3356; DOI:
10.1021/ic00239a008
PDF
Electron transfer. 80. Further reductions of carboxylato-bound chromium(V)
S. K. Ghosh and E. S. Gould
pp 3357 - 3359; DOI:
10.1021/ic00239a009
PDF
Oxidative and electrophilic pathways in the reactions of pentaaquo(organo)chromium(2+) ions with nitrous acid
Jon D. Melton, Andreja Bakac, and James H. Espenson
pp 3360 - 3367; DOI:
10.1021/ic00239a010
PDF
Electron-transfer reactions of technetium complexes. 1. Rate of the self-exchange reaction of the technetium(I)/technetium(II) couple [Tc(DMPE)3]+/2+, where DMPE = 1,2-bis(dimethylphosphino)ethane
Mary Noon Doyle, Karen Libson, Mary Woods, James C. Sullivan, and Edward Deutsch
pp 3367 - 3371; DOI:
10.1021/ic00239a011
PDF
Characterization of an air-stable chromium(II) dinicotinate complex: trans-[Cr(II)(nic-N)2(H2O)4]
William E. Broderick, Mark R. Pressprich, Urs Geiser, Roger D. Willett, and J. Ivan Legg
pp 3372 - 3377; DOI:
10.1021/ic00239a012
PDF
Synthetic analog approach to metallobleomycins. 1. Syntheses, structures and properties of the copper complexes of two peptides related to bleomycins
Steven J. Brown, Xiaolin Tao, Douglas W. Stephan, and Pradip K. Mascharak
pp 3377 - 3384; DOI:
10.1021/ic00239a013
PDF
Diplatinum(III) complexes with bridging 1-methyluracil ligands in head-tail arrangement: synthesis, structures, and solution behavior
Helmut Schoellhorn, Petra Eisenmann, Ulf Thewalt, and Bernhard Lippert
pp 3384 - 3391; DOI:
10.1021/ic00239a014
PDF
Resolutions involving metal complexation. Synthesis and resolution of (.+-.)-(2-mercaptoethyl)methylphenylarsine. Crystal and molecular structure of (-)589-bis[(R)-[1-(dimethylamino)ethyl]naphthyl-C2,N]chloro[.mu.-(S)-(2-mercaptoethyl)methylphenylarsine]dipalladium.cntdot.0.67dichlomethane
Pak Hing Leung, George M. McLaughlin, John W. L. Martin, and Stanley Bruce Wild
pp 3392 - 3395; DOI:
10.1021/ic00239a015
PDF
Diastereomerism in square-planar complexes of bivalent nickel, palladium, and platinum containing chiral 2-mercaptoethyl-substituted tertiary arsines and phosphines
Pak Hing Leung, John W. L. Martin, and Stanley Bruce Wild
pp 3396 - 3400; DOI:
10.1021/ic00239a016
PDF
Syntheses and spectral properties of tropocoronands, a new class of versatile metal-complexing macrocycles derived from aminotropone imines
Arie Zask, Nina Gonnella, Koji Nakanishi, Christopher J. Turner, Seichi Imajo, and Tetsuo Nozoe
pp 3400 - 3407; DOI:
10.1021/ic00239a017
PDF
Coordinatively saturated cationic ruthenium(II) complexes. Preparation, characterization, and reaction with potassium superoxide
Noriaki Oshima, Hiroharu Suzuki, and Yoshihiko Moro-oka
pp 3407 - 3412; DOI:
10.1021/ic00239a018
PDF
Protonation of iron, ruthenium, and osmium hydrides with fluorocarbon acids. Stereochemical rigidity in seven-coordinate trihydridotetrakis(triphenylphosphine)osmium(1+) bis(trifluoromethylsulfonyl)methanate(1-)
A. R. Siedle, R. A. Newmark, and L. H. Pignolet
pp 3412 - 3418; DOI:
10.1021/ic00239a019
PDF
Ligand substitution vs. ligand addition. 1. Differences in reactivity between first- and third-row transition-metal clusters. Reactions of dimethylamine with the sulfidometal carbonyl clusters M3(CO)9(.mu.3-S)2 (M = Fe, Os)
Richard D. Adams and James E. Babin
pp 3418 - 3422; DOI:
10.1021/ic00239a020
PDF
Synthesis and characterization of four vanadium(II) compounds, including vanadium(II) sulfate hexahydrate and vanadium(II) saccharinates
F. Albert Cotton, Larry R. Falvello, Rosa Llusar, Eduardo Libby, Carlos A. Murillo, and Willi Schwotzer
pp 3423 - 3428; DOI:
10.1021/ic00239a021
PDF
Indium molybdate, In11Mo40O62: a molybdate with units of four and five condensed Mo6 octahedra and linear In57+ and In68+ ions
Hj Mattausch, A. Simon, and E. M. Peters
pp 3428 - 3433; DOI:
10.1021/ic00239a022
PDF
Synthesis, characterization, and crystal structures of two scandium cluster carbides and a boride, Sc7X12C (X = I, Br) and Sc7I12B
Douglas S. Dudis, John D. Corbett, and Shiou Jyh Hwu
pp 3434 - 3438; DOI:
10.1021/ic00239a023
PDF
Photoelectrochemistry of dianionic maleonitriledithiolate complexes of nickel and platinum in ion-exchange films on transparent tin oxide electrodes
Lalchan Persaud and Cooper H. Langford
pp 3438 - 3442; DOI:
10.1021/ic00239a024
PDF
Semireduced bridging ligands containing N-N multiple bond coordination sites. ESR study of binuclear Group 6 metal carbonyl complexes
Wolfgang Kaim and Stephan Kohlmann
pp 3442 - 3448; DOI:
10.1021/ic00239a025
PDF
A nickel(III) complex with a NiO6 coordination sphere
Samaresh Bhattacharya, Rabindranath Mukherjee, and Animesh Chakravorty
pp 3448 - 3452; DOI:
10.1021/ic00239a026
PDF
EPR spectra of bis(nitroxyl) adducts of bis(hexafluoroacetylacetonato)manganese(II)
C. Benelli, D. Gatteschi, C. Zanchini, R. J. Doedens, M. H. Dickman, and L. C. Porter
pp 3453 - 3457; DOI:
10.1021/ic00239a027
PDF
Reactivity of dithiocarbamates of dimolybdenum. Crystal and molecular structure of oxobis[(diethylcarbamodithioato)(tetrahydrofuran)iodooxomolybdenum(V)]
Donald M. Baird, Arnold L. Rheingold, Scott D. Croll, and A. T. DiCenso
pp 3458 - 3461; DOI:
10.1021/ic00239a028
PDF
Coordination of pentadentate macrocycles, doubly deprotonated 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione to high-spin nickel(II) and low-spin nickel(III). X-ray study of a novel redox system
Ryosuke Machida, Eiichi Kimura, and Yoshihiko Kushi
pp 3461 - 3466; DOI:
10.1021/ic00239a029
PDF
Cobalt(III)-promoted hydrolysis of esters. Hydrolysis of chelated and monodentate .beta.-alanine isopropyl ester and interconversions via hydrolysis intermediates
E. Baraniak, D. A. Buckingham, C. R. Clark, B. H. Moynihan, and A. M. Sargeson
pp 3466 - 3478; DOI:
10.1021/ic00239a030
PDF
Metal ion activated aminolysis of esters. Reaction of glycine ethyl ester with bis(ethylenediamine)(isopropyl .beta.-alaninate)cobalt(3+) and general base-catalyzed decomposition of metal alcohol-amine intermediates
David A. Buckingham and Charles R. Clark
pp 3478 - 3483; DOI:
10.1021/ic00239a031
PDF
Equilibria for phosphine ligation to ferrous protoporphyrin IX dimethyl ester and related systems in toluene
Dennis V. Stynes, David Fletcher, and Xuening Chen
pp 3483 - 3488; DOI:
10.1021/ic00239a032
PDF
Structures, NMR spectra, and ligand-exchange properties of Costa-type organocobalt B12 models with N-donor ligands
Wallace O. Parker, Ennio Zangrando, Nevenka Bresciani-Pahor, Lucio Randaccio, and Luigi G. Marzilli
pp 3489 - 3497; DOI:
10.1021/ic00239a033
PDF
Cationic metal nitrosyl complexes. 6. Characterization of the 19-electron iron nitrosyl radical cation [Fe(NO)2LL'2]+
D. Ballivet-Tkatchenko, B. Nickel, A. Rassat, and J. Vincent-Vaucquelin
pp 3497 - 3501; DOI:
10.1021/ic00239a034
PDF
Effect of arene methylation on photochemical arene replacement reactions of the iron and ruthenium complexes [(.eta.5-C5(CH3)5)M(.eta.6-arene)]+ (M = Fe,Ru) complexes
Janet L. Schrenk, Amy M. McNair, Fred B. McCormick, and Kent R. Mann
pp 3501 - 3504; DOI:
10.1021/ic00239a035
PDF
Four compounds containing oxo-centered trivanadium cores surrounded by six .mu.,.eta.2-carboxylato groups
F. Albert Cotton, Michael W. Extine, Larry R. Falvello, Diane Beck Lewis, Gregg E. Lewis, Carlos A. Murillo, Willi Schwotzer, Milagros Tomas, and Jan M. Troup
pp 3505 - 3512; DOI:
10.1021/ic00239a036
PDF
Thermodynamics of complexation of lanthanides by 3-fluoro- 4-fluoro- and 3-nitrobenzoic acids
Gregory R. Choppin and Lauri H. J. Lajunen
pp 3512 - 3514; DOI:
10.1021/ic00239a037
PDF
Studies relating to the specificity of the hemerythrin active site
Graeme D. Armstrong and A. Geoffrey Sykes
pp 3514 - 3516; DOI:
10.1021/ic00239a038
PDF
Preparation and characterization of the .mu.-oxo dimer and hydroxo complexes of (tetrakis(pentafluorophenyl)porphinato)iron(III)
K. Jayaraj, A. Gold, G. E. Toney, J. H. Helms, and W. E. Hatfield
pp 3516 - 3518; DOI:
10.1021/ic00239a039
PDF
Electronegativity and bonding of transitional elements
R. T. Sanderson
pp 3518 - 3522; DOI:
10.1021/ic00239a040
PDF
Pentadienyl-metal-phosphine chemistry. 7. Synthesis, solid-state structure, and solution dynamics of .eta.5-pentadienylrhenium tris(phosphine) complexes. Measurement of the rotational barrier for the pentadienyl ligand
John R. Bleeke and Dennis A. Moore
pp 3522 - 3526; DOI:
10.1021/ic00239a041
PDF
Preparation of iridium(III) complexes containing (o-bromotetrafluorophenyl)diphenylphosphine. A new example of .eta.2-coordination and halocarbon binding in an (o-haloaryl)phosphine
F. Albert Cotton, Pascual Lahuerta, Mercedes Sanau, Willi Schwotzer, and Isabel Solana
pp 3526 - 3528; DOI:
10.1021/ic00239a042
PDF
Preparation and properties of the tribromide of trans-dibromotetrakis(acetonitrile)vanadium(III), [VBr2(CH3CN)4]Br3. A symmetric tribromide ion
F. Albert Cotton, Gregg E. Lewis, and Willi Schwotzer
pp 3528 - 3529; DOI:
10.1021/ic00239a043
PDF
Derivatization of the cuboidal Mo4S4-aquo ion: preparation and structure of Mo4S4(HB(pz)3)4(pz) (pz = pyrazolyl, C3N2H3-)
F. Albert Cotton, Zvi Dori, Rosa Llusar, and Willi Schwotzer
pp 3529 - 3532; DOI:
10.1021/ic00239a044
PDF
Relation between structure and magnetic exchange pathways in hexakis(pyridine N-oxide)copper complexes
J. S. Wood and C. P. Keijzers
pp 3532 - 3534; DOI:
10.1021/ic00239a045
PDF
Electrosynthesis and x-ray structure of a dinuclear rhodium complex containing a bridging nitrate ion
Louis J. Tortorelli, Craig A. Tucker, Clifton Woods, and John Bordner
pp 3534 - 3537; DOI:
10.1021/ic00239a046
PDF
Chemical and structural characterization of W(CO)5OPPh2NPPh3. A novel tungsten carbonyl complex containing a phosphine oxide ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation
Donald J. Darensbourg, Magdalena Pala, Debra Simmons, and Arnold L. Rheingold
pp 3537 - 3541; DOI:
10.1021/ic00239a047
PDF
Studies of the synthesis and thermolysis of tris[tris(amino)phosphine]molybdenum tricarbonyls: synthesis of fac-[(iso-PrNH)3P]3Mo(CO)3
Abbas Tarassoli, Haw Jan Chen, Viloya S. Allured, Tara G. Hill, R. Curtis Haltiwanger, Martin L. Thompson, and Arlan D. Norman
pp 3541 - 3544; DOI:
10.1021/ic00239a048
PDF
Mass spectra and beryllium-9 NMR spectra of partially fluorinated .beta.-diketonate complexes of beryllium
Joan C. Kunz, Manoranjan Das, and Daniel T. Haworth
pp 3544 - 3545; DOI:
10.1021/ic00239a049
PDF
Can the bis(diboranyl) structure of tetraborane(10) be observed?
Michael L. McKee
pp 3545 - 3547; DOI:
10.1021/ic00239a050
PDF
Formation of a binuclear complex by reaction of pentaaquo(cyanomethyl)chromium(2+) with mercury(II)
Margaret J. Sisley and Robert B. Jordan
pp 3547 - 3548; DOI:
10.1021/ic00239a051
PDF

Issue 20


Light-induced cleavage of DNA by metal complexes
Mindy B. Fleisher, Kenneth C. Waterman, Nicholas J. Turro, and Jacqueline K. Barton
pp 3549 - 3551; DOI:
10.1021/ic00240a001
PDF
Photoaquation of the iodopentaamminechromium(III) ion in acidic aqueous solution
A. D. Kirk, S. Arunachalam, and D. Kneeland
pp 3551 - 3552; DOI:
10.1021/ic00240a002
PDF
Synthesis and characterization of substitution-inert cobalt(III) complexes containing an N-glycoside derived from ethylenediamine and a monosaccharide (D-mannose, L-rhamnose, or D-ribose)
Katsuaki Ishida, Shigenobu Yano, and Sadao Yoshikawa
pp 3552 - 3554; DOI:
10.1021/ic00240a003
PDF
Photochemical reactions of cobalt(III)-amine complexes in nonaqueous solvents: mechanistic details of the oxygenation reactions of cobalt(II) systems
P. Ramamurthy and P. Natarajan
pp 3554 - 3560; DOI:
10.1021/ic00240a004
PDF
Coordiation chemistry of microbial iron transport. 38. Preparation, structure, and physical properties of dimeric copper(II) hydroxamate complexes, Cu2L2 [L = iso-PrN(O)C(=O)(CH2)nC(=O)N(O)-iso-Pr, n = 3-10]
Susan J. Barclay and Kenneth N. Raymond
pp 3561 - 3566; DOI:
10.1021/ic00240a005
PDF
Optical spectroscopy as a structural and electronic probe in a coordination compound: decaammine(.mu.-hydroxo)dichromium(5+) chloride monohydrate
Hans Riesen and Hans U. Guedel
pp 3566 - 3570; DOI:
10.1021/ic00240a006
PDF
Desorption chemical ionization mass spectrometry via electron capture of hydrolytically labile titanium porphyrins
E. Forest, J. C. Marchon, J. Ulrich, and H. Virelizier
pp 3570 - 3572; DOI:
10.1021/ic00240a007
PDF
Substituent effects in clusters. UV-photoelectron spectroscopic and quantum-chemical analyses of triosmium carbonyl hydrides H3Os3(CO)9BCO, H2Os3(CO)9CCO, and related clusters
R. D. Barreto, T. P. Fehlner, L. Y. Hsu, D. Y. Jan, and S. G. Shore
pp 3572 - 3581; DOI:
10.1021/ic00240a008
PDF
Thermodynamics of complexation of lanthanides by dicarboxylate ligands
G. R. Choppin, A. Dadgar, and E. N. Rizkalla
pp 3581 - 3584; DOI:
10.1021/ic00240a009
PDF
Coordination of thiocyanate in tetraamine and diimine-diamine complexes of copper(II)
Der Thin Wu and Chung Sun Chung
pp 3584 - 3587; DOI:
10.1021/ic00240a010
PDF
Room-temperature fused salts based on copper(I) chloride-1-methyl-3-ethylimidazolium chloride mixtures. 2. Reactions with dioxygen
Steven A. Bolkan and John T. Yoke
pp 3587 - 3590; DOI:
10.1021/ic00240a011
PDF
Structural studies of the hydrogen storage material magnesium nickel hydride (Mg2NiH4). 2. Monoclinic low-temperature structure
Peter Zolliker, K. Yvon, J. D. Jorgensen, and F. J. Rotella
pp 3590 - 3593; DOI:
10.1021/ic00240a012
PDF
Dinuclear complexes of transition metals containing carbonate ligands. 6. Synthesis, characterization and thermodynamic studies of dinuclear complexes of cobalt(III) containing bridging hydroxide and carbonate in acidic aqueous solution
Garfield Sadler and Tara P. Dasgupta
pp 3593 - 3597; DOI:
10.1021/ic00240a013
PDF
Structure and reactions of octacarbonyldiiron: An IR spectroscopic study using carbon-13 monoxide, photolysis with plane-polarized light, and matrix isolation
Susan C. Fletcher, Martyn Poliakoff, and James J. Turner
pp 3597 - 3604; DOI:
10.1021/ic00240a014
PDF
IR detection and characterization of (N2-1-butene)dicarbonylnitrosylcobalt and the iron complex Fe(CO)2-x(NO)2(.mu.2-1-btn)x (x = 1 or 2; 1-btn = 1-butene) in liquid xenon solution
Gerard E. Gadd, Martyn Poliakoff, and James J. Turner
pp 3604 - 3608; DOI:
10.1021/ic00240a015
PDF
Solid-state micro-Raman and Fourier transform infrared spectra of mixed carbonyl-isocyanide dirhenium(0) complexes, Re2(CO)10-n(CNR)n (n = 1-4)
Pierre D. Harvey, Ian S. Butler, Gillian W. Harris, and Neil J. Coville
pp 3608 - 3613; DOI:
10.1021/ic00240a016
PDF
Synthesis and x-ray crystal structure of di(pentamethylcyclopentadienyl)lanthanide and yttrium halide complexes
William J. Evans, Jay W. Grate, Keith R. Levan, Ira Bloom, Timothy T. Peterson, Robert J. Doedens, Hongming Zhang, and Jerry L. Atwood
pp 3614 - 3619; DOI:
10.1021/ic00240a017
PDF
Reactivity of the dirhenium(III) carboxylate complexes Re2(O2CCH3)2X4(H2O)2 (X = Cl or Br) toward monodentate phosphines. A novel disproportionation reaction leading to dirhenium(IV,II) alkoxide complexes of the type (RO)2X2ReReX2(PPh3)2 (X = Cl or Br; R = Me, Et, or Pr)
Akhil R. Chakravarty, F. Albert Cotton, Ann R. Cutler, and Richard A. Walton
pp 3619 - 3624; DOI:
10.1021/ic00240a018
PDF
Thermal reaction of octacarbonyltetraiododimolybdenum with dimethylphenylphosphine, diethylphenylphosphine and pyridine. Formation of metal-metal quadruple bonds vs. disproportionation. X-ray crystal structures of bis(dimethylphenylphosphine)(dimethylphenylphosphine oxide)triiodomolybdenum and diethylphenylphosphonium bis(diethylphenylphosphine)tetraiodomolybdate(1-)
F. Albert Cotton and Rinaldo Poli
pp 3624 - 3629; DOI:
10.1021/ic00240a019
PDF
Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with isocyanides. 4. Dinuclear species containing two or three isocyanide ligands
Lori Beth Anderson, Timothy J. Barder, F. Albert Cotton, Kim R. Dunbar, Larry R. Falvello, and Richard A. Walton
pp 3629 - 3636; DOI:
10.1021/ic00240a020
PDF
Synthesis, characterization, and molecular structure of a novel triply bonded dirhenium(II) complex that contains three intramolecular phosphine bridging ligands: tris-.mu.-[bis(dimethylphosphino)methane]tetrachlorodirhenium
Lori Beth Anderson, F. Albert Cotton, Larry R. Falvello, William S. Harwood, Diane Lewis, and Richard A. Walton
pp 3637 - 3641; DOI:
10.1021/ic00240a021
PDF
Quadruply bonded bis[bis(diphenylphosphino)ethane]tetraiododimolybdenum: twisted and eclipsed rotational conformations and their significance
F. Albert Cotton, Kim R. Dunbar, and Marek Matusz
pp 3641 - 3649; DOI:
10.1021/ic00240a022
PDF
Studies of the photoinduced ligand substitution reactions of hexakis(2,6-dimethylphenyl isocyanide)rhenium(1+) in the presence of halide ions
Nathan E. Stacy, Kay A. Conner, David R. McMillin, and Richard A. Walton
pp 3649 - 3652; DOI:
10.1021/ic00240a023
PDF
Magnetic studies of a linear chromium(III) trimer of a triketone
Londa L. Borer, Renee Horsma, Odatt A. Rajan, and Ekkehard Sinn
pp 3652 - 3654; DOI:
10.1021/ic00240a024
PDF
Oxidative fragmentation of the cuboid molybdenum-sulfur Mo4S4 cluster core: synthesis and structures of [Mo3(.mu.3-S)(.mu.-S)3([9]aneN3)3]4+ and {[MoO([9]aneN3)]2(.mu.-S)2}2+ ([9]aneN3 = 1,4,7-triazacyclononane)
F. Albert Cotton, Zvi Dori, Rosa Llusar, and Willi Schwotzer
pp 3654 - 3658; DOI:
10.1021/ic00240a025
PDF
Gas-phase electron diffraction study of tetrachloro-oxo-osmium(VI)
Kolbjorn Hagen, Richard J. Hobson, Catherine J. Holwill, and David A. Rice
pp 3659 - 3661; DOI:
10.1021/ic00240a026
PDF
Transition-metal complexes of a binucleating clathrochelate ligand: a reinvestigation of the crystal structure
Richard E. Marsh and William P. Schaefer
pp 3661 - 3662; DOI:
10.1021/ic00240a027
PDF
Mechanistic information from medium- and high-pressure effects on the photooxidation of nitrosylpentacyanoferrate(II)
G. Stochel, R. Van Eldik, and Z. Stasicka
pp 3663 - 3666; DOI:
10.1021/ic00240a028
PDF
Preparation and characterization of bis(dialkyldithiocarbamato)[hydrotris(3,5-dimethyl-1-pyrazolyl)borato]molybdenum(III) complexes produced by the oxidative decarbonylation of [{HB(3,5-Me2C3N2H)3}Mo(CO)3]- by tetraalkylthiuram disulfides. Crystal structure of {HB(3,5-Me2C3N2H)3}Mo(.eta.2-S2CNEt2)(.eta.1-S2CNEt2)
Charles G. Young, Sue A. Roberts, and John H. Enemark
pp 3667 - 3671; DOI:
10.1021/ic00240a029
PDF
Biological analogs. A structural model for the binding site of blue copper proteins
John Whelan and B. Bosnich
pp 3671 - 3675; DOI:
10.1021/ic00240a030
PDF
Spectroscopic study of the effect of methyl and phenyl substituents on the basicity of phosphine ligands in tungsten carbonyl derivatives
G. Michael Bancroft, Lisa Dignard-Bailey, and Richard J. Puddephatt
pp 3675 - 3680; DOI:
10.1021/ic00240a031
PDF
Isomerization processes observed for chromium compounds by using the gas chromatographic reactor
Philip J. Marriott and Yee Hing Lai
pp 3680 - 3683; DOI:
10.1021/ic00240a032
PDF
Experimental and quantum-chemical investigation of the magnetic exchange mechanism in a series of (.mu.-terephthalato)bis[(polyamine)copper(II)] complexes
E. G. Bakalbassis, J. Mrozinski, and C. A. Tsipis
pp 3684 - 3690; DOI:
10.1021/ic00240a033
PDF
Metal complexes containing the trimethylamine-carboxylatoborane ligand: synthesis and characterization of [M3O((CH3)3N.BH2CO2)6R3]+X- (M = Cr(III), Fe(III); R = H2O, CH3OH; X- = NO3-, Cl-)
Verrill M. Norwood and Karen W. Morse
pp 3690 - 3693; DOI:
10.1021/ic00240a034
PDF
Reduction of peroxotitanium(IV) by iodide, thiodiethanol, thioxane, and thiourea in acidic solution
John D. Lydon and Richard C. Thompson
pp 3694 - 3697; DOI:
10.1021/ic00240a035
PDF
The isotopic trans effect
Robert H. Crabtree and Afroze Habib
pp 3698 - 3699; DOI:
10.1021/ic00240a036
PDF
Synthesis and molecular structure of bis[bis(diphenylphosphino)methane]tetraiododimolybdenum.bis(toluene)
F. Albert Cotton, Kim R. Dunbar, and Rinaldo Poli
pp 3700 - 3703; DOI:
10.1021/ic00240a037
PDF
Products of the reaction between octacarbonyltetraiododimolybdenum and bis(dimethylphosphino)methane (dmpm). X-ray crystal structure of MoI2(CO)(dmpm)2.cntdot.C7H8
F. Albert Cotton and Rinaldo Poli
pp 3703 - 3705; DOI:
10.1021/ic00240a038
PDF
Crystal and molecular structure of rhenium manganese decacarbonyl, ReMn(CO)10, containing an unexpectedly short rhenium-manganese bond
Arnold L. Rheingold, Wilma K. Meckstroth, and Douglas P. Ridge
pp 3706 - 3707; DOI:
10.1021/ic00240a039
PDF
EXAFS studies of binuclear iron complexes as models for hemerythrin and related proteins
Britt Hedman, Man Sung Co, William H. Armstrong, Keith O. Hodgson, and Stephen J. Lippard
pp 3708 - 3711; DOI:
10.1021/ic00240a040
PDF
Raman spectral study on the solution structure of the chromium(III)-EDTA complex
Kan Kanamori and K. Kawai
pp 3711 - 3713; DOI:
10.1021/ic00240a041
PDF
A new class of substituted amine-boranes: the amine-(.alpha.-cyanoorgano)boranes
John L. Peters, Verrill M. Norwood, and Karen W. Morse
pp 3713 - 3714; DOI:
10.1021/ic00240a042
PDF
Synthesis and x-ray structure of sodium bis(guaninato(2-))tetraphosphatodiplatinate(10-) docosahydrate, a complex with doubly deprotonated guanine anions coordinated to diplatinum(III)
R. El-Mehdawi, Frank R. Fronczek, and D. Max Roundhill
pp 3714 - 3716; DOI:
10.1021/ic00240a043
PDF
Characterization of iron(III) porphyrins bearing aliphatic amine ligands
Yuying C. Hwang and Dabney White Dixon
pp 3716 - 3718; DOI:
10.1021/ic00240a044
PDF
Synthesis and characterization of a meso-tetrakis(4-ferrocenylphenyl)porphyrin and examination of its ability to undergo intramolecular photocatalyzed electron transfer
Ernst S. Schmidt, Thomas S. Calderwood, and Thomas C. Bruice
pp 3718 - 3720; DOI:
10.1021/ic00240a045
PDF

Issue 21


Chemical synthesis of elemental fluorine
Karl O. Christe
pp 3721 - 3722; DOI:
10.1021/ic00241a001
PDF
Electrochemical generation of iron(IV)-oxo porphyrins and iron(IV)-oxo porphyrin .pi. cation radicals
Thomas S. Calderwood and Thomas C. Bruice
pp 3722 - 3724; DOI:
10.1021/ic00241a002
PDF
Active-site chemistry of hemerythrin: kinetic studies on the reduction of metmyohemerythrin from Themiste zostericola and the mechanism for met and deoxy interconversion
Graeme D. Armstrong and A. Geoffrey Sykes
pp 3725 - 3729; DOI:
10.1021/ic00241a003
PDF
Kinetic studies of 1:1 electron-transfer reactions of blue copper proteins. 13. Reactions of rusticyanin from Thiobacillus ferrooxidans with inorganic redox partners
Joseph McGinnis, W. John Ingledew, and A. Geoffrey Sykes
pp 3730 - 3733; DOI:
10.1021/ic00241a004
PDF
Electronic effects on the spectra and carbon monoxide affinities of heme and (Thiolato) heme complexes. Cis and trans effects
Emily M. Gaul and Richard J. Kassner
pp 3734 - 3740; DOI:
10.1021/ic00241a005
PDF
Magnetic and spectroscopic study of pyrazine-bridged iron(II) halide complexes
John S. Haynes, John R. Sams, and Robert C. Thompson
pp 3740 - 3744; DOI:
10.1021/ic00241a006
PDF
Kinetics of ligand substitution and oxidation reactions of the [((phosphonomethyl)imino)diacetato]aquaoxovanadium(IV) ion: role of the hydrogen bond between the coordinated water and the phosphonate arm
Bateer Wang, Yoichi Sasaki, Kenichi Okazaki, Keiko Kanesato, and Kazuo Saito
pp 3745 - 3749; DOI:
10.1021/ic00241a007
PDF
Direct synthesis of hexafluoroferrates(III) and reaction of thiocyanate and fluoride with iron(III) and hydrogen peroxide as an access to fluoro(sulfato)ferrates(III)
Mihir K. Chaudhuri and Nashreen S. Islam
pp 3749 - 3751; DOI:
10.1021/ic00241a008
PDF
Complexation kinetics of highly substituted acyclic, monocyclic, and bicyclic tetraamines with copper(II) in basic aqueous media
Jane A. Drumhiller, Francois Montavon, Jean Marie Lehn, and Richard W. Taylor
pp 3751 - 3757; DOI:
10.1021/ic00241a009
PDF
Chemical and structural studies of azaboranes
Aheda Arafat, Jeff Baer, John C. Huffman, and Lee J. Todd
pp 3757 - 3761; DOI:
10.1021/ic00241a010
PDF
Spectrophotometric and x-ray absorption edge study of complexation of carbon monoxide with ferric tetrasulfophthalocyanine in alkaline solution
Clovis A. Linkous, William E. O'Grady, Dale Sayers, and C. Y. Yang
pp 3761 - 3765; DOI:
10.1021/ic00241a011
PDF
Complexes of functional phosphines. 10. Palladium complexes with the ligands (diphenylphosphino)acetophenone, (Ph2PCHCOPh)- and Ph2PCHC(Ph)OPPh2. Crystal and molecular structure of cis-[PdCl2{Ph2PCH:C(Ph)OPPh2}]
Salah Eddine Bouaoud, Pierre Braunstein, Daniel Grandjean, Dominique Matt, and Dominique Nobel
pp 3765 - 3770; DOI:
10.1021/ic00241a012
PDF
Strong antiferromagnetic exchange in a bromide-bridged copper dimer, bis(.mu.-bromo)bis[bromobis(tetramethylene sulfoxide)copper(II)]. Structure, susceptibility, and magnetostructural correlations
C. P. Landee and R. E. Greeney
pp 3771 - 3775; DOI:
10.1021/ic00241a013
PDF
Sequence distribution of aluminum(3+) and titanium(3+) ions in .beta.-phase (TiCl3)(AlCl3)0.33
Patrick Brant and Erik G. M. Tornqvist
pp 3776 - 3779; DOI:
10.1021/ic00241a014
PDF
Absorption spectrophotometric and x-ray diffraction studies of the trichlorides of berkelium-249 and californium-249
J. R. Peterson, J. P. Young, D. D. Ensor, and R. G. Haire
pp 3779 - 3782; DOI:
10.1021/ic00241a015
PDF
Hydrothermal synthesis of copper molybdates
Ahmad Moini, Roberta Peascoe, Philip R. Rudolf, and Abraham Clearfield
pp 3782 - 3785; DOI:
10.1021/ic00241a016
PDF
Electrochemical studies of monomeric niobium(V) and niobium(IV) porphyrins in nonaqueous media
J. E. Anderson, Y. H. Liu, R. Guilard, J. M. Barbe, and K. M. Kadish
pp 3786 - 3791; DOI:
10.1021/ic00241a017
PDF
Design of metal chelates with biological activity. 5. Complexation behavior of dihydroxamic acids with metal ions
David A. Brown, Ruth Geraty, Jeremy D. Glennon, and Nuala Ni Choileain
pp 3792 - 3796; DOI:
10.1021/ic00241a018
PDF
Successive high-temperature chlorine substitution and infrared matrix-isolation spectroscopy of methylaluminum chlorides
Erling Rytter and Steinar Kvisle
pp 3796 - 3804; DOI:
10.1021/ic00241a019
PDF
Formation of zwitterionic ligands, ROC-(+PMe3)S2-, by nucleophilic attack of trimethylphosphine on coordinated xanthates. X-ray structure of MoO[S2C(PMe3)O-iso-Pr-S,S'](CS2CO-iso-Pr-S,S'C)
Ernesto Carmona, Agustin Galindo, Enrique Gutierrez-Puebla, Angeles Monge, and Carmen Puerta
pp 3804 - 3807; DOI:
10.1021/ic00241a020
PDF
Cleavage reactions of halogen-bridged heterobimetallic palladium-platinum complexes. Crystal and molecular structure of bis(.mu.-di-tert-butyldiiminoethane)tetrachlorobis(tributylphosphine)palladiumplatinum
Howard C. Clark, George Ferguson, Vimal K. Jain, and Masood Parvez
pp 3808 - 3811; DOI:
10.1021/ic00241a021
PDF
Complexes with phosphinomethanes and -methanides as ligands. 10. Formation, structure, and properties of {bis[bis(dimethylphosphino)methane](.mu.-dimethylphosphido)bis(trimethylphosphine)dicobalt}, a dinuclear, odd-electron cobalt complex of formal oxidation state Co2+. Electronic structure of [CoL3]2PR2 radicals
Hans H. Karsch, Beatrix Milewski-Mahrla, Juergen O. Besenhard, Peter Hofmann, Peter Stauffert, and Thomas A. Albright
pp 3811 - 3821; DOI:
10.1021/ic00241a022
PDF
Gold(I) complexes with bidentate tertiary phosphine ligands: formation of annular vs. tetrahedral chelated complexes
Susan J. Berners-Price and Peter J. Sadler
pp 3822 - 3827; DOI:
10.1021/ic00241a023
PDF
Cobalt(II) bis(1,4,7-trithiacyclononane): a low-spin octahedral complex
G. S. Wilson, Dale D. Swanson, and R. S. Glass
pp 3827 - 3829; DOI:
10.1021/ic00241a024
PDF
Polyfluoroalkyl dibasic acid phosphates, bis(polyfluoroalkyl) monobasic acid phosphates, and their precursors
Tariq Mahmood and Jean'ne M. Shreeve
pp 3830 - 3837; DOI:
10.1021/ic00241a025
PDF
Direct evidence for an SN1CB mechanism. 4. Crystal and molecular structure of chloro(bis(8-quinolinyl)amido-N1,N2,N3)copper(II), a metal chelate containing an sp2-hybridized deprotonated amine
Jeffrey P. Puzas, Robert Nakon, and Jeffrey L. Petersen
pp 3837 - 3840; DOI:
10.1021/ic00241a026
PDF
Physical and chemical quenching of excited uranyl ion by dialkyl sulfides
Terence J. Kemp and Mark A. Shand
pp 3840 - 3843; DOI:
10.1021/ic00241a027
PDF
Strongly luminescing ruthenium(II)/ruthenium(II) and ruthenium(II)/platinum(II) binuclear complexes
Ram Sahai, David A. Baucom, and D. Paul Rillema
pp 3843 - 3845; DOI:
10.1021/ic00241a028
PDF
Proton NMR investigation of iron(III) 5,10,15,20-tetrakis(2,6-disubstituted phenyl)porphyrins. Isolation and characterization of hydroxy-ligated (5,10,15,20-tetrakis(2,6-difluorophenyl)porphinato)iron(III)
T. C. Woon, A. Shirazi, and Thomas C. Bruice
pp 3845 - 3846; DOI:
10.1021/ic00241a029
PDF

Issue 22


A new class of pnicogen-transition metal adducts: a stereo active lone pair at a 10-Sb-4 antimony center
Constantine A. Stewart and Anthony J. Arduengo
pp 3847 - 3848; DOI:
10.1021/ic00242a001
PDF
Synthesis and structure of the nickel(II) complex of 1,1,1-tris(((2-(methylthio)ethyl)thio)methyl)ethane, an all-sulfur ligand that promotes hexakis(thioether) coordination
Celia M. Thorne, Simon C. Rawle, Gary A. Admans, and Stephen R. Cooper
pp 3848 - 3850; DOI:
10.1021/ic00242a002
PDF
Teflate (OTeF5-) as a unique ligand for metal complexes: structure of [TlOTeF5(1,3,5-(CH3)3C6H3)2]2, a thallium(I) complex with neutral arene ligands
Steven H. Strauss, Mark D. Noirot, and Oren P. Anderson
pp 3850 - 3851; DOI:
10.1021/ic00242a003
PDF
Trichlorotetrakis(triethylphosphine)hexathioheptairon (Fe7S6(PEt3)4Cl3): a topological link between the prismatic and cube-octahedral structures of iron-sulfur clusters
I. Noda, B. S. Snyder, and R. H. Holm
pp 3851 - 3853; DOI:
10.1021/ic00242a004
PDF
Singlet-triplet transitions of aromatic compounds coordinating to a paramagnetic chromium(III) ion
Takeshi Ohno, Shunji Kato, Sumio Kaizaki, and Ichiro Hanazaki
pp 3853 - 3858; DOI:
10.1021/ic00242a005
PDF
Phosphorescent 8-quinolinol metal chelates. Excited-state properties and redox behavior
Roberto Ballardini, Graziano Varani, Maria Teresa Indelli, and Franco Scandola
pp 3858 - 3865; DOI:
10.1021/ic00242a006
PDF
Metal-nitroxyl interactions. 48. EPR spectra of spin-labeled pyridines coordinated to chromium(III) tetraphenylporphyrin chloride (S = 3/2) and comparison of the electron-electron exchange interaction with analogous complexes with metal S = 1/2
Kundalika M. More, Gareth R. Eaton, Sandra S. Eaton, and Kalman Hideg
pp 3865 - 3869; DOI:
10.1021/ic00242a007
PDF
Electron spin resonance studies of copper(II) polyamine and imidazole complexes
Shirin Siddiqui and Rex E. Shepherd
pp 3869 - 3876; DOI:
10.1021/ic00242a008
PDF
Comparison of the electronic properties of bis(disulfido)dioxidi-.mu.-sulfidodimolybdate(2-) and bis(disulfido)disulfidodi-.mu.-sulfidodimolybdate(2-)
J. Bernholc and E. I. Stiefel
pp 3876 - 3879; DOI:
10.1021/ic00242a009
PDF
Control of metal ion selectivity in ligands containing neutral oxygen and pyridyl groups
Kirty V. Damu, M. Salim Shaikjee, Joseph P. Michael, Arthur S. Howard, and Robert D. Hancock
pp 3879 - 3883; DOI:
10.1021/ic00242a010
PDF
Synthesis and metal complexes of macrocyclic triamines bearing a phenol pendant
Eiichi Kimura, Mayumi Yamaoka, Mieko Morioka, and Tohru Koike
pp 3883 - 3886; DOI:
10.1021/ic00242a011
PDF
Volume profiles as mechanistic information for aquations of cis-acidotetraammineaquacobalt(2+) (cis-CoX(NH3)4(H2O)2+; X = Cl-, Br-, NO3-)
Yoichi Kitamura, Tetsuroh Itoh, and Masayo Takeuchi
pp 3887 - 3890; DOI:
10.1021/ic00242a012
PDF
Complexation kinetics of diamino diamides with copper(II) in aqueous solution
Si Han Liu and Chung Sun Chung
pp 3890 - 3896; DOI:
10.1021/ic00242a013
PDF
Leaving-group effects on kinetic parameters for solvolysis reactions of sterically hindered palladium(II) complexes in aqueous solution
M. Kotowski and R. Van Eldik
pp 3896 - 3899; DOI:
10.1021/ic00242a014
PDF
Transmetalation of tetranuclear copper complexes. 9. Stoichiometry and kinetics of transmetalation of (.mu.4-O)[NCu]4X6 complexes by M(NS)2 reagents in aprotic solvents
Geoffrey Davies, Mohamed A. El-Sayed, and Ahmed El-Toukhy
pp 3899 - 3903; DOI:
10.1021/ic00242a015
PDF
Selective transmetalation and demetalation of heteropolynuclear metal complexes
Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Maher Henary, Taher S. Kasem, and Colleen A. Martin
pp 3904 - 3909; DOI:
10.1021/ic00242a016
PDF
Kinetics and mechanism of arene displacement in (.eta.-arene)dicarbonyl(chalcocarbonyl)chromium(0) complexes, (.eta.-arene)Cr(CO)2(CX) (X = S, Se), by tertiary phosphites
Ian S. Butler and Ashraf A. Ismail
pp 3910 - 3914; DOI:
10.1021/ic00242a017
PDF
Assay of hydride or volatile ligands via outer-sphere oxidation
T. H. Lemmen, E. G. Lundquist, L. F. Rhodes, B. R. Sutherland, D. E. Westerberg, and K. G. Caulton
pp 3915 - 3917; DOI:
10.1021/ic00242a018
PDF
Phosphorus-31 and carbon-13 solid-state NMR of tertiary phosphine-palladium complexes bound to silica
Richard A. Komoroski, Angelo J. Magistro, and Paul P. Nicholas
pp 3917 - 3925; DOI:
10.1021/ic00242a019
PDF
Spectroscopic and chemical properties of nitrogen-15-enriched molybdenum dinitrogen complexes trans,mer-Mo(N2)2(L)(PMePh2)3
Natalie J. Lazarowych, Robert H. Morris, and Joel M. Ressner
pp 3926 - 3932; DOI:
10.1021/ic00242a020
PDF
Synthesis, characterization, and reactivity of the meridional isomers of triphenylmethylphosphonium triiodotricarbonylruthenate(II) and triphenylmethylphosphonium hexaiodotetracarbonyldiruthenate(II)
Joseph R. Zoeller
pp 3933 - 3937; DOI:
10.1021/ic00242a021
PDF
Multiple routes to the formation of a phosphine-bridged trirhodium dihydride cation, [Rh3{(.mu.-(Ph2PCH2))2PPh}2(H)2(.mu.-Cl)2(CO)2]+
Alan L. Balch, John C. Linehan, and Marilyn M. Olmstead
pp 3937 - 3942; DOI:
10.1021/ic00242a022
PDF
Rhodium-rhodium bonds of order 0, 1, and 2 in dinuclear rhodium(I) phosphido and arsenido complexes: x-ray crystal structures of [Rh(CO)(tert-Bu2PH)]2(.mu.-tert-Bu2P)(.mu.-H) (Rh-Rh), [Rh(COD)]2(.mu.-tert-Bu2P)(.mu.-Cl) (COD = 1,5-cyclooctadiene), and [Rh(.mu.-tert-Bu2As)(CO)2]2
Atta M. Arif, Richard A. Jones, Mark H. Seeberger, Bruce R. Whittlesey, and Thomas C. Wright
pp 3943 - 3949; DOI:
10.1021/ic00242a023
PDF
Synthesis, properties, and structural characterization of the molybdenum bis(dimethylphosphino)methane (dmpm) complex Mo2(.mu.-dmpm)2Cl4
F. Albert Cotton, Larry R. Falvello, William S. Harwood, Gregory L. Powell, and Richard A. Walton
pp 3949 - 3953; DOI:
10.1021/ic00242a024
PDF
Solid-state structure and solution equilibria of cyano(triethylphosphine)gold(I)
A. L. Hormann, C. F. Shaw, D. W. Bennett, and W. M. Reiff
pp 3953 - 3957; DOI:
10.1021/ic00242a025
PDF
Dibromotris(N,N'-dimethylurea)manganese(II), a pentacoordinated high-spin manganese complex with monodentate ligands: structure and spectral properties
Jacqueline Delaunay and Rene P. Hugel
pp 3957 - 3961; DOI:
10.1021/ic00242a026
PDF
Catecholate and semiquinone complexes of vanadium. Factors that direct charge distribution in metal-quinone complexes
Marion E. Cass, Nancy Rowan Gordon, and Cortlandt G. Pierpont
pp 3962 - 3967; DOI:
10.1021/ic00242a027
PDF
Derivatives of tetrathiotungstate (VI). Synthesis and structure of (.mu.-.eta.3-disulfido)tris(.eta.2-disulfido)(thiolo)bis(sulfido)ditungstate(1-)
F. Secheresse, J. M. Manoli, and C. Potvin
pp 3967 - 3971; DOI:
10.1021/ic00242a028
PDF
Crystalline isomerism in (.mu.-oxo)bis[(phthalocyaninato)iron(III)]: further characterization of the isomer having a linear or quasi-linear Fe-O-Fe bond system (.mu.-oxo(2))
Claudio Ercolani, Marcello Gardini, Keith S. Murray, Giovanna Pennesi, and Gentilina Rossi
pp 3972 - 3976; DOI:
10.1021/ic00242a029
PDF
Highly electroconductive tetrathiafulvalenium salts of copper halides
Michiko B. Inoue, Motomichi Inoue, Quintus Fernando, and Kenneth W. Nebesny
pp 3976 - 3980; DOI:
10.1021/ic00242a030
PDF
Synthesis and structure of bis[rhodamine 123] tetrachloroplatinate dihydrate: the first tetrachloroplatinate(II) salt with anticancer activity
M. J. Abrams, D. H. Picker, P. H. Fackler, C. J. L. Lock, H. E. Howard-Lock, R. Faggiani, B. A. Teicher, and R. C. Richmond
pp 3980 - 3983; DOI:
10.1021/ic00242a031
PDF
Ligand field effects on the transport of 3d metal ions across a bulk liquid membrane by lipophilic tetraamine carriers
Michela Di Casa, Luigi Fabbrizzi, Angelo Perotti, Antonio Poggi, and Renato Riscassi
pp 3984 - 3987; DOI:
10.1021/ic00242a032
PDF
Resonance Raman frequencies and core size for low- and high-spin nickel porphyrins
Dongho Kim, Y. Oliver Su, and Thomas G. Spiro
pp 3988 - 3993; DOI:
10.1021/ic00242a033
PDF
Back-bonding in ruthenium porphyrins as monitored by resonance Raman spectroscopy
Dongho Kim, Y. Oliver Su, and Thomas G. Spiro
pp 3993 - 3997; DOI:
10.1021/ic00242a034
PDF
Electronic structure of transition-metal tetracoordinated complexes. 1. Theoretical ab initio and UV-photoelectron spectroscopy study of palladium(II) and platinum(II) square-planar acetylacetonate complexes
Santo Di Bella, Ignazio Fragala, and Gaetano Granozzi
pp 3997 - 4003; DOI:
10.1021/ic00242a035
PDF
The alkyne-cluster interaction: structural, theoretical, and spectroscopic study on the parallel .mu.3-.eta.2 bonding mode in trinuclear carbonyl clusters of ruthenium and osmium
S. Aime, R. Bertoncello, V. Busetti, R. Gobetto, G. Granozzi, and D. Osella
pp 4004 - 4010; DOI:
10.1021/ic00242a036
PDF
Ligand substitution vs ligand addition. 2. Reaction of dimethylamine with nonacarbonylbis(.mu.3-sulfido)triruthenium and the crystal and molecular structures of Ru3(CO)7(NHMe2)(.mu.-Me2NC:O)(.mu.3-S)2(.mu.-H) and Ru3(CO)6(NHMe2)(.mu.-Me2NC:O)2(.mu.3-S)2
Richard D. Adams and James E. Babin
pp 4010 - 4015; DOI:
10.1021/ic00242a037
PDF
Synthesis and characterization of a lacunar bis(isothiocyanato)cobalt(III) cyclidene complex: a structural model for distal steric effects in hemoproteins
Patricia J. Jackson, Colin Cairns, Wang Kan Lin, Nathaniel W. Alcock, and Daryle H. Busch
pp 4015 - 4020; DOI:
10.1021/ic00242a038
PDF
Cis and trans derivatives of sulfur hexafluoride resulting from oxidative-addition-displacement reactions of (trifluoromethyl)imidosulfites with chlorine fluoride
Helen M. Marsden and Jean'ne M. Shreeve
pp 4021 - 4027; DOI:
10.1021/ic00242a039
PDF
Menschutkin type amine alkylations involving methyl transfer from platinum(II) chelate complexes of o-(diphenylphosphino)thiophenetole
Annamarie Benefiel and D. Max Roundhill
pp 4027 - 4031; DOI:
10.1021/ic00242a040
PDF
Framework isomerism of mixed tetranuclear clusters
Manfred Mueller, Hans Thomas Schacht, Klaus Fischer, Juergen Ensling, Philipp Guetlich, and Heinrich Vahrenkamp
pp 4032 - 4038; DOI:
10.1021/ic00242a041
PDF
Organometallic chemistry of rhodium tetraphenylporphyrin derivatives: formyl, hydroxymethyl, and alkyl complexes
Bradford B. Wayland, Seth L. Van Voorhees, and Charles Wilker
pp 4039 - 4042; DOI:
10.1021/ic00242a042
PDF
Redox properties of polypyridyl-aqua complexes of osmium
David W. Pipes and Thomas J. Meyer
pp 4042 - 4050; DOI:
10.1021/ic00242a043
PDF
Synthesis of acetylene adducts of an iron-molybdenum cluster through trapping experiments on (C5H5)2Mo2FeTe2(CO)x: conversion of arachno-(C5H5)2Mo2FeTe2(CO)7 to closo-(C5H5)2Mo2FeTe2(CO)3(RC2H)
Leonard E. Bogan, George R. Clark, and Thomas B. Rauchfuss
pp 4050 - 4052; DOI:
10.1021/ic00242a044
PDF
Chelation of cis-halo(oxalato)tetraamminechromium(III) complexes: evidence for direct displacement of a coordinated anion by another
C. Narayanaswamy, T. Ramasami, and D. Ramaswamy
pp 4052 - 4054; DOI:
10.1021/ic00242a045
PDF
Ternary rhodium-tungsten-sulfur clusters
A. R. Siedle and W. B. Gleason
pp 4054 - 4057; DOI:
10.1021/ic00242a046
PDF
Crystal and molecular structure of chloramine-T trihydrate. Absence of a sodium-nitrogen interaction in the oxidant. N-chloro-N-sodiotoluene-p-sulfonamide
Marilyn M. Olmstead and Philip P. Power
pp 4057 - 4058; DOI:
10.1021/ic00242a047
PDF
Reversible addition of carbon monoxide to a trirhodium cluster: synthesis and x-ray crystal structure of .mu.-carbonyltetracarbonyltris(.mu.-di-tert-butylphosphido)trirhodium
Richard A. Jones and Thomas C. Wright
pp 4058 - 4060; DOI:
10.1021/ic00242a048
PDF
Metal complexes with polydentate sulfur-containing ligands. Crystal structure of (2,6-bis((ethylthio)methyl)pyridine)dibromozinc(II)
Francesc Teixidor, Lluis Escriche, Jaume Casabo, Elias Molins, and Carlos Miravitlles
pp 4060 - 4062; DOI:
10.1021/ic00242a049
PDF
Variable-temperature magic-angle-spinning carbon-13 NMR of solid dodecacarbonyltriiron
Brian E. Hanson, Edward C. Lisic, John T. Petty, and Gennaro A. Iannaconne
pp 4062 - 4064; DOI:
10.1021/ic00242a050
PDF
Linkage isomers of pentammineselenocyanatoruthenium(III) cation: synthesis and characterization
V. Palaniappan and U. C. Agarwala
pp 4064 - 4066; DOI:
10.1021/ic00242a051
PDF

Issue 23


Chemical and electrochemical redox transformations of oxomolybdenum and oxotungsten tetrathiolate complexes
S. L. Soong, V. Chebolu, S. A. Koch, T. O'Sullivan, and M. M. Millar
pp 4067 - 4068; DOI:
10.1021/ic00243a001
PDF
Dichlorotetrakis(pyridine)cobalt(III): a versatile and facile synthetic precursor
W. L. Purcell
pp 4068 - 4069; DOI:
10.1021/ic00243a002
PDF
Electronic control of the structural stability of quasiperiodic linear chains
Jeremy K. Burdett and Gordon J. Miller
pp 4069 - 4071; DOI:
10.1021/ic00243a003
PDF
Bromine atom abstraction from aryl and alkyl bromides by the triplet excited state of tetrakis(.mu.-pyrophosphito)diplatinum(II) tetraanion
D. Max Roundhill and Stephen J. Atherton
pp 4071 - 4072; DOI:
10.1021/ic00243a004
PDF
Discrete metal-sulfide-thiolate complexes of an early-3d-transition metal
Joanna K. Money, John R. Nicholson, John C. Huffman, and George Christou
pp 4072 - 4074; DOI:
10.1021/ic00243a005
PDF
Synthetic, spectroscopic and solution NMR studies of dimethyltin(IV) fluorosulfate derivatives
S. P. Mallela, S. Yap, J. R. Sams, and F. Aubke
pp 4074 - 4080; DOI:
10.1021/ic00243a006
PDF
Polyfluoroalkanediyl bis(phosphates), 5,5,6,6-tetrafluoro-2-hydroxy-1,3,2-dioxaphosphepane 2-oxide, and their precursors
Tariq Mahmood and Jean'ne M. Shreeve
pp 4081 - 4084; DOI:
10.1021/ic00243a007
PDF
Kinetics and mechanism for reduction of ammine and haloammine complexes of gold(III) by iodide
Lars I. Elding and L. H. Skibsted
pp 4084 - 4087; DOI:
10.1021/ic00243a008
PDF
Manganese(0) radicals and the reduction of cationic carbonyl complexes: selectivity in the ligand dissociation from 19-electron species
D. J. Kuchynka, C. Amatore, and J. K. Kochi
pp 4087 - 4097; DOI:
10.1021/ic00243a009
PDF
Reduction chemistry of Fe2(NO)4(.mu.-PR2)2 (R = phenyl, cyclohexyl) and protonation and alkylation of resultant binuclear iron nitrosyl anions
Yuan Fu Yu, Chung Nin Chau, and Andrew Wojcicki
pp 4098 - 4104; DOI:
10.1021/ic00243a010
PDF
Electron-transfer reactions between pentaaquo(organo)chromium(2+) and tris(bipyridyl)ruthenium(3+) ions
Jon D. Melton, James H. Espenson, and Andreja Bakac
pp 4104 - 4108; DOI:
10.1021/ic00243a011
PDF
Characterization of the structure, properties, and reactivity of a cobalt(II) macrocyclic complex
Andreja Bakac, Mark E. Brynildson, and James H. Espenson
pp 4108 - 4114; DOI:
10.1021/ic00243a012
PDF
Hydrolysis of the nickel-carbon bond of organonickel tetramethylcyclam complexes
M. S. Ram, James H. Espenson, and Andreja Bakac
pp 4115 - 4118; DOI:
10.1021/ic00243a013
PDF
Synthesis of N-substituted (ethylenediaminetriacetato)(thiocyanato)cobaltate(III) complexes and structural characterization by proton and carbon-13 NMR spectroscopy
Kenneth E. Rohly, Bodie E. Douglas, and Chris Maricondi
pp 4119 - 4125; DOI:
10.1021/ic00243a014
PDF
Organometallic S,S ligands with .pi.-donor properties. Structures and magnetism of bis(cyclopentadienyl)tetrakis(dimethyl monothiophosphito)trinickel [{(C5H5)Ni[P(S)(OCH3)2]2}2Ni], a complex with tetrahedral NiS4 coordination
Wolfgang Klaui, Karin Schmidt, Anja Bockmann, David J. Brauer, Jochen Wilke, Heiko Lueken, and Ulrich Elsenhans
pp 4125 - 4130; DOI:
10.1021/ic00243a015
PDF
Steric effects on the solution chemistry of nickel(II) complexes with N-monomethylated 14-membered tetraaza macrocycles. The blue-to-yellow conversion and the oxidation and reduction behavior
Mario Ciampolini, Luigi Fabbrizzi, Maurizio Licchelli, Angelo Perotti, Franca Pezzini, and Antonio Poggi
pp 4131 - 4135; DOI:
10.1021/ic00243a016
PDF
Ligand dissociation in octahedral ruthenium(II) complexes containing both unidentate and bidentate phosphine ligands
LeRoy L. Whinnery, Hong Jun Yue, and John A. Marsella
pp 4136 - 4139; DOI:
10.1021/ic00243a017
PDF
X-ray structure and reactivity of bis(2,2'-bipyridine)carbonylhydridoruthenium hexafluorophosphate hemi(acetone), a possible intermediate in the water-gas shift reaction catalyzed by ruthenium polypyridyl complexes
Jaap G. Haasnoot, Winfried Hinrichs, Orla Weir, and Johannes G. Vos
pp 4140 - 4143; DOI:
10.1021/ic00243a018
PDF
Coordination chemistry of the bicycloaminophosphorane Ph(H)P[(OCH2CH2)2N], a potential P/N ligand. Access to iron and ruthenium phosphoranides. Reversible migration of a phenyl group between iron and phosphorus: crystal and molecular structure of .eta.5-CpFe(CO)[P(OCH2CH2)2N](.eta.1-C6H5)
Pierre Vierling, Jean G. Riess, and Andre Grand
pp 4144 - 4152; DOI:
10.1021/ic00243a019
PDF
Syntheses of secondary-amine-substituted bis(phosphino)molybdenum tetracarbonyl complexes
Abbas Tarassoli, Haw Jan Chen, Martin L. Thompson, Viloya S. Allured, R. Curtis Haltiwanger, and Arlan D. Norman
pp 4152 - 4157; DOI:
10.1021/ic00243a020
PDF
(N,N'-Ethylenebis(acetylacetone iminato))vanadium(III) derivatives: syntheses and substitution reactions at the vanadium-chlorine bond
Marinella Mazzanti, Carlo Floriani, Angiola Chiesi-Villa, and Carlo Guastini
pp 4158 - 4164; DOI:
10.1021/ic00243a021
PDF
Structural studies on polynuclear osmium carbonyl hydrides. 33. Formation of tungsten-triosmium clusters. Crystal structure and reactivity of (.eta.5-C5H5)WOs3(CO)12(.mu.3-CC6H4CH3)(.mu.-H)2
Yun Chi, John R. Shapley, Melvyn Rowen Churchill, and Yong Ji Li
pp 4165 - 4170; DOI:
10.1021/ic00243a022
PDF
Trialkoxynitridomolybdenum compounds: (RO)3Mo.ident.N. Preparation, structures (R = tert-Bu and iso-Pr), and comparisons with a tungsten analog (R = tert-Bu)
Dominic M. T. Chan, Malcolm H. Chisholm, Kirsten Folting, John C. Huffman, and Nancy S. Marchant
pp 4170 - 4174; DOI:
10.1021/ic00243a023
PDF
Copper(II) and nickel(II) trinuclear species with dithiooxamide derivative ligands: structural, magnetic, spectroscopic, and electrochemical properties
Richard Veit, Jean Jacques Girerd, Olivier Kahn, Francis Robert, and Yves Jeannin
pp 4175 - 4180; DOI:
10.1021/ic00243a024
PDF
Reactions of cadmium thiolate (Cd(SR)2, R = n-butyl, phenyl) and the molecular structure of the 2,2'-bipyridine adduct of bis(n-butyl thioxanthato)cadmium(II)
S. Jill Amberson, F. W. B. Einstein, Peter C. Hayes, Rajesh Kumar, and Dennis G. Tuck
pp 4181 - 4184; DOI:
10.1021/ic00243a025
PDF
Synthesis and characterization of a platinum-mercury "A-frame" cluster
Paul R. Sharp
pp 4185 - 4189; DOI:
10.1021/ic00243a026
PDF
Oxidative addition of thiocyanate to coordinatively unsaturated trinuclear clusters: structures of [Pt3(SCN)(.mu.3-CO)(.mu.-dppm)3]+ and [Pd3(.mu.3-S)(CN)(.mu.-dppm)3]+ (dppm = bis(diphenylphosphino)methane)
George Ferguson, Brian R. Lloyd, Ljubica Manojlovic-Muir, Kenneth W. Muir, and Richard J. Puddephatt
pp 4190 - 4197; DOI:
10.1021/ic00243a027
PDF
Thermodynamic and structural studies of configurational isomers of (1,4,8,11-tetraazacyclotetradecane)nickel(2+)
E. Kent Barefield, Antonio Bianchi, E. Joseph Billo, Peter J. Connolly, Piero Paoletti, Jack S. Summers, and Donald G. Van Derveer
pp 4197 - 4202; DOI:
10.1021/ic00243a028
PDF
Structure and magnetism in ACuCl3 salts containing bibridged chains with square-pyramidal coordination geometry
U. Geiser, R. M. Gaura, R. D. Willett, and D. X. West
pp 4203 - 4212; DOI:
10.1021/ic00243a029
PDF
A mixed-valence titanium(III)-titanium(IV) tetramer and related compounds
L. Maya
pp 4213 - 4217; DOI:
10.1021/ic00243a030
PDF
Chromium(III)-doped pillared clays (PILC's)
K. A. Carrado, S. L. Suib, N. D. Skoularikis, and R. W. Coughlin
pp 4217 - 4221; DOI:
10.1021/ic00243a031
PDF
CEPA calculations on open-shell molecules. 7. Electronic structure and properties of HNS
Jan Wasilewski and Volker Staemmler
pp 4221 - 4228; DOI:
10.1021/ic00243a032
PDF
Multiplet theory of transition-metal ions
L. G. Vanquickenborne, P. Hoet, and K. Pierloot
pp 4228 - 4233; DOI:
10.1021/ic00243a033
PDF
Evidence for specific solvent-solute interactions as a major contributor to the Franck-Condon energy in intervalence-transfer absorptions of ruthenium ammine complexes
Junghae P. Chang, Ella Y. Fung, and Jeff C. Curtis
pp 4233 - 4241; DOI:
10.1021/ic00243a034
PDF
Weak exchange interactions between nitroxides and copper(II) ions monitored by EPR spectroscopy
C. Benelli, D. Gatteschi, C. Zanchini, J. M. Latour, and P. Rey
pp 4242 - 4244; DOI:
10.1021/ic00243a035
PDF
High-spin .fwdarw. low-spin relaxation kinetics and cooperative effects in the hexakis(1-propyltetrazole)iron bis(tetrafluoroborate) and [Zn1-xFex(ptz)6](BF4)2(ptz = 1-propyltetrazole) spin-crossover systems
Andreas Hauser, Philipp Guetlich, and Hartmut Spiering
pp 4245 - 4248; DOI:
10.1021/ic00243a036
PDF
Flash photolysis and pulse radiolysis of the Co(sep)3+-X- (sep = sepulchrate; X = I, Br) systems in aqueous solution
Fernando Pina, Mauro Maestri, Roberto Ballardini, Quinto G. Mulazzani, Mila D'Angelantonio, and Vincenzo Balzani
pp 4249 - 4252; DOI:
10.1021/ic00243a037
PDF
Volume profiles for the base hydrolysis of a series of monoalkyl-substituted chloropentaamminecobalt(III) complexes in aqueous solution
Rudi Van Eldik, Yoichi Kitamura, and Carlos P. Piriz Mac-Coll
pp 4252 - 4256; DOI:
10.1021/ic00243a038
PDF
Thermodynamic aspects of the nickel(III/II) redox change in polyaza macrocyclic complexes
Luigi Fabbrizzi, Angelo Perotti, Antonella Profumo, and Teresa Soldi
pp 4256 - 4259; DOI:
10.1021/ic00243a039
PDF
Template syntheses involving carbon acids. Synthesis and characterization of (3,10-dimethyl-3,10-dinitro-1,4,8,11-tetraazacyclotetradecane)copper(II) and (1,9-diamino-5-methyl-5-nitro-3,7-diazanonane)copper(II) cations and nitro group reduction products
Peter Comba, Neil F. Curtis, Geoffrey A. Lawrance, Alan M. Sargeson, Brian W. Skelton, and Allan H. White
pp 4260 - 4267; DOI:
10.1021/ic00243a040
PDF
Characterization of [bis(acetylacetone)ethylenediiminato]dichlorovanadium(IV), VCl2(acen), and its hydrolysis product, [bis(acetylacetone)ethylenediimine]chlorooxovanadium(IV) chloride, [VO(H2acen)Cl]Cl
R. Seangprasertkij and Thomas L. Riechel
pp 4268 - 4271; DOI:
10.1021/ic00243a041
PDF
Models for the interaction of zinc(2+) with DNA. Syntheses and x-ray structural characterizations of two polymeric tetrahedral zinc complexes of monomethyl phosphate esters of cytidine and deoxycytidine 5'-monophosphate nucleotides
Sandra K. Miller, Luigi G. Marzilli, Stefan Doerre, Petra Kollat, Rolf Dietrich Stigler, and John J. Stezowski
pp 4272 - 4277; DOI:
10.1021/ic00243a042
PDF
Synthesis, characterization, and electrochemistry of indium(III) porphyrins that contain a stable indium-carbon .sigma. bond
A. Tabard, R. Guilard, and K. M. Kadish
pp 4277 - 4285; DOI:
10.1021/ic00243a043
PDF
Rapid base-catalyzed deuterium exchange at the ring-adjacent methyl and methylene positions of octaalkyl and natural-derivative porphyrins and metalloporphyrins
Gregory M. Godziela, Susan K. Kramer, and Harold M. Goff
pp 4286 - 4288; DOI:
10.1021/ic00243a044
PDF
Raman and infrared spectroscopic studies of dioxomolybdenum(VI) complexes with cysteamine chelates
Lawrence J. Willis, Thomas M. Loehr, Kenneth F. Miller, Alice E. Bruce, and Edward I. Stiefel
pp 4289 - 4293; DOI:
10.1021/ic00243a045
PDF
Molecular environment effects in redox and coordination chemistry. Protection against solvation, local solvation, and steric hindrance to ligation in the electrochemistry of basket-handle iron porphyrins
Claire Gueutin, Doris Lexa, Michel Momenteau, Jean Michel Saveant, and Feng Xu
pp 4294 - 4307; DOI:
10.1021/ic00243a046
PDF
Iron-sulfur bond lengths in ferrous-carbonyl heme complexes as a function of sulfur donor type
Lung Shan Kau, Edmund W. Svastits, John H. Dawson, and Keith O. Hodgson
pp 4307 - 4309; DOI:
10.1021/ic00243a047
PDF
1,12-Bis(hydroxymethyl)decahydrododecaborate(2-) and B12H10(CH2X)22- and B12H10(CH2L)2 derivatives
Gary T. King and Norman E. Miller
pp 4309 - 4311; DOI:
10.1021/ic00243a048
PDF
Use of infrared spectroscopy to study incorporation of trivalent elements into molecular sieve gels
R. Szostak and T. L. Thomas
pp 4311 - 4312; DOI:
10.1021/ic00243a049
PDF
First synthesis of a nitro complex of ruthenium(III), as a key intermediate in the oxidation of nitro ligand to give both nitrosyl and nitrato ligands
Hirotaka Nagao, Masao Mukaida, Kunio Shimizu, F. Scott Howell, and Hidetake Kakihana
pp 4312 - 4314; DOI:
10.1021/ic00243a050
PDF
Surface organometallic chemistry: relative reactivity of carbonyl, hydride, and halide ligands in dodecacarbonyltetrahydrotetraosmium and dodecacarbonyltrihydroiodotetraosmium toward magnesia
Lindora D'Ornelas, Agnes Choplin, Jean Marie Basset, Jose Puga, and Robert A. Sanchez-Delgado
pp 4315 - 4316; DOI:
10.1021/ic00243a051
PDF

Issue 24


Synthesis and structural characterization of the tetraphenylphosphonium salts of the sulfido(tetrasulfido(2-))(tetrathiomolybdate)molybdate(2-) anion and its hexathiodimolybdate(2-) and heptathiodimolybdate(2-) desulfurized derivatives
D. Coucouvanis and A. Hadjikyriacou
pp 4317 - 4319; DOI:
10.1021/ic00244a001
PDF
High-nuclearity clusters containing carbene ligands. Synthesis, structural analyses, and isomerization of disulfidohexaosmium carbonyl cluster compounds containing secondary (dimethylamino)carbene ligands
Richard D. Adams, James E. Babin, and Hoon Sik Kim
pp 4319 - 4320; DOI:
10.1021/ic00244a002
PDF
Synthesis of a new family of water-soluble clusters: Ru3(CO)12-xLx (x = 1-3), Os3(CO)10L2, and Ir4(CO)9L3 (L = trisodium salt (hydrated) of tris(m-sulfonatophenyl)phosphine)
B. Fontal, J. Orlewski, C. C. Santini, and J. M. Basset
pp 4320 - 4322; DOI:
10.1021/ic00244a003
PDF
Reactions of osmium(IV) complexes of PAC ligands with azide species
Claudia J. Barner, Terrence J. Collins, Brian E. Mapes, and Bernard D. Santarsiero
pp 4322 - 4323; DOI:
10.1021/ic00244a004
PDF
Syntheses of stabilized linear tetraphosphazanes
Joseph M. Barendt, R. Curtis Haltiwanger, and Arlan D. Norman
pp 4323 - 4325; DOI:
10.1021/ic00244a005
PDF
Resonance Raman spectra of charge-transfer excited states of copper(I) complexes
John J. McGarvey, Steven E. J. Bell, and Joseph N. Bechara
pp 4325 - 4327; DOI:
10.1021/ic00244a006
PDF
Correlation between tin-119 isomer shifts and quadrupole coupling constants for dimethyltin(IV) salts of strong protonic acids and superacids
S. P. Mallela, S. Yap, J. R. Sams, and F. Aubke
pp 4327 - 4329; DOI:
10.1021/ic00244a007
PDF
Synthesis and crystal structure determination of a propylene glycol bridged molybdenum(VI) peroxo dimer, [MoO(O2)(C3H6O2)(CH3OH)]2.2CH3OH
Wilfred Shum
pp 4329 - 4330; DOI:
10.1021/ic00244a008
PDF
Ligand isotopic exchange kinetics of tris(acetylacetonato)aluminum(III) in acetylacetone under atmospheric and elevated pressures
Akira Nagasawa, Hiroaki Kido, Tomoko M. Hattori, and Kazuo Saito
pp 4330 - 4333; DOI:
10.1021/ic00244a009
PDF
Thermal and light-induced reduction of (+)-tris(bipyridyl)ruthenium(III) in aqueous solution: mechanistic inferences from optical rotation studies
Dilip Kotkar, Vishwas Joshi, and Pushpito K. Ghosh
pp 4334 - 4335; DOI:
10.1021/ic00244a010
PDF
Reactions of metalloporphyrins possessing metal-metal bonds. Synthesis and electrochemical studies of iron-tin (P)Sn(II)Fe(CO)4 and germanium-iron (P)Ge(II)Fe(CO)4 where P = octaethylporphyrin or tetraarylporphyrin
K. M. Kadish, C. Swistak, B. Boisselier-Cocolios, J. M. Barbe, and R. Guilard
pp 4336 - 4343; DOI:
10.1021/ic00244a011
PDF
Atom-transfer redox kinetics: general-acid-assisted oxidation of iodide by chloramines and hypochlorite
Krishan Kumar, Richard A. Day, and Dale W. Margerum
pp 4344 - 4350; DOI:
10.1021/ic00244a012
PDF
Synthesis and x-ray crystal structure of arachno-6-(trimethylsilyl)-6,9-dicarbatridecahydrooctaborane through a cage-expansion reaction of nido-2,3-bis(trimethylsilyl)-2,3-dicarbahexahydrotetraborane
Joseph R. Wermer, Narayan S. Hosmane, John J. Alexander, Upali Siriwardane, and Sheldon G. Shore
pp 4351 - 4354; DOI:
10.1021/ic00244a013
PDF
Synthesis, structure, and transport properties of tantalum nickel selenide (Ta2NiSe7) and tantalum platinum selenide (Ta2PtSe7)
Steven A. Sunshine and James A. Ibers
pp 4355 - 4358; DOI:
10.1021/ic00244a014
PDF
Oxidation-state-dependent changes in the coordination environment of oxovanadium complexes of ethylenebis((o-hydroxyphenyl)glycine)
Joseph A. Bonadies and Carl J. Carrano
pp 4358 - 4361; DOI:
10.1021/ic00244a015
PDF
Effect of crystal structure and percentage of ion exchange on ESR spectra of hydrated iron(III) ion exchanged synthetic zeolites
N. P. Evmiridis
pp 4362 - 4369; DOI:
10.1021/ic00244a016
PDF
Synthesis and crystal and molecular structure of trimethylammonium 7,8-dimercapto-7,8-dicarbaundecaborate(10) and trimethylammonium anti-7,7':8,8'-bis[dithio)bis(7,8-dicarbaundecaborate(10)]
C. Vinas, W. M. Butler, F. Teixidor, and R. W. Rudolph
pp 4369 - 4374; DOI:
10.1021/ic00244a017
PDF
Halogen ordering in cesium chromium chloride bromide (Cs3Cr2Cl6Br3): a spectroscopic study
Stephen E. Butler, Peter W. Smith, Robert Stranger, and Ian E. Grey
pp 4375 - 4378; DOI:
10.1021/ic00244a018
PDF
Synthesis of the new thia-aza cage 12,17-dimethyl-5-thia-1,9,12,17-tetraazabicyclo[7.5.5]nonadecane. Thermodynamic studies on protonation and copper(II) complex formation
Antonio Bianchi, Enrique Garcia-Espana, Mauro Micheloni, Nicoletta Nardi, and Francesco Vizza
pp 4379 - 4381; DOI:
10.1021/ic00244a019
PDF
Theoretical studies on inorganic ring systems. Tetraphosphabicyclobutane, cyclotriphosphane, and white phosphorus: ring strain and hybridization
Wolfgang W. Schoeller, Volker Staemmler, Paul Rademacher, and Edgar Niecke
pp 4382 - 4385; DOI:
10.1021/ic00244a020
PDF
Vanadium-sensitized photochemistry of heteropoly compounds. Mixed molybdo- and tungstovandates
P. Argitis and E. Papaconstantinou
pp 4386 - 4389; DOI:
10.1021/ic00244a021
PDF
Solid-state kinetic parameters and mechanism for the deaquation-anation of trans-fluoroaquabis(diamine)chromium(III) complexes containing chloride, bromide, iodide, and dithionate. Influence of amine size, entering anion, and trans to cis isomerization
Montserrat Corbella and Joan Ribas
pp 4390 - 4395; DOI:
10.1021/ic00244a022
PDF
Boron analogs of choline. 2. Efficient syntheses of boron analogs of choline, acetylcholine, and substituted acetylcholines
Bernard F. Spielvogel, Fahim U. Ahmed, and Andrew T. McPhail
pp 4395 - 4399; DOI:
10.1021/ic00244a023
PDF
Molecular geometry and fluxionality of the AX6E system ClF6-
Preston J. MacDougall
pp 4400 - 4404; DOI:
10.1021/ic00244a024
PDF
Mass spectral studies on the thermal decomposition of tetrasulfur tetranitride and the mechanism for formation of polymeric sulfur nitride
Elizabeth Besenyei, Guenter K. Eigendorf, and David C. Frost
pp 4404 - 4408; DOI:
10.1021/ic00244a025
PDF
Electrochemical reduction of seven-coordinate oxomolybdenum(VI) complexes. Multielectron transfer at mononuclear MoO4+ centers
Julie R. Bradbury and Franklin A. Schultz
pp 4408 - 4416; DOI:
10.1021/ic00244a026
PDF
Synthesis and properties of seven-coordinate (catecholato)bis(dithiocarbamato)oxomolybdenum(VI) complexes exhibiting metal- and ligand-centered electrochemistry
Julie R. Bradbury and Franklin A. Schultz
pp 4416 - 4422; DOI:
10.1021/ic00244a027
PDF
Reversible intramolecular isomerization associated with the electron-transfer reactions of mixed-carbonyl-isocyanide-phosphine complexes of molybdenum of the type [Mo(CO)2(CNR)2(PR'3)2]+/0
Kay A. Conner and Richard A. Walton
pp 4422 - 4430; DOI:
10.1021/ic00244a028
PDF
NMR and potentiometric studies of lithium salts in 1-butylpyridinium chloride-aluminum(III) chloride molten systems
Rick R. Rhinebarger, John W. Rovang, and Alexander I. Popov
pp 4430 - 4433; DOI:
10.1021/ic00244a029
PDF
Back-reactions in the photochemical disproportionation of hexacarbonylbis(methylcyclopentadienyl)dimolybdenum and the wavelength-dependent photochemistry of the Cp2Mo2(CO)6 complex with triphenylphosphine
Cecelia E. Philbin, Alan S. Goldman, and David R. Tyler
pp 4434 - 4436; DOI:
10.1021/ic00244a030
PDF
Molecular interstitials: an analysis of the gadolinium carbide chloride, Gd2C2Cl2
Gordon J. Miller, Jeremy K. Burdett, Christine Schwarz, and Arndt Simon
pp 4437 - 4444; DOI:
10.1021/ic00244a031
PDF
Electrocrystallization of poorly conducting charge-transfer complexes
Michael D. Ward
pp 4444 - 4446; DOI:
10.1021/ic00244a032
PDF
Heats of reaction of [Mo(CO)2Cp*]2 (Cp* = C5H5, C5Me5, C9H7) with carbon monoxide, acetylene, and phenylacetylene. Thermochemical investigation of the molybdenum-molybdenum triple bond
Steven P. Nolan, Ramon Lopez de la Vega, and Carl D. Hoff
pp 4446 - 4448; DOI:
10.1021/ic00244a033
PDF
Convenient synthetic route to coordination and organometallic compounds of alkanenitronate [O2N:CCR']- anions
B. N. Diel and H. Hope
pp 4448 - 4451; DOI:
10.1021/ic00244a034
PDF
Convenient synthesis of thiazyl hexafluoroarsenate(V), [SN]+[AsF6]-, and small quantities of thiazyl fluoride, NSF
Allen Apblett, Arthur J. Banister, David Biron, Aidan G. Kendrick, Jack Passmore, Melbourne Schriver, and Milena Stojanac
pp 4451 - 4452; DOI:
10.1021/ic00244a035
PDF
Kinetic study of ternary complex formation between (terpyridine)nickel and isomeric (pyridylazo)naphthol dyes: acceleration of a ring-closure step
Richard L. Reeves and James A. Reczek
pp 4452 - 4454; DOI:
10.1021/ic00244a036
PDF
Quenching of excited-state reactivity of (oxalato)bis(triethylphosphine)platinum(II) by water
Andrea L. Prignano and William C. Trogler
pp 4454 - 4456; DOI:
10.1021/ic00244a037
PDF

Issue 25


Concerning the nonadiabaticity problem in outer-sphere electron- and energy-transfer reactions
Vincenzo Balzani and Franco Scandola
pp 4457 - 4459; DOI:
10.1021/ic00245a001
PDF
High-nuclearity clusters of ruthenium. Synthesis and crystal and molecular structure of heptadecacarbonyldi-.mu.4-sulfido(.eta.-toluene)octaruthenium
Richard D. Adams, James E. Babin, and Miklos Tasi
pp 4460 - 4461; DOI:
10.1021/ic00245a002
PDF
A monomeric octahedral cobalt(III) complex of a substituted N,N'-bis(salicylidene)diethylenetriamine ligand
A. E. Koziol, R. C. Palenik, and G. J. Palenik
pp 4461 - 4462; DOI:
10.1021/ic00245a003
PDF
ENDOR study of a one-electron 2:18 reduced fluoropolytungstate
D. Gourier, P. Doppelt, and C. Sanchez
pp 4462 - 4464; DOI:
10.1021/ic00245a004
PDF
Selenium-77 nuclear magnetic resonance study of octaselenium(2+) and decaselenium(2+): examples of rigid and fluxional species. Disproportionation of Se102+ at low temperatures
R. C. Burns, M. J. Collins, R. J. Gillespie, and G. J. Schrobilgen
pp 4465 - 4469; DOI:
10.1021/ic00245a005
PDF
Electronic structure of tris(.eta.5-pentamethylcyclopentadienyl)hexa-.mu.-oxotrirhenium(2+) and of related early-transition-metal arene clusters
Peter Hofmann, Notker Roesch, and Helmut R. Schmidt
pp 4470 - 4478; DOI:
10.1021/ic00245a006
PDF
Distinguishable sites in tetranuclear oxocopper(II) complexes (py)3Cu4Cl4O2 and (DENC)3Cu3M(H2O)Cl4O2 (M = Co, Ni, Cu, Zn)
Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Maher Henary, and Colleen A. Martin
pp 4479 - 4487; DOI:
10.1021/ic00245a007
PDF
Pulsed-laser photochemical study of tris(1,10-phenanthroline)chromium(III) ion in acidic and alkaline aqueous media
Jochen Lilie, William L. Waltz, Sang H. Lee, and Linda L. Gregor
pp 4487 - 4492; DOI:
10.1021/ic00245a008
PDF
Radiolytic and electrochemical reduction of tris(2,2'-bipyrazine)ruthenium(2+) in aqueous solution. Stability, redox, and acid-base properties of tris(2,2'-bipyrazine)ruthenium(1+)
Margherita Venturi, Quinto G. Mulazzani, Mauro Ciano, and Morton Z. Hoffman
pp 4493 - 4498; DOI:
10.1021/ic00245a009
PDF
Light-induced reduction of rhodium(III) and palladium(II) on titanium dioxide dispersions and the selective photochemical separation and recovery of gold(III), platinum(IV), and rhodium(III) in chloride media
Enrico Borgarello, Nick Serpone, Gary Emo, Ron Harris, Ezio Pelizzetti, and Claudio Minero
pp 4499 - 4503; DOI:
10.1021/ic00245a010
PDF
Terbium ion binding to a synthetic .gamma.-carboxyglutamic acid containing heptapeptide corresponding to bovine prothrombin residues 17-23
Henry C. Marsh, Randal A. Hoke, David W. Deerfield, Lee G. Pedersen, Richard G. Hiskey, and Karl A. Koehler
pp 4503 - 4506; DOI:
10.1021/ic00245a011
PDF
Spectrophotometric and voltammetric characterization of complexes of bis(2,2'-bipyridine)(2,2'-bibenzimidazole)ruthenium and -osmium in oxidation states II, III, and IV in acetonitrile/water mixtures
Alan M. Bond and Masaaki Haga
pp 4507 - 4514; DOI:
10.1021/ic00245a012
PDF
Cluster syntheses. 13. Chemistry of sulfido ruthenium carbonyl clusters. Synthesis and characterization of the new unsaturated ruthenium carbonyl dimethylphenylphosphine sulfido clusters, Ru4(CO)11-nLn(.mu.4-S)2 (n = 0-2, L = PMe2Ph)
Richard D. Adams, James E. Babin, and Miklos Tasi
pp 4514 - 4519; DOI:
10.1021/ic00245a013
PDF
Synthesis, structure and reactivity of polymeric tetrabutylammonium di-.mu.-chlorobis(pentachlorophenyl)platinateargentate(1-), a novel chain polymeric Pt-Ag compound. Structure of (NBu4)[PtAgCl2(C6Cl5)2(PPh3)] and [Pt(C6Cl5)2(.mu.-Cl)2Ag2(PPh2Me)2]
Rafael Uson, Juan Fornies, Milagros Tomas, Jose M. Casas, F. Albert Cotton, and Larry R. Falvello
pp 4519 - 4525; DOI:
10.1021/ic00245a014
PDF
A second example of rupture and realignment of the phosphine bridge orientation in polynuclear complexes. The formation and structure of bis(.mu.-2,6-bis(diphenylphosphino)pyridine)(.mu.-iodo)(.mu.-carbonyl)dirhodium tetraphenylborate
Alan L. Balch, L. Alan Fossett, and Marilyn M. Olmstead
pp 4526 - 4529; DOI:
10.1021/ic00245a015
PDF
Infrared spectrum of hexacarbonylbis(.mu.-carbonyl)(.mu.-methylene)diiron, Fe2(CO)6(.mu.-CO)2(.mu.-CH2), in cryogenic matrixes
Sou Chan Chang, Zakya H. Kafafi, Robert H. Hauge, Kenton H. Whitmire, W. Edward Billups, and John L. Margrave
pp 4530 - 4533; DOI:
10.1021/ic00245a016
PDF
NMR studies and structure of the [3]ferrocenophanes Fe(.eta.5-C5H4S3)(.eta.5-C5H3P(S)Ph2-1,n) (n = 2 or 3)
Ian R. Butler, William R. Cullen, F. Geoffrey Herring, N. R. Jagannathan, Frederick W. B. Einstein, and Richard Jones
pp 4534 - 4541; DOI:
10.1021/ic00245a017
PDF
Crystal structure and magnetic properties of the cluster complex tris(1-cysteinethiolato)pentacopper(2+) perchlorate monohydrate, a mixed-valence copper-mercaptide species
Parimal K. Bharadwaj, Elizabeth John, Chuan Liang Xie, Dechun Zhang, David N. Hendrickson, Joseph A. Potenza, and Harvey J. Schugar
pp 4541 - 4546; DOI:
10.1021/ic00245a018
PDF
Multiply bonded octahalodiosmate(III) anions. 3. Synthesis and characterization of the octahalodiosmate(III) anion [Os2X8]2- (X = Cl, Br). Crystal structure determinations of two forms of (PPN)2Os2Cl8 (PPN = bis(triphenylphosphine)nitrogen(1+)
Phillip E. Fanwick, Stephen M. Tetrick, and Richard A. Walton
pp 4546 - 4552; DOI:
10.1021/ic00245a019
PDF
Comparisons of .pi.-bonding and hydrogen bonding in isomorphous compounds: [M(NH3)5Cl]Cl2 (M = Cr, Co, Rh, Ir, Ru, Os)
Trevor W. Hambley and Peter A. Lay
pp 4553 - 4558; DOI:
10.1021/ic00245a020
PDF
Crystal structure of tetrakis(tetraethylammonium) dodecachlorotetracuprate(4-), a new structural type for a tetranuclear copper(II) halide complex
R. D. Willett and Urs Geiser
pp 4558 - 4561; DOI:
10.1021/ic00245a021
PDF
Synthesis and structure of Cp2Cp12Mo4S4 cubane clusters: an affirmation of the Dahl binding model
P. Douglas Williams and M. David Curtis
pp 4562 - 4570; DOI:
10.1021/ic00245a022
PDF
Kinetics of vanadium(III)-chromium(II) electron transfer revisited
Francois P. Rotzinger
pp 4570 - 4572; DOI:
10.1021/ic00245a023
PDF
Rates of nitrous oxide production in the oxidation of hydroxylamine by iron(III)
James H. Butler and Louis I. Gordon
pp 4573 - 4577; DOI:
10.1021/ic00245a024
PDF
Electron paramagnetic resonance studies of the intramolecular coordination in superstructured iron(III) porphyrins
Corinne Schaeffer, Michel Momenteau, Joel Mispelter, Bernard Loock, Christiane Huel, and Jean Marc Lhoste
pp 4577 - 4583; DOI:
10.1021/ic00245a025
PDF
Isolation and structure of bis(ethane-1,2-dithiolato)(trimethylsilyloxy)vanadate(1-), an intermediate in the conversion of [VO(edt)2]2- to [VS(edt)2]2- (edt2 = ethane-1,2-dithiolate) with (Me3Si)2S. EPR characterization of the series [VE(LL)2]z- (E = O, S, OSiMe3, LL = edt; E = O, LL = propane-1,3-dithiolato
Joanna K. Money, Kirsten Folting, John C. Huffman, David Collison, J. Temperley, Frank E. Mabbs, and George Christou
pp 4583 - 4589; DOI:
10.1021/ic00245a026
PDF
How a bifunctional complex drives reactivity of carbon dioxide-like molecules: sodium [N,N'-ethylenebis(salicylaldiminato)]cobaltate(I) promotion of the reductive coupling of molecules resembling carbon dioxide
Francesco Arena, Carlo Floriani, A. Chiesi-Villa, and Carlo Guastini
pp 4589 - 4596; DOI:
10.1021/ic00245a027
PDF
Use of bromine(I) fluorosulfate for the preparation of new N-bromo sulfonimides
Sukhjinder Singh and Darryl D. DesMarteau
pp 4596 - 4597; DOI:
10.1021/ic00245a028
PDF
Synthesis, characterization, and reactivity of phosphine- and arsine-bridged dirhodium complexes containing bridging pyrazolate and triazolate ligands
Christopher J. Janke, Louis J. Tortorelli, James L. E. Burn, Craig A. Tucker, and Clifton Woods
pp 4597 - 4602; DOI:
10.1021/ic00245a029
PDF
Extended Hueckel calculations and the role of d orbitals in transition-metal-cluster bonding
D. G. Evans
pp 4602 - 4604; DOI:
10.1021/ic00245a030
PDF
Catalytic hydrogen-deuterium exchange in deuteriated alcohols promoted by early-transition-metal alkoxides. Insight into a mechanistic puzzle
William A. Nugent and Rosalie M. Zubyk
pp 4604 - 4606; DOI:
10.1021/ic00245a031
PDF
Reactions of hydrogen chloride(g), deuterium chloride(g), and hydrogen bromide(g) with the adduct pyrazine-phosphorus(V) chloride
Howard C. Knachel, Sherry D. Owens, Steven H. Lawrence, Mary E. Dolan, Michael C. Kerby, and Terese A. Salupo
pp 4606 - 4608; DOI:
10.1021/ic00245a032
PDF
Comparative matrix isolation and time-resolved infrared studies on the photochemistry of decacarbonylmanganeserhenium and decacarbonyldirhenium: evidence for carbonyl-bridged nonacarbonylmanganeserhenium
Stephen Firth, P. Michael Hodges, Martyn Poliakoff, and James J. Turner
pp 4608 - 4610; DOI:
10.1021/ic00245a033
PDF
Kinetics of acid hydrolysis of the nitridotrisulfate ion
David Littlejohn, Abigail R. Wizansky, and S. G. Chang
pp 4610 - 4611; DOI:
10.1021/ic00245a034
PDF
Circular dichroism of the reduction products of tris(2,2'-bypyridine)ruthenium(2+)
Jon S. Gold and Steven J. Milder
pp 4611 - 4612; DOI:
10.1021/ic00245a035
PDF

Issue 26


New organonitrogen derivatized polyoxomolybdate anion clusters. Syntheses and characterization of tetranuclear and octanuclear oxomolybdates containing coordinatively bound organohydrazido(2-) units: [Mo4O10(OCH3)2(NNPh2)2]2- and [Mo8O16(OCH3)6(NNMePh)6]2-
Shahid N. Shaikh and Jon Zubieta
pp 4613 - 4615; DOI:
10.1021/ic00246a001
PDF
The structure of a monomeric phosphinoborane: synthesis and x-ray crystal structure of (diphenylphosphino)dimesitylborane
Xudong Feng, Marilyn M. Olmstead, and Philip P. Power
pp 4615 - 4616; DOI:
10.1021/ic00246a002
PDF
A fluxional high-nuclearity gold-platinum cluster: structure of [Au6Pt(CC-tert-butyl)(PPh3)7]+[Au(CC-tert-butyl)2]-
D. Ewan Smith, Alan J. Welch, Ilse Treurnicht, and Richard J. Puddephatt
pp 4616 - 4617; DOI:
10.1021/ic00246a003
PDF
Reversible double addition of hydrogen on a bis(.mu.-sulfido) binuclear rhodium complex
Claudio Bianchini, Carlo Mealli, Andrea Meli, and Michal Sabat
pp 4617 - 4618; DOI:
10.1021/ic00246a004
PDF
Structural characterization and cage-condensation reactions of the coupled-cage borane 1:2'-[B5H8]2: new routes to higher single-cage boranes and carboranes
James J. Briguglio, Patrick J. Carroll, Edward W. Corcoran, and Larry G. Sneddon
pp 4618 - 4622; DOI:
10.1021/ic00246a005
PDF
Boron-nitrogen compounds. 111. Reactions of borazines with pyrazole and related studies: (.mu.-amido)(.mu.-pyrazolato)diboron species, novel relatives of the pyrazaboles
J. Bielawski, M. K. Das, E. Hanecker, K. Niedenzu, and H. Noeth
pp 4623 - 4628; DOI:
10.1021/ic00246a006
PDF
Reactions of 2-substituted ethylamines with hexachlorocyclotriphosphazene
Christopher W. Allen and John A. MacKay
pp 4628 - 4632; DOI:
10.1021/ic00246a007
PDF
Organophosphazenes. 21. Synthesis of ((.alpha.-methylethenyl)phenyl)fluorocyclotriphosphazenes
Jonathan C. Shaw and Christopher W. Allen
pp 4632 - 4635; DOI:
10.1021/ic00246a008
PDF
Kinetic and isotopic studies on the reaction between trioxodinitrate and the hexaammineruthenium(III) cation
Mohammad Javaid Akhtar, Francis T. Bonner, Martin N. Hughes, Elizabeth J. Humphreys, and Chun Su Lu
pp 4635 - 4639; DOI:
10.1021/ic00246a009
PDF
Kinetics and mechanism of the reaction between trans-dioxotetracyanotungstate(IV) and azide in aqueous solution
Johann G. Leipoldt, Rudi Van Eldik, Stephen S. Basson, and Andreas Roodt
pp 4639 - 4642; DOI:
10.1021/ic00246a010
PDF
Synthesis, characterization, and electrochemical studies of iron, cobalt, and nickel complexes of polyphosphine ligands
Daniel L. DuBois and Alex Miedaner
pp 4642 - 4650; DOI:
10.1021/ic00246a011
PDF
Synthesis, characterization, and photobehavior of macrocyclic difluoro complexes of chromium(III)
Noel A. P. Kane-Maguire, Kevin C. Wallace, and David G. Speece
pp 4650 - 4654; DOI:
10.1021/ic00246a012
PDF
Mechanism of chiral recognition of octahedral metal complexes effected by bis(.mu.-d-tartrato)diantimonate(III) anion in solution. 2. Cage complexes of the type [Co(N)6]3+
Katsuhiko Miyoshi, Shinji Izumoto, Keiji Nakai, and Hayami Yoneda
pp 4654 - 4657; DOI:
10.1021/ic00246a013
PDF
Reaction of the antitumor drug cis-diamminedichloroplatinum(II) with the trinucleotide d(GpApG): identification of the two main products and kinetic aspects of their formation
Johannis L. Van der Veer, Hans Van den Elst, Jeroen H. J. Den Hartog, Anne Marie J. Fichtinger-Schepman, and Jan Reedijk
pp 4657 - 4663; DOI:
10.1021/ic00246a014
PDF
Synthesis and characterization of tetra-N-alkylated cyclam ligands that contain a functionalized nitrogen substituent
E. Kent Barefield, Keith A. Foster, Gary M. Freeman, and Keith D. Hodges
pp 4663 - 4668; DOI:
10.1021/ic00246a015
PDF
Isolation and characterization of a five-coordinate manganese(III) porphyrin cation. Crystal and molecular structure of aquo(tetraphenylporphinato)manganese(III) triflate
Michael M. Williamson and Craig L. Hill
pp 4668 - 4671; DOI:
10.1021/ic00246a016
PDF
Deuterium NMR study of amino acid coordination to chromium(III)
Charles A. Green, Helen Place, Roger D. Willett, and J. Ivan Legg
pp 4672 - 4677; DOI:
10.1021/ic00246a017
PDF
Structural study of the copper sites in metallothionein from Neurospora crassa
T. A. Smith, K. Lerch, and K. O. Hodgson
pp 4677 - 4680; DOI:
10.1021/ic00246a018
PDF
Chemistry of coordination compounds. 7. Single-crystal optical spectral studies of tetrabutylammonium bis(maleonitriledithiolato)nickelate(II)
G. V. R. Chandramouli and P. T. Manoharan
pp 4680 - 4686; DOI:
10.1021/ic00246a019
PDF
Theoretical characterization of nitrogen fixation: effect of ligand on the initial dinitrogen activation
A. K. Rappe
pp 4686 - 4691; DOI:
10.1021/ic00246a020
PDF
Exchange interaction through hydrogen-bond bridges and the effect of a single-oxygen bridge. Crystal structures and magnetic susceptibilities of two binuclear copper(II) complexes of 2-amino-2-methyl-1-propanol
Heikki Muhonen
pp 4692 - 4698; DOI:
10.1021/ic00246a021
PDF
Hexacoordinate phosphorus. 3. Neutral fluoro(trifluoromethyl)(N,N-dimethylcarbamato-O,O')phosphorus(V) derivatives
Ronald G. Cavell and Larry Vande Griend
pp 4699 - 4704; DOI:
10.1021/ic00246a022
PDF
A macrocyclic tetradentate ligand containing tertiary amine and pyridine functional groups. Electrochemical and x-ray structural studies on [CoII(CR-Me3)Cl]ClO4, chloro[meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene]cobalt(1+) perchlorate
Chi Ming Che, Shing Tat Mak, and Thomas C. W. Mak
pp 4705 - 4708; DOI:
10.1021/ic00246a023
PDF
Structure of the intermediate zirconium bromide hydride (Zr2Br2H) by neutron diffraction and its structural and bonding relationships to other phases
Sunil D. Wijeyesekera and John D. Corbett
pp 4709 - 4714; DOI:
10.1021/ic00246a024
PDF
A cobalt oxygen carrier in zeolite Y. A molecular "ship in a bottle"
Norman Herron
pp 4714 - 4717; DOI:
10.1021/ic00246a025
PDF
Heterobimetallic complexes of rhodium with platinum, silver, and gold containing bridging 2-[bis(diphenylphosphino)methyl]pyridine (PNP) ligands
Robert J. McNair and Louis H. Pignolet
pp 4717 - 4723; DOI:
10.1021/ic00246a026
PDF
Monoarylcobalt(II) compounds stabilized by bis ortho chelation
Adolphus A. H. Van der Zeijden and Gerard Van Koten
pp 4723 - 4725; DOI:
10.1021/ic00246a027
PDF
Multicomponent polyanions. 39. Speciation in the aqueous hydrogen ion-molybdate(MoO42-)-hydrogenphosphate(HPO42-) system as deduced from a combined Emf-phosphorus-31 NMR study
Lage Pettersson, Ingegaerd Andersson, and Lars Olof Oehman
pp 4726 - 4733; DOI:
10.1021/ic00246a028
PDF
Electron transfer. 81. Reductions of unsaturated dicarboxylic acids with vitamin B12x [cob(I)alamin]
G. Chithambarathanu Pillai, J. W. Reed, and E. S. Gould
pp 4734 - 4736; DOI:
10.1021/ic00246a029
PDF
Electron transfer. 82. Reduction of carboxylato-bound chromium(V) with hypophosphorous acid
S. K. Ghosh, Rathindra N. Bose, K. Laali, and E. S. Gould
pp 4737 - 4740; DOI:
10.1021/ic00246a030
PDF
Electron transfer. 83. Reductions of unsaturated esters with vitamin B12s [cob(I)alamin]
G. Chithambarathanu Pillai and E. S. Gould
pp 4740 - 4743; DOI:
10.1021/ic00246a031
PDF
Tetrakis(phenanthroline)di-.mu.-oxodimanganese(III,IV) tris(hexafluorophosphate).cntdot.acetonitrile and tetrakis(phenanthroline)di-.mu.-oxodimanganese(IV) tetraperchlorate.cntdot.acetonitrile: crystal structure analyses at 100 K, interpretation of disorder, and optical, magnetic, and electrochemical results
M. Stebler, A. Ludi, and H. B. Buergi
pp 4743 - 4750; DOI:
10.1021/ic00246a032
PDF
Tris(trifluoromethyl)phosphine iron(0) carbonyls: stereochemical effects
Anton B. Burg
pp 4751 - 4755; DOI:
10.1021/ic00246a033
PDF
Kinetics of reduction of metmyoglobins by ascorbate. Effect of the modification of the heme distal side, heme propionates, and 2,4-substituents of deuterohemin
Keiichi Tsukahara, Tomoyuki Okazawa, Hideki Takahashi, and Yasuo Yamamoto
pp 4756 - 4760; DOI:
10.1021/ic00246a034
PDF
Reactions of hydrogen peroxide with the iron-containing superoxide dismutase from Escherichia coli
David M. Dooley, Jennifer L. Karas, Timothy F. Jones, Cheryl E. Cote, and Susan B. Smith
pp 4761 - 4766; DOI:
10.1021/ic00246a035
PDF
Hydrogen bonding in metalloporphyrins. Mechanistic study of the reactions of (tetraphenylporphinato)iron(III) azide with imidazole and N-methylimidazole
W. Byers, J. A. Cossham, J. O. Edwards, A. T. Gordon, J. G. Jones, E. T. P. Kenny, A. Mahmood, J. McKnight, D. A. Sweigart, and et al.
pp 4767 - 4774; DOI:
10.1021/ic00246a036
PDF
A picosecond study of rapid multistep radiationless decay in manganese(III) porphyrins
Xinwei Yan, Christine Kirmaier, and Dewey Holten
pp 4774 - 4777; DOI:
10.1021/ic00246a037
PDF
Electronic structure of diammine(ascorbato)platinum(II) and the trans influence on the ligand dissociation energy
Harold Basch, M. Krauss, and W. J. Stevens
pp 4777 - 4779; DOI:
10.1021/ic00246a038
PDF
New multidentate ligands. 28. Synthesis and evaluation of new macrocyclic ligands containing bidentate endocyclic catechol donor groups
Yizhen Sun, Arthur E. Martell, and Ramunas J. Motekaitis
pp 4780 - 4785; DOI:
10.1021/ic00246a039
PDF
Thorium and uranium porphyrins. Synthesis and crystal structure of bis(acetylacetonato)(2,3,7,8,12,13,17,18-octaethylporphyrinato)thorium(IV)
A. Dormond, B. Belkalem, P. Charpin, M. Lance, D. Vigner, G. Folcher, and R. Guilard
pp 4785 - 4790; DOI:
10.1021/ic00246a040
PDF
Reaction of chromium(II) with iodoacetamide and properties of (H2O)5CrCH2CO(NH2)2+
P. Kita and R. B. Jordan
pp 4791 - 4794; DOI:
10.1021/ic00246a041
PDF
A proton magnetic resonance study of the conformational characterization of nickel(II)-tetraaza macrocyclic complexes
Jy Wann Chen, Chi Chang Chang, and Chung Sun Chung
pp 4794 - 4797; DOI:
10.1021/ic00246a042
PDF
Reaction of tris(oxalato)ruthenium(III) anion with titanium(III) and (oxalato)titanium(III) complexes
Olusegun Olubuyide, Kejian Lu, A. Olayinka Oyetunji, and Joseph E. Earley
pp 4798 - 4799; DOI:
10.1021/ic00246a043
PDF
Oxidation of (tetraphenylporphyrin)chromium(III) chloride by styrene ozonide
Ernst S. Schmidt, Thomas C. Bruice, Robert S. Brown, and Charles L. Wilkins
pp 4799 - 4800; DOI:
10.1021/ic00246a044
PDF

Issue 27


Vicinal heteroatom-carbon-13 spin-spin coupling constants in the apical positions of cage complexes: inorganic analogs of heteroatomic bicyclo[2.2.2]octane molecules
Peter A. Lay and Alan M. Sargeson
pp 4801 - 4802; DOI:
10.1021/ic00247a001
PDF
Carbon-to-boron bridged o-carboranes
Shao Hai Wu and Maitland Jones
pp 4802 - 4803; DOI:
10.1021/ic00247a002
PDF
Photoinduced long-range electron transfer in the zinc-substituted cytochrome c/cytochrome c peroxidase complex
Karen Taylor Conklin and George McLendon
pp 4804 - 4806; DOI:
10.1021/ic00247a003
PDF
Nineteen-electron adducts: measurement of .DELTA.G.degree. for the reactions of tricarbonyl(methylcyclopentadienyl)molybdenum with halide ligands
Cecelia E. Philbin, Cynthia A. Granatir, and David R. Tyler
pp 4806 - 4807; DOI:
10.1021/ic00247a004
PDF
pH-Induced intramolecular electron transfer
Gregory A. Neyhart and Thomas J. Meyer
pp 4807 - 4808; DOI:
10.1021/ic00247a005
PDF
Heterolytic and homolytic oxygen-oxygen bond cleavage reactions of acylperoxomanganese(III) porphyrins
John T. Groves and Yoshihito Watanabe
pp 4808 - 4810; DOI:
10.1021/ic00247a006
PDF
Synthetic study of some rare-earth-metal monohalide hydrides MXHx and their alkali-metal intercalates
Gerd Meyer, Shiou Jyh Hwu, Sunil Wijeyesekera, and John D. Corbett
pp 4811 - 4818; DOI:
10.1021/ic00247a007
PDF
Siloxy-zirconium chemistry. 1. Reaction of zirconium-carbon .sigma.-bonds with R3SiOH and the crystal structure of (1,2-dimethoxyethane)bis(triphenylsiloxy)dichlorozirconium(IV), (DME)ZrCl2(OSiPh3)2
Elizabeth A. Babaian, Duane C. Hrncir, Simon G. Bott, and Jerry L. Atwood
pp 4818 - 4821; DOI:
10.1021/ic00247a008
PDF
X-ray and neutron diffraction study of the new cationic bis(hydrido)-bridged platinum-iridium complex [(PEt3)2Pt(.mu.-H)2IrH2(PEt3)2 ]+[BPh4]-
Alberto Albinati, Thomas J. Emge, Thomas F. Koetzle, Stefano V. Meille, Alfredo Musco, and Luigi M. Venanzi
pp 4821 - 4827; DOI:
10.1021/ic00247a009
PDF
Manganese(III)-catecholate coordination in the bis(tetrabromocatecholato)(triphenylphosphine oxide)manganese(III) anionic dimer
Scott K. Larsen, Cortlandt G. Pierpont, Giovanni DeMunno, and Giuliano Dolcetti
pp 4828 - 4831; DOI:
10.1021/ic00247a010
PDF
Complexes of the type M2X4(LL)(LL') that contain mixed intramolecular phosphine ligand bridges. Synthesis and characterization of.beta.-[bis(diphenylphosphino)methane][bis(diphenylphosphino)ethane]tetrachlorodirhenium and related species
Phillip E. Fanwick, Dawn R. Root, and Richard A. Walton
pp 4832 - 4835; DOI:
10.1021/ic00247a011
PDF
Reactivity of bulky alkyldichlorostibines and alkyldichlorobismuthines toward [W(CO)5]2-: synthesis of compounds containing stibinidene, bismuthinidene, and dibismuth ligands
A. M. Arif, A. H. Cowley, N. C. Norman, and M. Pakulski
pp 4836 - 4840; DOI:
10.1021/ic00247a012
PDF
Substitution reactions of five-coordinate complexes. 2. Formation and aquation kinetics of the (Acido)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) (red) cation
Der Thin Wu and Chung Sun Chung
pp 4841 - 4845; DOI:
10.1021/ic00247a013
PDF
Reinvestigation of the pressure effect on the outer-sphere electron-transfer reaction between aquapentaamminecobalt(III) and hexacyanoferrate(II) in aqueous solution
Yoichi Sasaki, Kaoru Endo, Akira Nagasawa, and Kazuo Saito
pp 4845 - 4847; DOI:
10.1021/ic00247a014
PDF
Chiral metal complexes. 21. Stereochemical analysis of ternary ruthenium(II) complexes of .alpha.-diimines and glycine or N-substituted glycines, including the crystal structure of racemic bis(2,2'-bipyridine)glycinatoruthenium perchlorate dihydrate
Malcolm A. Anderson, John P. G. Richards, Allison G. Stark, Frederick S. Stephens, Robert S. Vagg, and Peter A. Williams
pp 4847 - 4851; DOI:
10.1021/ic00247a015
PDF
Where is the oxygen binding site of cytochrome c oxidase? Transmembrane helices of subunits I and II
Munime Lundeen
pp 4852 - 4856; DOI:
10.1021/ic00247a016
PDF
Electrochemistry of hanging-base basket-handle iron porphyrins. Coordination of iron(II) by the base and dioxygen
Doris Lexa, Michel Momenteau, J. M. Saveant, and Feng Xu
pp 4857 - 4865; DOI:
10.1021/ic00247a017
PDF
Neutral spin-delocalized mixed-valence manganese(I)-manganese(II) dimers bridged by alkoxide, imidazolate, or malonodinitrile anions
Renate Gross and Wolfgang Kaim
pp 4865 - 4870; DOI:
10.1021/ic00247a018
PDF
Preparation and structural studies of methylmercury compounds containing amino-deprotonated adenine
Jean Pierre Charland and Andre L. Beauchamp
pp 4870 - 4876; DOI:
10.1021/ic00247a019
PDF
Syntheses, properties and electrochemistry of transition-metal complexes of the macrocycle 1,4,7-tris(2-pyridylmethyl)-1,4,7-triazacyclononane (L). Crystal structures of [NiL](ClO4)2, [MnL](ClO4)2, and [PdL](PF6)2 containing a distorted-square-base-pyramidal PdIIN5 core
Karl Wieghardt, Ernst Schoeffmann, Bernhard Nuber, and Johannes Weiss
pp 4877 - 4883; DOI:
10.1021/ic00247a020
PDF
Transition-metal complexes with polyamino alcohols. 1. Structures of a dinuclear chromium(III) complex and a trinuclear cobalt complex with N-(3-aminopropyl)diethanolamine, a bifurcated quadridentate tripod ligand
Donald A. House, Vickie McKee, and Peter J. Steel
pp 4884 - 4889; DOI:
10.1021/ic00247a021
PDF
Synthesis and cluster interconversion chemistry of a linear trinuclear hexakis(.mu.-benzenethiolato)triiron(II) hexacarbonyl compound
M. Anton Walters and John C. Dewan
pp 4889 - 4893; DOI:
10.1021/ic00247a022
PDF
Pressure effects on the excited-state reaction dynamics of cis-bis(bipyridine)dichlororhodium(III), cis-Rh(bpy)2Cl2+
S. Wieland, J. DiBenedetto, R. Van Eldik, and P. C. Ford
pp 4893 - 4897; DOI:
10.1021/ic00247a023
PDF
Effect of nitrilotriacetate on the mechanism of reduction of copper(II) ions by .alpha.-hydroxyalkyl free radicals via complexes with copper-carbon bonds as intermediates. A pulse-radiolytic study
Mohamed Masarwa, Haim Cohen, and Dan Meyerstein
pp 4897 - 4900; DOI:
10.1021/ic00247a024
PDF
Kinetics of the iodine monochloride reaction with iodide measured by the pulsed-accelerated-flow method
Dale W. Margerum, Peter N. Dickson, Julius C. Nagy, Krishan Kumar, Conrad P. Bowers, and Kimber D. Fogelman
pp 4900 - 4904; DOI:
10.1021/ic00247a025
PDF
Kinetic study of the conversion of cis-diaqua(1,4,7,10-tetraazacyclotridecane)nickel(II) to the planar complex
Anne M. Martin, Kenneth J. Grant, and E. Joseph Billo
pp 4904 - 4906; DOI:
10.1021/ic00247a026
PDF
Binuclear platinum(II) photochemistry. Nucleophile-induced reduction of electron acceptors by electronically excited Pt2(P2O5H2)44-
Chi Ming Che, Kar Cheong Cho, Wai Sang Chan, and Harry B. Gray
pp 4906 - 4909; DOI:
10.1021/ic00247a027
PDF
Use of NMR chemical shifts to study the bonding in mixed-ligand-metal complexes
Henry A. Kuska
pp 4909 - 4910; DOI:
10.1021/ic00247a028
PDF